Positive electrode for lithium secondary battery, manufacturing method thereof, and lithium secondary battery

Patent metadata

Field	Value
Publication number	US-9935313-B2
Application number	US-201715409566-A
Country	US
Kind code	B2
Filing date	Jan 19, 2017
Priority date	Sep 9, 2011
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

Occlusion and release of lithium ion are likely to one-dimensionally occur in the b-axis direction of a crystal in a lithium-containing composite oxide having an olivine structure. Thus, a positive electrode in which the b-axes of lithium-containing composite oxide single crystals are oriented vertically to a surface of a positive electrode current collector is provided. The lithium-containing composite oxide particles are mixed with graphene oxide and then pressure is applied thereto, whereby the rectangular parallelepiped or substantially rectangular parallelepiped particles are likely to slip. In addition, in the case where the rectangular parallelepiped or substantially rectangular parallelepiped particles whose length in the b-axis direction is shorter than those in the a-axis direction and the c-axis direction are used, when pressure is applied in one direction, the b-axes can be oriented in the one direction.

First claim

What is claimed is:

1. A positive electrode for a lithium secondary battery comprising:
a positive electrode current collector; and
a positive electrode active material layer over the positive electrode current collector,
wherein the positive electrode active material layer includes:
a plurality of active material particles; and
a graphene oxide,
wherein the plurality of active material particles are a lithium-containing composite oxide having an olivine structure, and

wherein a peak intensity ratio of a (020) diffraction to a (101) diffraction of the lithium-containing composite oxide having the olivine structure in a X-ray diffraction spectrum of the positive electrode active material layer is greater than or equal to 4.5 and less than or equal to 5.5.

2. The positive electrode for a lithium secondary battery according to claim 1 , wherein the lithium-containing composite oxide having the olivine structure is lithium iron phosphate.

3. The positive electrode for a lithium secondary battery according to claim 1 , wherein the plurality of active material particles are rectangular parallelepiped or substantially rectangular parallelepiped particles.

4. The positive electrode for a lithium secondary battery according to claim 1 , wherein the plurality of active material particles are rectangular parallelepiped or substantially rectangular parallelepiped single crystal particles.

5. The positive electrode for a lithium secondary battery according to claim 4 , wherein b-axis of the rectangular parallelepiped or substantially rectangular parallelepiped single crystal particles are oriented vertically to a surface of the positive electrode current collector.

6. The positive electrode for a lithium secondary battery according to claim 4 , wherein length in a b-axis direction of the rectangular parallelepiped or substantially rectangular parallelepiped single crystal particles are shorter than lengths in an a-axis direction and a c-axis direction of the rectangular parallelepiped or substantially rectangular parallelepiped single crystal particles.

7. The positive electrode for a lithium secondary battery according to claim 1 , wherein the graphene oxide is multilayer graphene oxide including 2 to 100 graphene oxide sheets.

8. The positive electrode for a lithium secondary battery according to claim 1 , wherein one of surface of the graphene oxide is contact with at least two of the plurality of active material particles, and
wherein another of surface of the graphene oxide is contact with the other of at least two of the plurality of active material particles.

9. The positive electrode for a lithium secondary battery according to claim 1 , wherein the graphene oxide is reduced.

10. The positive electrode for a lithium secondary battery according to claim 5 , wherein a number of rectangular parallelepiped or substantially rectangular parallelepiped particle having the b-axis thereof oriented vertically to the surface of the positive electrode current collector is larger than a number of rectangular parallelepiped or substantially rectangular parallelepiped particle oriented in other axes directions.

11. A lithium secondary battery comprising:
a negative electrode;
an electrolyte solution; and
the positive electrode for a lithium secondary battery according to claim 1 .

12. A positive electrode for a lithium secondary battery comprising:
a positive electrode current collector; and
a positive electrode active material layer over the positive electrode current collector,
wherein the positive electrode active material layer includes:
a plurality of active material particles; and
a graphene oxide,
wherein the plurality of active material particles are rectangular parallelepiped or substantially rectangular parallelepiped single crystal particles, and

wherein a peak intensity ratio of a (020) diffraction to a (101) diffraction of the plurality of active material particles in a X-ray diffraction spectrum of the positive electrode active material layer is greater than or equal to 4.5 and less than or equal to 5.5.

13. The positive electrode for a lithium secondary battery according to claim 12 , wherein the plurality of active material particles are a lithium-containing composite oxide having an olivine structure.

14. The positive electrode for a lithium secondary battery according to claim 13 , wherein the lithium-containing composite oxide having the olivine structure is lithium iron phosphate.

15. The positive electrode for a lithium secondary battery according to claim 12 , wherein b-axis of the plurality of active material particles are oriented vertically to a surface of the positive electrode current collector.

16. The positive electrode for a lithium secondary battery according to claim 12 , wherein length in a b-axis direction of the plurality of active material particles are shorter than lengths in an a-axis direction and a c-axis direction of the plurality of active material particles.

17. The positive electrode for a lithium secondary battery according to claim 12 , wherein the graphene oxide is multilayer graphene oxide including 2 to 100 graphene oxide sheets.

18. The positive electrode for a lithium secondary battery according to claim 12 , wherein one of surface of the graphene oxide is contact with at least two of the plurality of active material particles, and
wherein another of surface of the graphene oxide is contact with the other of at least two of the plurality of active material particles.

19. The positive electrode for a lithium secondary battery according to claim 12 , wherein the graphene oxide is reduced.

20. A lithium secondary battery comprising:
a negative electrode;
an electrolyte solution; and
the positive electrode for a lithium secondary battery according to claim 12 .

Assignees

• Semiconductor Energy Lab

Inventors

• Miwa Takuya
• Inoue Nobuhiro
• Nomoto Kuniharu
• Momo Junpei

Classifications

• H01M4/1397

  of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M4/0435

  Rolling or calendering · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2004/028

  Positive electrodes · CPC title