Organic-inorganic composite, structural body, and method for producing organic-inorganic composite

Patent metadata

Field	Value
Publication number	US-9944767-B2
Application number	US-201615275850-A
Country	US
Kind code	B2
Filing date	Sep 26, 2016
Priority date	Mar 27, 2014
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

The organic-inorganic composite of the present invention includes an organic compound having a carbonyl group, an inorganic compound containing a metal component, and a silver component. The ratio of the number of metal atoms in the inorganic compound to the number of carbon atoms in the organic compound is from 0.04 to 1.60, and the ratio of the number of silver atoms in the silver component to the number of carbon atoms in the organic compound is from 0.07 to 0.55. The organic-inorganic composite may include, for example, an inorganic compound having a metal matrix structure containing a metal M and oxygen, an organic compound having a carbonyl group, and silver ions. The carbonyl group is bonded to a side chain R 1 of the organic compound and has an end group R 2 .

First claim

What is claimed is:

1. An organic-inorganic composite comprising:
a polymer having a carbonyl group,
an inorganic compound having a metal matrix structure containing oxygen, and
a silver component,
wherein the ratio of the number of metal atoms in the inorganic compound to the number of carbon atoms in the polymer is from 0.04 to 1.60, and the ratio of the number of silver atoms in the silver component to the number of carbon atom in the polymer is from 0.07 to 0.55, and
wherein a separation performance indicating the function of olefin/paraffin separation is 20 or more.

2. The organic-inorganic composite according to claim 1 , wherein the inorganic compound contains at least one metal atom selected from the group consisting of Si, Ti, Al, and Zr.

3. The organic-inorganic composite according to claim 1 , wherein the inorganic compound is a hydrolysate of a metal alkoxide.

4. The organic-inorganic composite according to claim 1 , wherein the polymer includes a carbon structure in which carbon atoms are bonded and the carbonyl group bonded to the carbon structure.

5. The organic-inorganic composite according to claim 1 , wherein the organic-inorganic composite has the function of selectively allowing a specific component contained in a fluid composed of plural components to pass through.

6. A structural body comprising:
a substrate and
the organic-inorganic composite according to claim 1 , being formed on the substrate.

7. A method for producing an organic-inorganic composite that includes an inorganic compound, an organic compound, and a silver component,
the method comprising a hybridization step of obtaining the organic-inorganic composite by using, as a raw material of the organic compound, a polymer having a carbonyl group, using, as a raw material of the inorganic compound, a material containing a metal compound containing oxygen, and using a raw material of the silver component,
wherein steps after the silver component is added are performed at a temperature of 100° C. or lower to form said organic-inorganic composite wherein the ratio of the number of metal atoms in the inorganic compound to the number of carbon atoms in the polymer is from 0.04 to 1.60, and the ratio of the number of silver atoms in the silver component to the number of carbon atoms in the polymer is from 0.07 to 0.55, and
wherein a separation performance indicating the function of olefin/paraffin separation is 20 or more.

8. The method for producing an organic-inorganic composite according to claim 7 , wherein, in the hybridization step, a compound containing at least one metal atom selected from the group consisting of Si, Ti, Al, and Zr is used as the raw material of the inorganic compound.

9. The method for producing an organic-inorganic composite according to claim 7 , wherein, in the hybridization step, a metal alkoxide is used as the raw material of the inorganic compound, and the metal alkoxide is hydrolyzed in a solution containing the metal alkoxide and the polymer to thereby hybridize the inorganic compound with the polymer.

10. The method for producing an organic-inorganic composite according to claim 9 , wherein, in the hybridization step, the silver component is added after the hydrolysis.

11. The method for producing an organic-inorganic composite according to claim 7 , wherein, in the hybridization step, heat treatment is performed after the inorganic compound and the polymer are hybridized, and then the silver component is added.

Assignees

• Ngk Insulators Ltd

Inventors

• Kinoshita Naoto
• Noda Kenichi
• Shibata Hiroyuki

Classifications

• C08L101/06 Primary

  containing oxygen atoms {(C08L101/025 takes precedence)} · CPC title

• B01D71/022

  Metals · CPC title

• C08G77/02

  Polysilicates · CPC title

• C08L79/00

  Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00 · CPC title

• B01D67/0079

  Manufacture of membranes comprising organic and inorganic components · CPC title