Rubber composition

Patent metadata

Field	Value
Publication number	US-9938398-B2
Application number	US-201415031391-A
Country	US
Kind code	B2
Filing date	Oct 23, 2014
Priority date	Oct 24, 2013
Publication date	Apr 10, 2018
Grant date	Apr 10, 2018

Abstract

The invention relates to vulcanizable rubber compositions comprising at least the following components:
a) at least one functionalized polymer, b) at least one modified polybutadiene having a proportion of cis-1,4 units of >95% by weight and a proportion of 1,2-vinyl content of <1% by weight, the polybutadiene having been modified by means of sulphur chlorides after the polymerization, c) at least one silica, d) at least one further filler, e) at least one vulcanizing agent, f) at least one oil and g) optionally at least one further rubber additive.

First claim

What is claimed is:

1. Vulcanizable rubber composition comprising:
a) at least one functionalized polymer,
b) at least one modified polybutadiene having a proportion of cis-1,4 units of >95% by weight and a 1,2-vinyl content of <1% by weight, the polybutadiene having been modified by means of sulphur chlorides after the polymerization,
c) at least one silica,
d) at least one further filler,
e) at least one vulcanizing agent, and
f) at least one oil.

2. The vulcanizable rubber composition according to claim 1 , wherein the functionalized polymer comprises at least one of:
functionalized diene polymers, and
functionalized diene copolymers

obtained by copolymerization of dimes with vinylaromatic monomers.

3. The vulcanizable rubber composition according to claim 1 , wherein the functionalized polymer is at least one of: a polybutadiene, a polyisoprene, a butadiene-isoprene copolymer, a butadiene-styrene copolymer, an isoprene-styrene copolymer and a butadiene-isoprene-styrene terpolymer.

4. The vulcanizable rubber composition according to claim 1 , wherein:
the functionalized polymer comprises end group-functionalized butadiene-styrene copolymers prepared by solution polymerization, wherein the end group-functionalized butadiene-styrene copolymers have Mooney viscosities (ML 1+4 (100° C.)) of 30 to 150 Mooney units, mean molar masses (number-average, Mn) of 100,000 to 1,000,000 g/mol, and glass transition temperatures of −110° C. to 0° C.; and
the modified polybutadiene is obtained by solution polymerization in the presence of at least one inert organic solvent and in the presence of at least one catalyst based on neodymium compounds within a temperature range of −20° C. to 150° C., stopping the polymerization by adding protic compounds to produce polybutadiene, and modifying the polybutadiene with sulphur chlorides to increase the Mooney viscosity thereof, wherein the polybutadiene, before modification with the sulphur chlorides has a Mooney viscosity (ML 1+4 at 100° C.) of at least 20 MU, and the modified polybutadiene after the modification with the sulphur chlorides has a Mooney viscosity (ML 1+4 at 100° C.) of at least 30 MU.

5. The vulcanizable rubber composition according to claim 4 , wherein:
the polybutadiene, before modification with the sulphur chlorides has a Mooney viscosity (ML 1+4 at 100° C.) of at least 40 MU, and the modified polybutadiene after the modification with the sulphur chlorides has a Mooney viscosity (ML 1+4 at 100° C.) of 60-80 MU; and
the composition comprises:
a) 50 to 90 parts by weight of the at least one functionalized solution butadiene-styrene copolymer (SSBR),
b) 10-50 parts by weight of the at least one modified polybutadiene (NdBR),
c) 50-120 parts by weight of the at least one silica,
d) 2-25 parts by weight of at least one further filler,
e) 1-5 parts by weight of at least one vulcanizing agent, and
f) 5-50 parts by weight of at least one oil,

where the parts by weight figures for components c)-f) are each based on 100 parts by weight of rubber (sum total of a) and b)).

6. The vulcanizable rubber composition according to claim 1 , wherein the functionalized polymer comprises end group-functionalized butadiene-styrene copolymers prepared by solution polymerization.

7. The vulcanizable rubber composition according to claim 6 , wherein the end group-functionalized butadiene-styrene copolymers have Mooney viscosities (ML 1+4 (100° C.)) of 10 to 200 Mooney units.

8. The vulcanizable rubber composition according to claim 7 , wherein the end group-functionalized butadiene-styrene copolymers have mean molar masses (number-average, Mn) of 10,000 to 2,000,000 g/mol.

9. The vulcanizable rubber composition according to claim 8 , wherein the end group-functionalized butadiene-styrene copolymers have glass transition temperatures of −110° C. to 20° C.

10. The vulcanizable rubber composition according to claim 1 , wherein the modified polybutadiene is obtained by solution polymerization in the presence of at least one inert organic solvent and in the presence of at least one catalyst based on neodymium compounds within a temperature range of −20° C. to 150° C., stopping the polymerization by adding protic compounds, and modifying the polymer with sulphur chlorides to increase the Mooney viscosity thereof.

11. The vulcanizable rubber composition according to claim 10 , wherein, prior to modifying the polymer with sulphur chlorides, the sulphur chlorides, are treated with a carboxylic add, fatty add and/or fatty add ester.

12. The vulcanizable rubber composition according to claim 11 , wherein the sulphur chlorides are disulphur dichloride, sulphur chloride, sulphur bromide, sulphur dichloride, thionyl chloride, disulphur dibromide and/or thionyl bromide.

13. The vulcanizable rubber composition according to claim 12 , wherein the modified polybutadiene, after modification with the sulphur chlorides, has a Mooney viscosity (ML 1+4 at 100° C.) at least 50% greeter than the Mooney viscosity (ML 1+4 at 100° C.) of the polybutadiene prior to modification with the sulphur chlorides.

14. The vulcanizable rubber composition according to claim 13 , wherein the polybutadiene, before modification with the sulphur chlorides has a Mooney viscosity (ML 1+4 at 100° C.) of at least 20 MU, and the modified polybutadiene after the modification with sulphur chlorides has a Mooney viscosity (ML 1+4 at 100° C.) of at least 30 MU, and a gel content less than 1% by weight.

Assignees

• Arlanxeo Deutschland Gmbh

Inventors

• Hardy David John
• Kloppenburg Heike
• Lucassen Alex
• Steinhauser Norbert
• Zhang Yan

Classifications

• C08L15/00 Primary

  Compositions of rubber derivatives (C08L11/00, C08L13/00 take precedence) · CPC title

• C08L9/00 Primary

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• B60C1/00 Primary

  Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition · CPC title

• C08L9/06

  Copolymers with styrene · CPC title

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title