Coated metal material and method of production of same

Patent metadata

Field	Value
Publication number	US-9933550-B2
Application number	US-99880109-A
Country	US
Kind code	B2
Filing date	Dec 2, 2009
Priority date	Dec 3, 2008
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

Disclosed is a coated metallic material having a high total light reflectance and excellent moldability. Also disclosed is a method for producing the coated metallic material. Further disclosed is a molded coated metallic article. The coated metallic material is characterized by comprising a coating layer having at least three layers composed of a primer layer, an intercoating layer and a top layer, wherein the intercoating layer contains rutile-type titanium oxide in an amount of 35 to 70% in terms of a solid material concentration by volume and also contains a polyester resin (A) having a number average molecular weight of 19000 to 28000 as a binder resin component, and wherein the polyester resin (A) is contained in the binder at a concentration of 20 mass % or more. In the coated metallic material, an interface between the intercoating layer and the top layer has a center-line average roughness (Ra) of 0.8 μm or more, so that the adhesion between the intercoating layer and the top layer can be further improved and the diffusion reflectance can also be further improved.

First claim

The invention claimed is:

1. A coated metal material having at least three coating layers of a primer layer, middle coat layer, and top layer at least at part of a surface of the metal material, the coated metal material being produced by applying a liquid coating onto a metal material,
wherein said middle coat layer contains, as a pigment, only rutile titanium oxide in a solid volume concentration of 35 to 70%, said middle coat layer uses as a binder resin ingredient a polyester resin A with a number average molecular weight of 19000 to 28000, and a concentration of the polyester resin A in said binder resin ingredient is 20 mass % or more, and a centerline average roughness Ra of an interface of said middle coat layer and said top layer is 2.0μm or more,
wherein said middle coat layer has a thickness of 30 to 110 μm, and contains pores in a volume ratio of 0.02 to 1.1 times the solid content,
wherein said primer layer contains a binder resin, and further contains, as a pigment, only rutile titanium oxide in a solid volume concentration of 20 to 35%, and has a thickness of 12 to 22 μm, and
wherein said top layer contains, as a pigment, only rutile titanium oxide in a solid volume concentration of 20 to 35%, and has a thickness of 12 to 22 μm.

2. The coated metal material as set forth in claim 1 , wherein the binder resin ingredient of said middle coat layer contains said polyester resin A and, further, a polyester resin B with a number average molecular weight of 2000 to 6000 and a hydroxyl value of 20 or more and the polyester resin A and the polyester resin B has a mass ratio of 0.25≤polyester resin B/polyester resin A≤4.

3. The coated metal material as set forth in claim 2 , wherein said number average molecular weight of the polyester resin B in the binder resin ingredient of the middle coat layer is 3000 to 4500.

4. The coated metal material as set forth in claim 2 , wherein said hydroxyl value of the polyester resin B in the binder resin ingredient of the middle coat layer is 40 to 200.

5. The coated metal material as set forth in claim 2 , wherein said mass ratio of the polyester resin A and the polyester resin B is 0.65≤polyester resin B/polyester resin A≤1.5.

6. The coated metal material as set forth in claim 1 , wherein said rutile titanium oxide contained in the middle coat layer has a solid volume concentration of 55 to 65%.

7. The coated metal material as set forth in claim 1 , wherein said rutile titanium oxide contained in the middle coat layer has an average particle size of 200 to 400 nm.

8. The coated metal material as set forth in claim 7 , wherein said rutile titanium oxide contained in the middle coat layer has an average particle size of 250 to 350 nm.

9. The coated metal material as set forth in claim 1 , wherein said polyester resin A has a number average molecular weight of 20000 to 23000.

10. The coated metal material as set forth in claim 1 , wherein said concentration of the polyester resin A in the binder resin ingredient of the middle coat layer is 40 to 60 mass %.

11. The coated metal material as set forth in claim 1 , wherein said middle coat layer contains, in addition to the rutile titanium oxide, particles of a larger particle size and lower refractive index than the rutile titanium oxide.

12. The coated metal material as set forth in claim 11 , wherein said particle size of the particles of a lower refractive index is 1 to 10 μm.

13. The coated metal material as set forth in claim 12 , wherein said particle size of the particles of a lower refractive index is 4 to 7 μm.

14. The coated metal material as set forth in claim 11 , wherein a refractive index difference of said particles of a lower refractive index and said rutile titanium oxide is 0.5 or more.

15. The coated metal material as set forth in claim 14 , wherein said refractive index difference is 1 or more.

16. The coated metal material as set forth in claim 1 , wherein said middle coat layer contains pores in a volume ratio of 0.5 to 0.95 times the solid content.

17. The coated metal material as set forth in claim 1 , wherein said primer layer uses as a binder resin ingredient the polyester resin A with a number average molecular weight of 19000 to 28000 and a concentration of the polyester resin A in said binder resin ingredient is 80 mass % or more.

18. The coated metal material as set forth in claim 17 , wherein the number average molecular weight of the polyester resin A in the binder resin ingredient of said primer layer is 20000 to 23000.

19. The coated metal material as set forth in claim 17 , wherein the concentration of the polyester resin A in said binder resin ingredient of said primer layer is 90 to 100 mass %.

20. The coated metal material as set forth in claim 1 , wherein said solid volume concentration of the rutile titanium oxide of the primer layer is 22 to 28%.

21. The coated metal material as set forth in claim 1 , wherein said top layer uses as a binder resin ingredient the polyester resin A with a number average molecular weight of 19000 to 28000 and the concentration of the polyester resin A in said binder resin ingredient is 80 mass % or more.

22. The coated metal material as set forth in claim 21 , wherein the number average molecular weight of the polyester resin A in the binder resin ingredient of said top layer is 20000 to 23000.

23. The coated metal material as set forth in claim 21 , wherein the concentration of the polyester resin A in said binder resin ingredient of said top layer is 90 to 100 mass %.

24. The coated metal material as set forth in claim 1 , wherein the solid volume concentration of the rutile titanium oxide of said top layer is 22 to 28%.

25. The coated metal material as set forth in claim 1 , wherein said top layer contains a matting agent in a solid volume concentration of 3 to 15%.

26. The coated metal material as set forth in claim 25 , wherein the solid volume concentration of said matting agent is 5 to 12%.

27. The coated metal material as set forth in claim 25 , wherein said matting agent is silica of a particle size of 3 to 9 μm.

28. The coated metal material as set forth in claim 27 , wherein the particle size of said silica is 4 to 7 μm.

29. The coated metal material as set forth in claim 1 , wherein a boundary part of said middle coat layer and said top layer has a mixed layer of ingredients in said middle coat layer and ingredients in said top layer mixed together and said mixed layer has a thickness of 3 to 12 μm.

30. The coated metal material as set forth in claim 29 , wherein the thickness of said mixed layer is 6 to 12 μm.

31. The coated metal material as set forth in claim 1 , wherein a filtered center line waviness W CA of outermost surface of the coating layer is 2 μm or less.

32. The coated metal material as set forth in claim 31 , wherein said W CA is 0.5 μm or less.

33. The coated metal material as set forth in claim 1 , wherein an outermost coating film layer of said coating layers contains a silicone resin or fluorocarbon resin.

34. The coated metal material as set forth in claim 1 , wherein an outermost coating film layer of said coating layers has a —Si—O—Si-bond in a resin skeleton forming the coating film.

35. The coated metal material as set forth in clai

Assignees

• Hosokawa Tomoaki
• Ueda Kohei
• Inoue Ikuya
• Obara Yuki
• Nippon Steel & Sumitomo Metal Corp

Inventors

• Hosokawa Tomoaki
• Ueda Kohei
• Inoue Ikuya
• Obara Yuki

Classifications

• Y10T428/259

  Silicic material · CPC title

• Y10T428/31663

  As siloxane, silicone or silane · CPC title

• Y10T428/256

  Heavy metal or aluminum or compound thereof · CPC title

• Y10T428/31678

  Of metal · CPC title

• C09D167/00

  Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain (based on polyester-amides C09D177/12; based on polyester-imides C09D179/08); Coating compositions based on derivatives of such polymers · CPC title