Hematite manufacturing process and hematite manufactured by same

Patent metadata

Field	Value
Publication number	US-9938158-B2
Application number	US-201414898710-A
Country	US
Kind code	B2
Filing date	May 15, 2014
Priority date	Jun 17, 2013
Publication date	Apr 10, 2018
Grant date	Apr 10, 2018

Abstract

Magnesium oxide produced by a process is used as a neutralizing agent for preliminary neutralization treatment of a leached slurry obtained by leaching a nickel oxide ore at a high temperature and pressure with sulfuric acid added. A neutralizing agent is added to a leachate, obtained by leaching a nickel oxide ore, to separate impurities, and a sulfurizing agent is added to the resulting neutralized solution to obtain nickel and cobalt sulfides, followed by separating the sulfurized solution; discharge waste water, obtained by adding a neutralizing agent to the sulfurized solution to separate aluminum and manganese, is concentrated to precipitate and separate calcium contained in the discharge waste water as calcium sulfate; the resulting solution is concentrated to precipitate magnesium in the solution as magnesium sulfate; the magnesium sulfate is roasted with a reducing agent to obtain magnesium oxide and a sulfurous gas; and the magnesium oxide is washed.

First claim

The invention claimed is:

1. A process for producing hematite comprising
(a) preparing a slurry wherein a sulfuric acid solution is added to a nickel oxide ore that contains cobalt and other metals,
(b) leaching nickel and cobalt in the slurry at a high temperature and high pressure,
(c) adding magnesium oxide as a first neutralizing agent to the slurry to adjust pH,
(d) separating the slurry into a leachate containing nickel and cobalt and leached residue as hematite,
(e) recovering the hematite,
(f) adding a second neutralizing agent to the leachate to separate impurities, and adding a sulfurizing agent to the resulting neutralized solution to obtain a sulfurized solution and sulfides of nickel and cobalt, and separating the sulfurized solution,
(g) adding a third neutralizing agent to the sulfurized solution to separate aluminum and manganese from the sulfurized solution and then concentrating the sulfurized solution to an end point at which the specific gravity of the concentrated sulfurized solution reaches 1.1 to 1.3 g/cm 3 , thereby to precipitate and separate calcium as calcium sulfate and produce a separated solution,
(h) crystallizing magnesium sulfate from the separated solution of step (g) and separating the magnesium sulfate,
(i) roasting the magnesium sulfate with a reducing agent producing magnesium oxide and a sulfurous acid gas, and
(j) washing the magnesium oxide from step (i), and recycling the magnesium oxide as an addition to the first neutralization agent in step (c).

2. The process for producing hematite according to claim 1 , wherein the end point of concentration of the sulfurized solution in step (g) is a point at which the specific gravity of the concentrated solution reaches 1.25 g/cm 3 .

3. The process for producing hematite according to claim 1 , wherein concentration of the solution in step (g) and in step (h) is performed by natural drying.

4. The process for producing hematite according to claim 1 , wherein the sulfurized solution is a filtrate obtained by adding the third neutralizing agent to the sulfurized solution to adjust pH to 7.0 to 8.5, and then performing solid-liquid separation.

5. The process for producing hematite according to claim 1 , wherein at least one of coke, coal, charcoal, bamboo charcoal and waste activated carbon is used in step (i).

6. The process for producing hematite according to claim 1 , wherein the sulfurous acid gas generated in step (i) is transformed into sulfuric acid and the resulting sulfuric acid is used for the leaching of the nickel oxide ore at a high temperature and high pressure repeatedly.

7. The process for producing hematite according to claim 1 , wherein the crystals of magnesium sulfate obtained in step (h) are dissolved by adding water thereto and the resulting solution is concentrated again in the magnesium crystallization step repeatedly.

8. The process for producing hematite according to claim 1 , wherein hematite has a sulfur grade of less than 1% by weight and a calcium grade of less than 1% by weight, and is used as an ironmaking raw material.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Ozaki Yoshitomo
• Ohara Hideki

Classifications

• C22B23/043

  Sulfurated acids or salts thereof · CPC title

• C01B17/501

  by reduction of sulfur compounds · CPC title

• C01F11/46

  Sulfates (dehydration of gypsum {for the production of calcium sulfate cements} C04B11/02) · CPC title

• C22B23/0461

  by chemical methods · CPC title

• C01F5/40

  Magnesium sulfates (double sulfates of magnesium with sodium or potassium C01D5/12, with other alkali metals {C01D15/00}, C01D17/00) · CPC title