Apparatus, method and system for detecting salt in a hydrocarbon fluid

Patent metadata

Field	Value
Publication number	US-9939405-B2
Application number	US-201514965583-A
Country	US
Kind code	B2
Filing date	Dec 10, 2015
Priority date	Jul 13, 2012
Publication date	Apr 10, 2018
Grant date	Apr 10, 2018

Abstract

A method for determining a salt concentration of a hydrocarbon fluid using a conductivity sensor and a hydrocarbon testing solution includes forming the hydrocarbon testing solution. The electropolymerizable monomer is operable to form a resultant associated polymer at a peak potential of the electropolymerizable polymer. The method includes introducing the hydrocarbon testing solution into the conductivity sensor. The method includes inducing a range of potential across the hydrocarbon testing solution such that at least a portion of the electropolymerizable monomer polymerizes. The range of induced potential includes the peak potential of the electropolymerizable polymer. The method includes detecting a range of electrical current associated with the range of potential induced. The method also includes the step of determining the salt concentration of the hydrocarbon fluid using the range of potential induced and the range of electrical current detected.

First claim

What is claimed is:

1. A conductivity sensor useful for determining the salt concentration of a hydrocarbon testing solution by forming a resultant associated polymer, the conductivity sensor comprising:
a housing that is operable to contain the hydrocarbon testing solution and that is non-conductive;
a three-electrode set positioned within the housing comprising a working electrode, a counter electrode and a reference electrode, where the working electrode has a first surface area and the counter electrode has a second surface area, where the second surface area is greater than the first surface area, where the working and reference electrodes together are operable to induce a potential in the hydrocarbon testing solution, and where the working and counter electrodes together are operable to detect a current in the hydrocarbon testing solution; and
a mixing apparatus positioned within the housing.

2. The conductivity sensor of claim 1 where the mixing apparatus is a magnetic stirring bar that is operable to magnetically couple to an external magnetic stirring plate.

3. The conductivity sensor of claim 1 further comprising a means for removing the resultant associated polymer from the interior of the conductivity sensor.

4. The conductivity sensor of claim 3 comprising a nozzle that is operable to introduce a non-aqueous solvent of the resultant associated polymer into the conductivity sensor.

5. The conductivity sensor of claim 4 where the non-aqueous solvent introducing nozzle is operable to direct the non-aqueous solvent onto the three-electrode set.

Assignees

• Saudi Arabian Oil Co

Inventors

• Akmal Naim
• Aleisa Rashed Mohammad
• Vaidya Milind M

Classifications

• G01N27/413 Primary

  Concentration cells using liquid electrolytes {measuring currents or voltages in voltaic cells} · CPC title

• G01N33/2835

  Specific substances contained in the oils or fuels · CPC title

• G01N27/301

  Reference electrodes · CPC title

• C10G31/08 Primary

  by treating with water · CPC title

• G01N27/4166

  measuring a particular property of an electrolyte · CPC title