Nano phosphatic hybrid geopolymeric corrosion resistant coating material and a method of preparation thereof

Patent metadata

Field	Value
Publication number	US-9938414-B2
Application number	US-201715461900-A
Country	US
Kind code	B2
Filing date	Mar 17, 2017
Priority date	Mar 18, 2016
Publication date	Apr 10, 2018
Grant date	Apr 10, 2018

Abstract

The present invention provides a nano phosphatic hybrid geopolymeric corrosion resistant coating material. The tailored precursor of corrosion resistant coating material is obtained by a process involving, together dry grinding of raw materials fly ash, sodium hydroxide, rice husk, tri calcium phosphate and cetyl trimethyl ammonium bromide optionally with sodium silicate, in solid powder form. The developed coating material obtained by adding water to tailored precursor contains nano sized phosphatic compounds of Cancrisilite (sodium aluminum carbonate silicate hydrate), quartz, mullite, heamatite, sodium aluminum silicate, Herschelite (sodium aluminum silicate hydrate), Sucrose, α D-Glucose, Native cellulose, and phenol, responsible for providing improved corrosion resistant properties and adhesion to the mild steel substrates. The geo-polymeric coating material is used as an anti-corrosive, heat resistant coating material on various materials e.g. mild steel substrates.

First claim

The invention claimed is:

1. A nano phosphatic hybrid geopolymeric coating material comprising tailored precursor wherein the tailored precursor is obtained by together mechanico-chemical dry grinding of fly ash in an amount of 70 to 90% by wt., solid sodium hydroxide in an amount of 10 to 15% by wt., rice husk in an amount of 1 to 5% by wt., tri calcium phosphate in an amount of 1 to 5% by wt., cetyl trimethyl ammonium bromide in an amount of 2 to 5% by wt., and optionally sodium silicate in an amount of 5 to 7% by wt. and,
said tailored precursor containing nano sized phosphatic compounds of Cancrisilite (sodium aluminium carbonate silicate hydrate), quartz, mullite, heamatite, sodium aluminium silicate, Herschelite (sodium aluminium silicate hydrate), sucrose, α-D-Glucose, native cellulose, and phenol.

2. The coating material of claim 1 , wherein the material is obtained by adding water to the tailored precursor.

3. The coating material of claim 1 , wherein the particle size of the nano phosphatic hybrid geopolymeric coating material is in the range of 37.1 to 53.7 nm.

4. The coating material of claim 1 , wherein the nano phosphatic hybrid geopolymeric coating material has an adhesion strength in the range of 1.0-2.5 MPa.

5. The coating material of claim 1 , wherein the nano phosphatic hybrid geopolymeric coating material has anti corrosive and heat resistant properties.

6. A corrosion and heat resistant substrate, wherein the substrate is coated with the coating material of claim 1 .

7. A process for making nano phosphatic hybrid geopolymeric coating material, the process comprising:
(i) mechanico-chemical dry grinding of:
(a) fly ash in an amount of 70 to 90% by wt.,
(b) solid sodium hydroxide in an amount of 10 to 15% by wt.,
(c) rice husk in an amount of 1 to 5% by wt.,
(d) tri calcium phosphate in an amount of 1 to 5% by wt.,
(e) cetyl trimethyl ammonium bromide in an amount of 2 to 5% by wt., and
(f) optionally sodium silicate in an amount of 5 to 7% by wt.; to obtain a tailored precursor; and
(ii) reacting the tailored precursor with water to obtain the coating material.

8. The process of claim 7 , wherein mechanico-chemical dry grinding is performed using a ball mill for a period ranging from 8 to 24 hours.

9. The process of claim 7 , wherein the tailored precursor is reacted with water in a ratio of 1:3 to obtain the coating material.

10. A nano phosphatic hybrid geopolymeric coating material as obtained by the process of claim 7 .

11. A corrosion and heat resistant coating material as obtained by the process of claim 7 .

12. A corrosion and heat resistant substrate, wherein the substrate is coated with the coating material of claim 10 .

13. A nano phosphatic hybrid geopolymeric coating material as obtained by reacting a tailored precursor with water, wherein the tailored precursor is obtained by together mechanico-chemical dry grinding of fly ash in an amount of 70 to 90% by wt., solid sodium hydroxide in an amount of 10 to 15% by wt., rice husk in an amount of 1 to 5% by wt., tri calcium phosphate in an amount of 1 to 5% by wt., cetyl trimethyl ammonium bromide in an amount of 2 to 5% by wt., and optionally sodium silicate in an amount of 5 to 7% by wt.

Assignees

• Council Scient Ind Res

Inventors

• Amritphale Sudhir Sitaram
• Mishra Deepti
• SINGH Archana
• Anshul Avneesh
• Das Satyabrata

Classifications

• C09D7/1266

  Chemistry & Metallurgy · mapped topic

• C09D7/1216

  Chemistry & Metallurgy · mapped topic

• C09D7/1233

  Chemistry & Metallurgy · mapped topic

• C08K13/02

  Organic and inorganic ingredients · CPC title

• C09D101/02

  Cellulose; Modified cellulose · CPC title