Curable organopolysiloxane composition for transducers and applications of such curable silicone composition for transducers

Patent metadata

Field	Value
Publication number	US-9947858-B2
Application number	US-201314655811-A
Country	US
Kind code	B2
Filing date	Dec 26, 2013
Priority date	Dec 28, 2012
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

The present invention provides a curable organopolysiloxane composition capable of producing a cured article that can be used as a transducer and provided with excellent mechanical characteristics and/or electrical characteristics. The present invention also relates to a novel curable organopolysiloxane composition for transducer use comprising a curable organopolysiloxane composition, dielectric inorganic fine particles having a specific dielectric constant of greater than or equal to 10, and fine particles having a specific dielectric constant of less than 10.

First claim

What is claimed:

1. A member for transducers, the member being formed by at least partial curing of a curable transducer composition, comprising:
(A) a curable organopolysiloxane composition,
(D) dielectric inorganic fine particles having a specific dielectric constant at 1 kHz of greater than or equal to 10 at room temperature, and
(E 0 ) fine particles having a specific dielectric constant at 1 kHz of less than 10 at room temperature,
further optionally comprising one or more of:
(F) an additive for improvement of mold releasability or insulation breakdown characteristics; and
(G) a compound having a highly dielectric functional group, wherein the compound is other than an organopolysiloxane participating in the curing reaction.

2. The member according to claim 1 , wherein the specific dielectric constant of said dielectric inorganic fine particles (D) is greater than or equal to 50.

3. The member according to claim 1 , wherein the dielectric inorganic fine particles (D) are one or more types of inorganic fine particles selected from the group consisting of: titanium oxide, barium titanate, strontium titanate, lead titanate zirconate, barium titanate, and composite metal oxides in which the barium and titanium positions of barium titanate are partially replaced by an alkaline earth metal or rare earth metal.

4. The member according to claim 1 , wherein the component (E 0 ) is at least one inorganic fine particle selected from the group consisting of electrically conductive inorganic particles, insulating-inorganic particles, and reinforcing inorganic particles.

5. The member according to claim 1 , wherein a part or the entire amount of the components (D) and (E 0 ) is surface-treated by one or more types of surface treatment agent.

6. The member according to claim 1 , wherein the average particle diameter of said component (D) is in the range of 0.01 to 10 μm.

7. The member according to claim 4 , wherein said component (E 0 ) comprises electrically conductive fine particles having the BET specific surface area of greater than or equal to 10 m 2 /g.

8. The member according to claim 4 , wherein said component (E 0 ) is a mixture of reinforcing fine particles and electrically conductive fine particles.

9. The member according to claim 1 , wherein the blending amount of the component (D) is 10 to 90% by weight and the blending amount of the component (E 0 ) is 0.05 to 20% by weight.

10. The member according to claim 1 , comprising:
5 to 90% by weight of curable organopolysiloxane composition (A),
10 to 93.9% by weight of dielectric inorganic fine particles (D), and 1.05 to 30% by weight of fine particles (E 0 ) comprising 1 to 20% by weight of (E1) reinforcing fine particles and 0.05 to 10% by weight of (E2) electrically conductive fine particles.

11. The member according to claim 5 , wherein the surface of the components (D) and (E 0 ) is treated by blending components (D) and (E 0 ) and one or more types of surface treatment agent using mechanical means.

12. The member according to claim 5 , wherein the surface treatment agent is silazanes, organopolysiloxanes, silane coupling agents or mixture thereof.

13. The member according to claim 1 , wherein the method of preparing the curable transducer composition comprises: a step of treating the surface of component (D) and component (E 0 ) by blending one or more types of surface treatment agent using at least one mechanical means selected from the group consisting of twin screw extruders, twin screw kneaders, and single screw blade-type extruders.

14. The member according to claim 13 organopolysiloxane, wherein the content of fillers is greater than or equal to 50 mass % of the composition prepared by said mixing procedure.

15. The member according to claim 1 , wherein the (A) curable organopolysiloxane composition is curable by condensation curing reaction, addition curing reaction, peroxide curing reaction, photo-curing reaction or drying with solvent removal.

16. The member according to claim 1 ,
wherein (A) curable organopolysiloxane composition comprises:
(A11) at least one first type of organohydrogenpolysiloxane having silicon atom-bonded hydrogen atoms at both molecular terminals, a weight fraction of hydrogen atoms being 0.1 to 1.0% by weight of the curable transducer composition;
(A12) at least one second type of organohydrogenpolysiloxane having at least 3 silicon atom-bonded hydrogen atoms in a single molecule, a weight fraction of hydrogen atoms being 0.03 to 2.0% by weight of the curable transducer composition;
(A2) at least one type of organopolysiloxane having at least 2 alkenyl groups in a single molecule, a weight fraction of the alkenyl groups being 0.05 to 0.5% by weight of the curable transducer composition; and
(A3) a hydrosilylation reaction catalyst.

17. The member according to claim 1 , wherein
(A) curable organopolysiloxane comprises reactive organopolysiloxane having a highly dielectric functional group.

18. The member according to claim 1 , wherein the member is a silicone elastomer intermediate layer.

19. A transducer comprising:
a pair of electrodes;
a silicone elastomer intermediate layer of claim 18 disposed between the electrodes.

20. The transducer of claim 19 having two or more silicone elastomer intermediate layers, wherein at least two of the silicone elastomer intermediate layers are stacked.

Assignees

• Dow Corning
• Dow Corning Toray Co Ltd

Inventors

• Fujisawa Toyohiko
• Fukui Hiroshi
• Furukawa Haruhiko
• Hupfield Peter Cheshire
• Kim Hong Sub
• Kitaura Eiji
• Larson Kent R
• Nishiumi Wataru
• Ogawa Takuya
• Onishi Masayuki
• Ozaki Kouichi
• Wakita Keiji

Classifications

• C08G77/12

  containing silicon bound to hydrogen · CPC title

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• C08L83/00

  Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers · CPC title

• C08K2003/2275

  Ferroso-ferric oxide (Fe3O4) · CPC title

• C08K3/01

  characterized by their specific function · CPC title