Production method of ultrafine crystalline alloy ribbon
US-9224527-B2 · Dec 29, 2015 · US
US9943904B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9943904-B2 |
| Application number | US-90938310-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 21, 2010 |
| Priority date | Jun 30, 2004 |
| Publication date | Apr 17, 2018 |
| Grant date | Apr 17, 2018 |
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A magnesium alloy material such as a magnesium alloy cast material or a magnesium alloy rolled material, excellent in mechanical characteristics and surface precision, a producing method capable of stably producing such material, a magnesium alloy formed article utilizing the rolled material, and a producing method therefor. The magnesium material includes a melting step of melting a magnesium alloy in a melting furnace to obtain a molten metal, a transfer step of transferring the molten metal from the melting furnace to a molten metal reservoir, and a casting step of supplying a movable mold with the molten metal from the molten metal reservoir, through a pouring gate, and solidifying the molten metal to continuously produce a cast material. Parts are formed by a low-oxygen material having an oxygen content of 20 mass % or less. The cast material is given a thickness of from 0.1 to 10 mm.
Opening claim text (preview).
The invention claimed is: 1. A magnesium alloy cast material, comprising: a surface part; a central part; and a ripple mark present on the surface part, wherein the ripple mark present on the surface part of the cast material satisfies a relation rw×rd<1.0 for a maximum width rw and a maximum depth rd, rw and rd being in units of mm, wherein during casting, a molten metal is supplied from a pouring gate with a supply pressure of equal to or larger than 101.8 kPa and less than 118.3 kPa, and supplied such that a distance from a distal end of the pouring gate to a position where the molten metal first contacts a movable mold substantially becomes less than 10% of a distance between a plane containing the rotary axes of rolls and the distal end of the pouring gate, and wherein the magnesium alloy comprises magnesium and at least a first additional element and at least a second additional element, wherein the at least first additional element is selected from the group of Al, and Zn, in an amount of 0.5 mass % or more per element wherein the difference in mass of the at least first additional element is less than 10% between the surface part and the central part of the magnesium alloy cast material, and the at least second additional element includes Sr, in an amount of 0.5 mass % or more per element wherein the difference in mass of the at least second additional element is less than 10% between the surface part and the central part of the magnesium alloy cast material. 2. The magnesium alloy cast material of claim 1 , wherein an intermetallic compound has an average size of 20 μm or less. 3. The magnesium alloy cast material of claim 1 , wherein a dendrite arm spacing (DAS) is from 0.5 μm to 5.0 μm. 4. The magnesium alloy cast material of claim 1 , wherein a depth of a surface defect is less than 10% of a thickness of the cast material. 5. The magnesium alloy cast material of claim 1 , wherein a plate thickness of the cast material is from 0.1 to 10.0 mm. 6. The magnesium alloy cast material of claim 1 , wherein the cast material, upon being subjected to rolling, has an average size of a crystal grain of from 0.5 μm to 30 μm. 7. The magnesium alloy cast material of claim 6 , wherein a difference between the average size of a crystal grain in a surface part of the cast material subjected to rolling and the average size of a crystal grain in a central part thereof is 20% or less. 8. The magnesium alloy cast material of claim 6 , wherein an average size of an intermetallic compound is from 20 μm or less. 9. The magnesium alloy cast material of claim 6 , wherein a depth of a surface defect is less than 10% of a thickness of the cast material subjected to rolling. 10. A magnesium alloy cast material, comprising: a surface part; a central part; and a ripple mark present on the surface part, wherein the ripple mark present on the surface part of the cast material satisfies a relation rw×rd<1.0 for a maximum width rw and a maximum depth rd, rw and rd being in units of mm, wherein during casting, a molten metal is supplied from a pouring gate with a supply pressure of equal to or larger than 101.8 kPa and less than 118.3 kPa, and supplied such that a distance from a distal end of the pouring gate to a position where the molten metal first contacts a movable mold substantially becomes less than 10% of a distance between a plane containing the rotary axes of rolls and the distal end of the pouring gate, and wherein the magnesium alloy comprises magnesium and at least a first additional element and at least a second additional element, wherein the at least first additional element is selected from the group of Al, Zn, Mn, Y, Zr, Cu, Ag and Si, in an amount of 0.5 mass % or more per element wherein the difference in mass of the at least first additional element is less than 10% between the surface part and the central part of the magnesium alloy cast material, and the at least second additional element is selected from the group of Ni, Au, Pt, Sr, Ti, B, Bi, Ge, In, Nd, La and Re, in an amount of 0.5 mass % or more per element wherein the difference in mass of the at least second additional element is less than 10% between the surface part and the central part of the magnesium alloy cast material. 11. A magnesium alloy cast material, comprising: a surface part; a central part; and a ripple mark present on the surface part, wherein the ripple mark present on the surface part of the cast material satisfies a relation rw×rd<1.0 for a maximum width rw and a maximum depth rd, rw and rd being in units of mm, wherein during casting, a molten metal is supplied from a pouring gate with a supply pressure of equal to or larger than 101.8 kPa and less than 118.3 kPa, and supplied such that a distance from a distal end of the pouring gate to a position where the molten metal first contacts a movable mold substantially becomes less than 10% of a distance between a plane containing the rotary axes of rolls and the distal end of the pouring gate, and wherein the magnesium alloy comprises magnesium and at least a first additional element and at least a second additional element, wherein the at least first additional element is selected from the group of Al, Zn, Y and Si, in an amount of 0.5 mass % or more per element wherein the difference in mass of the at least first additional element is less than 10% between the surface part and the central part of the magnesium alloy cast material, and the at least second additional element is selected from the group of Ni, Au, Pt, Sr, Ti, B, Bi, Ge, In, Nd, La and Re, in an amount of 0.5 mass % or more per element wherein the difference in mass of the at least second additional element is less than 10% between the surface part and the central part of the magnesium alloy cast material.
Casting surfaces · CPC title
Alloys based on magnesium · CPC title
of specific alloys · CPC title
Surface feature [e.g., rough, mirror] · CPC title
with zinc or cadmium as the next major constituent · CPC title
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