Negative electrode for use in secondary battery and secondary battery including the same
US-9350018-B2 · May 24, 2016 · US
US9945037B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9945037-B2 |
| Application number | US-201314391655-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 15, 2013 |
| Priority date | Oct 15, 2012 |
| Publication date | Apr 17, 2018 |
| Grant date | Apr 17, 2018 |
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A steel sheet used to manufacture a container, wherein the steel sheet includes a chromate film layer or a film layer including Zr on the Ni plating layer, the Ni plating layer includes one or more of a hydroxyl Ni and a Ni oxide, an adhesion amount of the Ni plating layer in terms of an amount of Ni is 0.3 g/m 2 or more, a concentration of oxygen atoms of the Ni plating layer due to the hydroxyl Ni and the Ni oxide is 1 to 10 atomic %, an adhesion amount of the chromate film layer in terms of the amount of Cr is 1 to 40 mg/m 2 , and an adhesion amount of the film layer including Zr in terms of an amount of Zr is 1 to 40 mg/m 2 or more.
Opening claim text (preview).
The invention claimed is: 1. A steel sheet used to manufacture a container, the steel sheet comprising: a Ni plating layer; and a chromate film layer or a film layer including Zr, on the Ni plating layer, wherein the Ni plating layer includes one or more of a hydroxyl Ni and a Ni oxide, an adhesion amount of the Ni plating layer in terms of an amount of Ni is 0.3 g/m 2 or more, a concentration of oxygen atoms of the Ni plating layer due to the hydroxyl Ni and the Ni oxide is 1 to 10 atomic %, an adhesion amount of the chromate film layer in terms of an amount of Cr is 1 to 40 mg/m 2 , and an adhesion amount of the film layer including Zr in terms of an amount of Zr is 1 to 40 mg/m 2 . 2. The steel sheet used to manufacture a container according to claim 1 , wherein the concentration of oxygen atoms is 1 to 10 atomic % in an entire area of a thickness of the Ni plating layer excluding a natural oxide film formed on a surface of the Ni plating layer. 3. A method of manufacturing a steel sheet used to manufacture a container according to claim 1 , the method comprising: forming the Ni plating layer including one or more of the hydroxyl Ni and the Ni oxide by dipping a base steel sheet in a plating bath and then performing a cathode-electrolysis, wherein a current density is set to a value higher than a critical current density of precipitation of Ni, the critical current density depending on a plating bath condition including a concentration of a Ni ion and a pH thereof, and wherein the plating bath consists of an aqueous solution in which one or more of a Ni sulfate and a Ni chloride is dissolved, and forming the chromate film layer of which the adhesion amount in terms of the amount of Cr is 1 to 40 mg/m 2 on the Ni plating layer or forming the film layer including Zr of which the adhesion amount in terms of the amount of Zr is 1 to 40 mg/m 2 , on the Ni plating layer. 4. The method of manufacturing a steel sheet according to claim 3 , wherein a concentration of the Ni sulfate of the aqueous solution of the plating bath is set to 5% to 30% and a concentration of the Ni chloride of the aqueous solution of the plating bath is set to 5% to 30%. 5. The method of manufacturing a steel sheet according to claim 3 , wherein the pH of the plating bath is set to 2 to 4. 6. The method of manufacturing a steel sheet according to claim 4 , wherein the pH of the plating bath is set to 2 to 4.
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