Biocompatible electrochemical supercapacitor

Patent metadata

Field	Value
Publication number	US-9941522-B2
Application number	US-201414772744-A
Country	US
Kind code	B2
Filing date	Mar 4, 2014
Priority date	Mar 7, 2013
Publication date	Apr 10, 2018
Grant date	Apr 10, 2018

Abstract

A supercapacitor to be submerged in a medium containing a biological material and an oxidant, wherein the anode comprises a first enzyme that can catalyse the oxidation of the biological material and the cathode comprises a second enzyme that can catalyse the reduction of the oxidant, and wherein each of the anode and cathode electrodes consists of a solid agglomerate of a conductive material mixed with the first or the second enzyme, said agglomerate having a specific surface that is larger than or equal to 20 m 2 /g and an average pore size varying between 0.7 nm and 10 pm.

First claim

The invention claimed is:

1. A supercapacitor intended to be immersed in a medium containing a biological material and an oxidizer, wherein the anode comprises a first enzyme capable of catalyzing the oxidation of the biological material and the cathode comprises a second enzyme capable of catalyzing the reduction of the oxidizer, and wherein each of the anode and cathode electrodes is formed of a solid cluster of a conductive material mixed with the first or with the second enzyme, said cluster having a specific surface area greater than or equal to 20 m 2 /g and an average pore size ranging from 0.7 nm to 10 μm.

2. The supercapacitor of claim 1 , wherein the conductive material is selected from the group comprising carbon nanotubes, graphene sheets, and a mixture thereof.

3. The supercapacitor of claim 1 , wherein the biological material is a sugar and wherein the first enzyme is selected from the group comprising the glucose oxidase enzyme, the lactose oxidase enzyme, the galactose oxidase enzyme, the fructose oxidase enzyme, the glucose dehydrogenase enzyme, and a mixture thereof.

4. The supercapacitor of claim 1 , wherein the second enzyme is selected from the group comprising the polyphenol oxidase enzyme (PPO), the laccase enzyme, the bilirubin oxidase enzyme, and a mixture thereof.

5. The supercapacitor of claim 1 , wherein the anode further comprises a first redox mediator capable of exchanging electrons with the first enzyme.

6. The supercapacitor of claim 5 , wherein the first mediator is selected from the group comprising ubiquinone, ferrocene, cobaltocene, N-methyl phenothiazine, 8-hydroxyquinoline-5-sulfonic acid hydrate (HQS), and a mixture thereof.

7. The supercapacitor of claim 1 , wherein the cathode further comprises a second redox mediator capable of exchanging electrons with the second enzyme.

8. The supercapacitor of claim 7 , wherein the second mediator is selected from the group comprising quinone, ABTS, osmocene, ruthenocene, cobalt(II) tetraphenylporphyrin, zinc phtalocyanine, and a mixture thereof.

9. The supercapacitor of claim 1 , wherein each cluster of the anode and of the cathode is attached to an electrode wire .

10. The supercapacitor of claim 1 , wherein the anode and cathode electrodes are each surrounded with a semipermeable membrane which lets through the oxidizer and the biological material and which does not let through the first and second enzymes.

11. The supercapacitor of claim 1 , wherein the anode and cathode electrodes are altogether surrounded with a semipermeable membrane which lets through the biological material and the oxidizer and which does not let through the first and second enzymes.

12. A method of manufacturing a supercapacitor, wherein the anode and the cathode are formed by compression of a dissolved mixture comprising a conductive material associated with a first or a second enzyme to form a solid cluster of the conductive material mixed with the first or with the second enzyme, said cluster having a specific surface area greater than or equal to 20 m 2 /g and an average pore size ranging from 0.7 nm to 10 μm.

Assignees

• Centre Nat Rech Scient
• Univ Joseph Fourier

Inventors

• Cosnier Serge
• Holzinger Michael
• Le Goff Alan
• Agnes Charles

Classifications

• H01G11/36 Primary

  Nanostructures, e.g. nanofibres, nanotubes or fullerenes · CPC title

• Y02B90/18

  Cross-Sectional Technologies · mapped topic

• H01M2250/30

  Fuel cells in portable systems, e.g. mobile phone, laptop · CPC title

• H01G11/62

  characterised by the solute, e.g. salts, anions or cations therein · CPC title

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title