Resin composition and manufacturing method thereof
US-2024400734-A1 · Dec 5, 2024 · US
US9944737B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9944737-B2 |
| Application number | US-201515537441-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 15, 2015 |
| Priority date | Dec 22, 2014 |
| Publication date | Apr 17, 2018 |
| Grant date | Apr 17, 2018 |
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Provided is a method of suspension polymerization comprising (i) providing a suspension of liquid droplets in an aqueous medium, wherein said droplets comprise (a) one or more water-insoluble vinyl monomers, and (b) a polyelectrolyte (PED) having a polarity, (c) one or more initiators, and wherein said aqueous medium comprises a polyelectrolyte (PEW) having a polarity that is opposite to the polarity of said polyelectrolyte (PED), (ii) polymerizing said vinyl monomer or allowing said vinyl monomer to polymerize.
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The invention claimed is: 1. A method of suspension polymerization comprising (i) providing a suspension of liquid droplets in an aqueous medium, wherein said droplets comprise (a) one or more water-insoluble vinyl monomers, and (b) a polyelectrolyte (PED) having a polarity, (c) one or more initiators, and wherein said aqueous medium comprises a polyelectrolyte (PEW) having a polarity that is opposite to the polarity of said polyelectrolyte (PED), (ii) polymerizing said vinyl monomer or allowing said vinyl monomer to polymerize. 2. The method of claim 1 , wherein the suspension has a pH of 5 to 10. 3. The method of claim 1 , wherein said polyelectrolyte (PED) has negative polarity and said polyelectrolyte (PEW) has positive polarity. 4. The method of claim 1 , wherein said polyelectrolyte (PED) comprises polymerized units of ionic monomer in an amount of 3 mole % to 12 mole %. 5. The method of claim 1 , wherein said polyelectrolyte (PEW) comprises polymerized units of ionic monomer in an amount of 40 mole % to 100 mole %. 6. The method of claim 1 , wherein said polyelectrolyte (PED) is a vinyl polyelectrolyte.
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