Method for metal electrowinning and an electrowinning cell

Patent metadata

Field	Value
Publication number	US-9932683-B2
Application number	US-201414895260-A
Country	US
Kind code	B2
Filing date	May 30, 2014
Priority date	Jun 5, 2013
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

The invention relates to a method for electrowinning a metal from an electrolyte in an electrowinning cell that comprises an electrolysis tank, one or more anodes, and one or more cathodes, which anodes and cathodes are housed in the electrolysis tank. The method comprises supplying sulfur dioxide to the anode to depolarize the anode process and to reduce the energy consumption of the electrowinning cell.

First claim

The invention claimed is:

1. A method for electrowinning a metal from an electrolyte in an electrowinning cell that comprises an electrolysis tank, one or more anodes, and one or more cathodes, which anodes and cathodes are housed in the electrolysis tank, the method comprising supplying sulfur dioxide to the anode to depolarize the anode process and to reduce the energy consumption of the electrowinning cell, wherein housing each anode in an anode bag of its own and introducing sulfur dioxide into the lower part of the anode bag which anode bag comprises a diaphragm cloth bag or an ion exchange membrane.

2. The method according to claim 1 , further comprising introducing sulfur dioxide in gas form into the electrolysis tank in the vicinity of the anode.

3. The method according to claim 1 , further comprising dissolving sulfur dioxide into an electrolyte before introducing said electrolyte into the electrolysis tank in the vicinity of the anode.

4. The method according to claim 1 , wherein the anodes are comprised of platinum coated titanium mesh.

5. The method according to claim 1 , wherein the anodes are comprised of gold coated titanium mesh.

6. The method according to claim 1 , wherein the anodes are PbCaSn anodes spray-coated with platinum powder.

7. The method according to claim 1 , wherein the anodes are PbCaSn anodes spray-coated with gold powder.

8. The method according to claim 1 , wherein the anodes are stainless steel anodes with platinum coating.

9. The method according to claim 1 , wherein the anodes are stainless steel anodes with gold coating.

10. An electrowinning cell for electrowinning a metal from an electrolyte, comprising an electrolysis tank, one or more anodes and one or more cathodes, which anodes and cathodes are housed in the electrolysis tank, and means for supplying sulfur dioxide to the anode to depolarize the anode process, wherein each anode is housed in an anode bag of its own and the sulfur dioxide is supplied into the lower part of the anode bag which anode bag comprises a diaphragm cloth bag or an ion exchange membrane.

11. The electrowinning cell according to claim 10 , wherein the means for supplying sulfur dioxide into the electrolysis tank comprises a manifold arranged to introduce sulfur dioxide into the vicinity of each anode.

12. The electrowinning cell according to claim 10 , wherein the anode comprises a titanium mesh provided with a platinum coating.

13. The electrowinning cell according to claim 12 , wherein the titanium mesh comprises 0.10-0.50 g/cm 2 titanium.

14. The electrowinning cell according to claim 12 , wherein the titanium mesh comprises about 0.15 g/m 2 of titanium.

15. The electrowinning cell according to claim 10 , wherein the anode comprises a titanium mesh provided with a gold coating.

16. The electrowinning cell according to claim 10 , wherein the anode is a PbCaSn anode spray-coated with platinum powder.

17. The electrowinning cell according to claim 10 , wherein the anode is a PbCaSn anode spray-coated with gold powder.

18. The electrowinning cell according to claim 10 , wherein the anode is a stainless steel anode coated with platinum.

19. The electrowinning cell according to claim 10 , wherein the anode is stainless steel anode coated with gold.

Assignees

• Outotec Finland Oy

Inventors

• Barker Michael H
• Virtanen Henri K

Classifications

• C25C1/12

  of copper · CPC title

• C25C7/06 Primary

  Operating or servicing · CPC title

• C25C7/02

  Electrodes (consumable anodes for the refining the metals C25C1/00 - C25C5/00); Connections thereof · CPC title

• C25C7/00

  Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells (for the production of aluminium C25C3/06 - C25C3/22) · CPC title

• C25C1/16

  of zinc, cadmium or mercury · CPC title