Process for producing synthesis gas and electrical energy

Patent metadata

Field	Value
Publication number	US-9938144-B2
Application number	US-201514827496-A
Country	US
Kind code	B2
Filing date	Aug 17, 2015
Priority date	Aug 19, 2014
Publication date	Apr 10, 2018
Grant date	Apr 10, 2018

Abstract

The invention relates to a process for producing synthesis gas, in which carbon and hydrogen are obtained from hydrocarbon by thermal decomposition. At least a portion of the carbon obtained by the thermal decomposition is reacted, and at least a portion of the hydrogen obtained is reacted with carbon dioxide by a reverse water-gas shift reaction to give carbon monoxide and water. Carbon obtained by the thermal hydrocarbon decomposition is used as fuel in a power plant operation wherein the carbon is combusted to produce electrical power, and carbon dioxide formed in the combustion of the carbon is used in the reverse water-gas shift reaction.

First claim

The invention claimed is:

1. A process for producing synthesis gas, said process comprising:
subjecting a hydrocarbon feedstock containing methane to thermal decomposition to obtain carbon and hydrogen,
using at least a portion of the carbon obtained by said thermal decomposition as fuel in a power plant operation to produce electrical power wherein said at least a portion of the carbon is combusted to produce a carbon dioxide-containing flue gas,
subjecting the carbon dioxide-containing flue gas to a chemical and/or physical gas scrubbing operation to yield carbon dioxide and a residual gas,
reacting at least a portion of the hydrogen obtained by said thermal decomposition with at least a portion of the obtained carbon dioxide obtained from said scrubbing operation in a reverse water-gas shift reaction to produce a synthesis gas containing carbon monoxide and water, and converting said synthesis gas to methanol and/or dimethyl ether and/or hydrocarbons wherein waste heat is generated, and using at least a portion of the waste heat generated in the conversion of said synthesis gas in said scrubbing operation,
wherein the thermal decomposition is conducted in the presence of a solid granular material,
wherein the thermal energy required for synthesis gas production is generated by oxidation or partial oxidation of a fuel comprising hydrocarbons and/or hydrogen and/or by electrical power.

2. The process according to claim 1 , wherein a portion of the waste heat ( 12 ) generated in the conversion of said synthesis gas is used in a power plant operation for production of electrical power.

3. The process according to claim 1 , wherein said thermal decomposition is conducted in a first reaction zone (Z 1 ) and hydrogen formed during said thermal decomposition is passed out of the first reaction zone (Z 1 ) into a second reaction zone (Z 2 ) where said hydrogen is reacted with carbon dioxide in said reverse water-gas shift reaction to produce water and carbon monoxide.

4. The process according to claim 3 , wherein energy required for said thermal decomposition in said first reaction zone (Z 1 ) is supplied from said second reaction zone (Z 2 ).

5. The process according to claim 3 , wherein hydrocarbon material that is undecomposed or incompletely decomposed in said first reaction zone (Z 1 ) is passed into said second reaction zone (Z 2 ) and reacted therein with water to produce hydrogen and carbon dioxide.

6. The process according to claim 3 , wherein said first reaction zone (Z 1 ) and said second reaction zone (Z 2 ) are connected by means of a moving bed (W) containing said solid granular material and said moving bed moves from said second reaction zone (Z 2 ) to said first reaction zone (Z 1 ).

7. The process according to claim 6 , wherein gas discharged from said second reaction zone (Z 2 ) is conducted in countercurrent flow to said moving bed (W) and is cooled down by direct heat exchange with said moving bed.

8. The process according to claim 6 , wherein said hydrocarbon material ( 2 ) is conducted through said first reaction zone (Z 1 ) in countercurrent to said moving bed (W) and said hydrocarbon material ( 2 ) is heated up by direct heat exchange with said moving bed.

9. The process according to claim 6 , wherein carbon deposited on said solid granular material is separated (A) downstream of said first reaction zone (Z 1 ) and removed from said moving bed (W).

10. The process according to claim 6 , wherein said solid granular materials comprises corundum (Al 2 O 3 ), quartz glass (SiO 2 ), mullite (Al 2 O 3 .SiO 2 ), cordierite ((Mg,Fe) 2 (Al 2 Si)[Al 2 Si 4 O 18 ]), steatite (SiO 2 .MgO.Al 2 O 3 ), coal, coke or carbon produced in by thermal hydrocarbon decomposition, or combinations thereof.

11. The process according to claim 6 , wherein said solid granular material is a carbon-rich granular material formed from solid grains having at least 95% by weight.

12. The process according to claim 11 , wherein said solid grains have an equivalent diameter of 0.05 to 50 mm.

13. The process according to claim 6 , wherein said solid granular material has a porosity of 0.1 to 0.85 ml/ml.

14. The process according to claim 6 , wherein said solid granular material is macroporous and has a mean pore radius of 0.01 to 50 μm.

15. The process according to claim 6 , wherein said solid granular material has a specific surface area of 0.02 to 100 m 2 /g.

Assignees

• Linde Ag
• Basf Se

Inventors

• Maass Hans-Jurgen
• Machhammer Otto
• Bode Andreas
• Kolios Grigorios

Classifications

• C01B3/28 Primary

  using moving solid particles, e.g. fluidised bed technique · CPC title

• C10J3/18

  using electricity · CPC title

• C01B2203/1235

  Hydrocarbons · CPC title

• C01B2203/061

  Methanol production · CPC title

• C01B32/40

  Carbon monoxide · CPC title