Propylene copolymers in soft thermoplastic blends

Patent metadata

Field	Value
Publication number	US-9938400-B2
Application number	US-10833608-A
Country	US
Kind code	B2
Filing date	Apr 23, 2008
Priority date	Apr 23, 2008
Publication date	Apr 10, 2018
Grant date	Apr 10, 2018

Abstract

Thermoplastic polyolefins (TPOs) and/or thermoplastic vulcanizates (TPVs) are blended with low molecular weight propylene-dominated copolymers to provide polymeric compositions with an improved balance between processability and toughness. The compositions have improved processability by facilitating the ease with which a TPO or TPV, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into articles.

First claim

What is claimed is:

1. A polymeric composition comprising:
from about 20 to about 50 wt %, based on the total weight of hydrocarbons in the polymeric composition, of a propylene-dominated copolymer component comprising a blend of two propylene-dominated copolymers made in the presence of a bridged metallocene catalyst, each propylene-dominated copolymer comprising from 5 to 35 wt % of comonomer derived units selected from the group consisting of ethylene and C 4 to C 20 olefins, and from 95 to 65 wt % propylene derived units, by weight of the respective copolymer,
wherein the propylene-dominated copolymer component has an MFR from 2000 to 7500 dg/min, a heat of fusion between 4.0 and 40 J/g, an isotactic triad fraction of at least 75 percent, a melting point greater than 35° C. and less than 75° C. a tacticity index (m/r) from 4 to 12 an intermolecular tacticity such that at least 75 wt % of the copolymer component is soluble in two adjacent temperature fractions of a thermal fractionation carried out in hexane in 8° C. increments, a reactivity ratio product r 1 r 2 of less than 1.5 and a molecular weight distribution Mw/Mn between 1.5 and 6;
wherein the two propylene-dominated copolymers differ by at least one of comonomer content, Mw, Mn, Tm, Hf, Mw/Mn, 2,1 insertions, 3,1 insertions, and tensile modulus, wherein the difference is 100% or greater; and
wherein the propylene-dominated copolymer component has less than 10000 ppm by weight of the copolymer component of a molecular degradation agent or its reaction products;
in intimate admixture therewith, from about 50 to about 80 wt %, based on the total weight of hydrocarbons in the polymeric composition, of a soft thermoplastic blend component comprising (1) a continuous thermoplastic matrix phase comprising a propylene homopolymer, propylene copolymer, or mixture thereof, having a melting point greater than about 110° C. and (2) a dispersed elastomeric phase selected from the group consisting of natural rubber, polyisoprene rubber, poly(styrene-co-butadiene) rubber (SBR), polybutadiene rubber (BR), poly(isoprene-co-butadiene) rubber (IBR), styrene-isoprene-butadiene rubber (SIBR), nitrile rubber, propylene oxide polymers, star-branched butyl rubber, halogenated star-branched butyl rubber, brominated butyl rubber, chlorinated butyl rubber, star-branched polyisobutylene rubber, star-branched brominated butyl (polyisobutylene/isoprene copolymer) rubber, poly(isobutylene-co-p-methylstyrene), halogenated poly(isobutylene-co-p-methylstyrene), and mixtures thereof, wherein the dispersed elastomeric phase is dispersed as particles having an average (mean) diameter of less than 10 μm within the continuous thermoplastic matrix phase, and where the soft thermoplastic blend component has a MFR less than 200 g/10 min,
wherein the polymeric composition has an MFR of at least 1 dg/min and less than or equal to 81.9 dg/min and a 1% secant flexural modulus of from 1 to 100 MPa.

2. The polymeric composition of claim 1 wherein the polymeric composition has a Tm within 10° C. of the soft thermoplastic blend component.

3. The polymeric composition of claim 1 wherein the polymeric composition has the MFR greater than the MFR of the soft thermoplastic blend component, a tensile toughness greater than the tensile toughness of the soft thermoplastic blend component, or both.

4. The polymeric composition of claim 1 having the MFR of greater than 5 dg/min and less than or equal to 81.9 dg/min and a Tc of greater than 75° C.

5. The polymeric composition of claim 1 wherein the composition has a Tc greater than 60° C.

6. The polymeric composition of claim 1 wherein the polymeric composition has one or more of the following characteristics: a) a tensile strength of less than 40 MPa; b) an Ultimate Elongation of greater than 30%; and c) a 300% modulus of less than 14 MPa.

7. The polymeric composition of claim 1 wherein the soft thermoplastic blend component comprises from about 55 to about 80 wt % of the composition and the propylene dominated copolymer component comprises from about 20 to about 45 wt % of the composition, based on the total weight of hydrocarbons in the polymeric composition.

8. The polymeric composition of claim 1 wherein at least one of the two propylene-dominated copolymers comprises at least 75 to 95 wt % of the propylene-derived units by weight of the respective propylene-dominated copolymer.

9. The polymeric composition of claim 1 wherein at least one of the two propylene-dominated copolymers comprises from about 5 wt % to about 20 wt % ethylene-derived units by weight of the respective propylene-dominated copolymer.

10. The polymeric composition of claim 1 wherein at least one of the two propylene-dominated copolymers comprises from about 0.5 to about 3 wt % diene derived units by weight of the respective propylene-dominated copolymer.

11. The polymeric composition of claim 1 wherein the propylene-dominated copolymer component comprises one or more of the following characteristics:
an elasticity in percent equal to or less than 0.935M +12 where M is the 500% tensile modulus in MPa and is at least 0.5 MPa;
a proportion of inversely inserted propylene units greater than 0.5%, based on 2,1insertion of propylene monomer in all propylene insertions;
a proportion of inversely inserted propylene units greater than 0.05%, based on 1,3 insertion of propylene monomer in all propylene insertions.

12. The polymeric composition of claim 1 wherein the continuous thermoplastic matrix phase of the soft thermoplastic blend component comprises an isotactic polypropylene or an isotactic random copolymer of propylene and from 0% to 9% wt by weight of the thermoplastic phase of an alpha-olefin, wherein the thermoplastic matrix phase has a melting point greater than about 120° C. and an MFR of from 0.1 to 150 dg/min.

13. The polymeric composition of claim 1 wherein the continuous thermoplastic matrix phase of the soft thermoplastic blend component comprises from about 1 to about 98 wt % based on the weight of the soft thermoplastic blend component of the propylene homopolymer, the propylene copolymer, or mixture thereof, wherein the propylene homopolymer, the propylene copolymer, or mixture thereof has a melting point greater than about 120° C., and wherein the propylene copolymer is selected from the group consisting of random propylene copolymers and propylene-styrene block copolymers.

14. The polymeric composition of claim 13 wherein the the propylene homopolymer, the propylene copolymer, or mixture thereof is selected from the group consisting of (a) isotactic polypropylene homopolymer, and (b) random copolymer of propylene and the comonomer selected from the group consisting of ethylene and C 4 to C 20 olefins, wherein the random copolymer contains at least 90% by weight of the random copolymer of the propylene derived units.

15. The polymeric composition of claim 1 wherein the elastomeric phase of the soft thermoplastic blend component is vulcanized.

16. A process for making the polymeric composition of claim 1 , comprising melt blending the propylene-dominated copolymer component and the soft thermoplastic blend component.

17. The process of claim 16 further comprising forming a film, fabric, fiber, sheet, molded object, extruded form or thermoformed article from the melt.

18. The polymeric composition obtained from the process of claim 16 .

19. The polymeric composition of claim 1 in a film, fabric, fiber, sheet, molded object, extruded form or thermoformed article.

20. A

Assignees

• Sahnoune Abdelhadi
• Datta Sudhin
• Tse Mun Fu
• Sims Charles L
• Coffey James N
• Jiang Peijun
• Exxonmobil Chemical Patents Inc

Inventors

• Sahnoune Abdelhadi
• Datta Sudhin
• Tse Mun Fu
• Sims Charles L
• Coffey James N
• Jiang Peijun

Classifications

• C08L23/14

  Copolymers of propene (C08L23/16 takes precedence) · CPC title

• C08L23/10 Primary

  Homopolymers or copolymers of propene · CPC title

• C08L23/142

  at least partially crystalline copolymers of propene with other olefins · CPC title

• C08L2666/04

  Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof · CPC title