Aerogel-containing polyurethane composite material

Patent metadata

Field	Value
Publication number	US-9944793-B2
Application number	US-201314405429-A
Country	US
Kind code	B2
Filing date	Jun 3, 2013
Priority date	Jun 4, 2012
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

The present invention relates to a composite material comprising nanoporous particles and at least one binder constructed from at least one isocyanate and at least one polymer P selected from the group consisting of polyvinylamine, poly(meth)acrylic acid, poly(meth)acrylic ester, polyvinyl alcohol, polyvinylthiol and mixtures thereof, wherein said at least one binder is used in an amount of 0.1 to 20 wt %, based on the amount of nanoporous particles, a composition for producing a composite material of this type, a process for producing a composite material of this type, shaped articles comprising said composite material and the use of said composite material for thermal and/or acoustical insulation.

First claim

The invention claimed is:

1. A composite material comprising
nanoporous aerogel particles or pyrogenous silica particles, and
at least one binder prepared by reacting at least one water-emulsifiable prepolymer and at least one water-soluble, or water-dispersible polymer selected from the group consisting of a polyvinylamine having a molecular weight of 10,000 to 1,000,000 g/mol, a polyvinyl alcohol having a molecular weight of 10,000 to 500,000 g/mol, a polyvinylthiol having a molecular weight of 10,000 to 500,000 g/mol, and any mixture thereof, wherein the reaction results in crosslinking of the at least one water-emulsifiable prepolymer with the at least one water-soluble or water-dispersible polymer, wherein the at least one binder is present in an amount of 0.1 wt % to 20 wt %, relative to an amount of the nanoporous aerogel particles or the pyrogenous silica particles, and the at least one water-emulsifiable prepolymer is prepared from an isocyanate compound and at least one compound that includes Zerewitinow-reactive groups selected from the group consisting of a polyol, a sulfonic acid, and mixtures thereof.

2. The composite material according to claim 1 wherein the nanoporous aerogel particles or the pyrogenous silica particles are granular.

3. The composite material according to claim 1 wherein the at least one compound comprising Zerewitinow-reactive groups is a polyethylene glycol having a molecular weight of 200 to 6000 g/mol, an alkylpolyethylene glycol having a molecular weight of 200 to 2000 g/mol, or any mixture thereof.

4. The composite material according to claim 1 wherein the nanoporous aerogel particles or the pyrogenous silica particles includes a hydrophobic coating.

5. The composite material according to claim 1 wherein the at least one water-soluble, or water-dispersible polymer comprises the mixture of the polyvinylamine, the polyvinyl alcohol, and a polyacrylic acid having a molecular weight of 1000 to 400,000 g/mol, and a filler selected from the group consisting of sheet-silicates, clay minerals, metal oxides, silica gel, and glass spheres.

6. A process for producing a composite material according to claim 1 , comprising:
reacting at least one water-emulsifiable prepolymer, and at least one water-soluble or water-dispersible polymer selected from the group consisting of a polyvinylamine having a molecular weight of 10,000 to 1,000,000 g/mol, a polyvinyl alcohol having a molecular weight of 10,000 to 500,000 g/mol, a polyvinylthiol having a molecular weight of 10,000 to 500,000 g/mol, and any mixture thereof, wherein the reaction results in crosslinking of the at least one water-emulsifiable prepolymer with the at least one water-soluble or water-dispersible polymer to provide a composition;
mixing the composition with nanoporous aerogel particles or pyrogenous silica particles to form a mixture that is

a) subjected to a shaping operation and optional curing, or
b) pelletized, and subjected to shaping and optionally curing.

7. A shaped article comprising a composite material according to claim 1 and at least one additional foam material.

8. The shaped article according to claim 7 wherein the at least one additional foam material is laminated to the composite material, or mixed with the composite material.

9. The shaped article according to claim 8 wherein the at least one additional foam material comprises polyurethane, polystyrene, or a mixture thereof.

10. The shaped article according to claim 7 further comprising at least one outer layer that is laminated to the composite material.

11. A thermal or acoustical insulation comprising the composite material according to claim 1 .

12. A composite material comprising:
nanoporous aerogel particles or pyrogenous silica particles; and
a binder prepared from reacting a mixture of a polyvinylamine having a molecular weight of 10,000 to 500,000 g/mol, a polyvinyl alcohol having a molecular weight of 10,000 to 100,000 g/mol, and a water-emulsifiable prepolymer prepared from an isocyanate compound and a compound that includes Zerewitinow-reactive groups selected from the group consisting of a polyol, a sulfonic acid, and a mixture thereof, wherein the reaction of said polyvinylamine, polyvinyl alcohol and water-emulsifiable prepolymer results in crosslinking of the water-emulsifiable prepolymer with polyvinylamine and polyvinyl alcohol, wherein the binder is present in an amount of 0.1 wt % to 20 wt %, relative to an amount of the nanoporous aerogel particles or the pyrogenous silica particles.

13. The composite material according to claim 12 in the form of a plate.

14. The composite material according to claim 12 wherein the compound that includes Zerewitinow-reactive groups is an isocyanate-reactive sulfonic acid.

15. The composite material according to claim 12 wherein the prepolymer prepared from an isocyanate compound and a compound comprising Zerewitinow-reactive groups is a polyethylene glycol having a molecular weight of 200 to 6000 g/mol, an alkylpolyethylene glycol having a molecular weight of 200 to 2000 g/mol, or any mixture thereof.

16. The composite material according to claim 15 wherein the binder further comprises a polyacrylic acid having a molecular weight of 1000 to 400,000 g/mol, the composite material further comprises a filler selected from the group consisting of sheet-silicates, clay minerals, metal oxides, silica gel, and glass spheres, and the composite material has a flexural strength/stress at 10% compression of from 50 kPa to 130 kPa.

17. The composite material according to claim 12 , wherein the composite material has a thermal conductivity of 12 to 22 mW/m·K.

18. The composite material according to claim 12 wherein the binder further comprises a polyacrylic acid having a molecular weight of 1000 to 400,000 g/mol.

19. The composite material according to claim 18 further comprising a filler selected from the group consisting of sheet-silicates, clay minerals, metal oxides, silica gel, and glass spheres, and the composite material has a flexural strength/stress at 10% compression of from 50 kPa to 130 kPa.

20. The composite material according to claim 12 , wherein the nanoporous aerogel particles are is present and the composite material has a thermal conductivity of 12 to 22 mW/m·K.

21. The composite material according to claim 12 , wherein the pyrogenous silica particles are present and the composite material has a thermal conductivity of 12 to 22 mW/m·K.

22. A composite material comprising:
nanoporous aerogel particles or pyrogenous silica particles,
at least one binder prepared by reacting at least one water-emulsifiable prepolymer, and at least one water-soluble, or water-dispersible polymer prepared from a polyvinylamine having a molecular weight of 10,000 to 1,000,000 g/mol, a polyvinyl alcohol having a molecular weight of 10,000 to 500,000 g/mol, and a polyacrylic acid having a molecular weight of 1000 to 400,000 g/mol, wherein the reaction of the water-emulsifiable prepolymer with the at least one water-soluble or water-dispersible polymer results in crosslinking of the water-emulsifiable prepolymer with the at least one water-soluble or water-dispersible polymer, and
a filler selected from the group consisting of sheet-silicates, clay minerals, metal oxides, silica gel, and glass spheres,
wherein the at least one binder is present in an amount of 0.1 wt % to 20 wt %, relative to an amount of the nanoporous aerogel particles or the pyrogenous silica p

Assignees

• Basf Se

Inventors

• Eling Berend
• Auffarth Stefan

Classifications

• C08J2475/00

  Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers · CPC title

• C08J2205/042

  Nanopores, i.e. the average diameter being smaller than 0,1 micrometer · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• C08L75/04 Primary

  Polyurethanes · CPC title

• C08G18/792

  formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates · CPC title