Adhesion promoter for solventborne primer surfacers

Patent metadata

Field	Value
Publication number	US-9932483-B2
Application number	US-201415104771-A
Country	US
Kind code	B2
Filing date	Dec 17, 2014
Priority date	Dec 17, 2013
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

The present invention relates to a solventborne primer surfacer which comprises at least one additive preparable by reacting at least one alpha,omega-hydroxy-functionalized oligoester which possesses an OH number of 30 to 160 mg KOH/g, a theoretical carbon-carbon double bond content of 1 to 2.5 mmol/g, a number-average molecular weight of 1000 to 3000 g/mol, and a weight-average molecular weight of 2800 to 10 000 g/mol, and at least one alkoxysilane which possesses an OH-reactive functional group, the sum of the weight percentage fractions of all additives of the invention being 0.5 to 10 wt %, based on the total amount of the solventborne primer surfacer. The present invention further relates to a process for producing multicoat paint systems, and to multicoat paint systems producible by means of said process. The invention further relates to the use of the additive identified above in solventborne primer surfacers for improving adhesion.

First claim

The invention claimed is:

1. A solventborne primer surfacer comprising at least one organic solvent and at least one additive preparable by reacting
(a) at least one alpha,omega-hydroxy-functionalized oligoester which possesses the following structural formula (I):

where
the radicals R 1 independently of one another are a linear or cyclic alkylene radical,
the radicals R 2 independently of one another are an alkylene or alkenylene radical, the ratio of alkylene to alkenylene radicals being such that the alpha,omega-hydroxy-functionalized oligoester of the structural formula (I) possesses a theoretical carbon-carbon double bond content of 1 to 2.5 mmol/g, and
the index m is such that the number-average molecular weight of the alpha,omega-hydroxy-functionalized oligoester of the structural formula (I) is 1000 to 3000 g/mol,
wherein the alpha,omega-hydroxy-functionalized oligoester possesses an OH number of 30 to 160 mg KOH/g, and a weight-average molecular weight of 2800 to 10 000 g/mol, and
(b) at least one alkoxysilane of the structural formula (II)
A-R—Si(R′) x (OR″) 3-x

where
A is an OH-reactive functional group,
R is an aliphatic radical having 2 to 12 carbon atoms, a cycloaliphatic radical having 3 to 12 carbon atoms, an aromatic radical having 6 to 12 carbon atoms, or an araliphatic radical having 7 to 18 carbon atoms,
the radical R′ is a C 1 to C 12 alkyl radical,
R″ is a methyl or ethyl radical, and
x is 0 to 2,
with the proviso that at least 90 mol % of all the OH groups of the alpha,omega-hydroxy-functionalized oligoester have been reacted with an OH-reactive functional group A, and,
the sum of the weight percentage fractions of all additives of the invention is 0.5 to 10 wt %, based on the total amount of the solventborne primer surfacer.

2. The solventborne primer surfacer as claimed in claim 1 , wherein the alpha,omega-hydroxy-functionalized oligoester is prepared using at least one saturated linear aliphatic dicarboxylic acid or anhydride thereof, at least one monounsaturated linear aliphatic dicarboxylic acid or anhydride thereof, and at least one saturated aliphatic diol.

3. The solventborne primer surfacer of claim 1 , wherein the sum of the weight percentage fractions of all the additives is 1.5 to 7.5 wt %, based on the total amount of the solventborne primer surfacer.

4. The solventborne primer surfacer as claimed in claim 1 , wherein the radicals R 1 are linear alkylene radicals having 6 to 10 carbon atoms.

5. The solventborne primer surfacer of claim 1 , wherein the radicals R 2 are linear alkylene radicals having 4 to 8 carbon atoms or linear alkenylene radicals having 2 to 4 carbon atoms.

6. The solventborne primer surfacer of claim 1 , wherein the alkoxysilane possesses the general structural formula (II.1)
OCN—R 1 —Si(R′) x (OR″) 3-x

where
R 1 is a C 2 to C 12 alkylene radical, a C 2 to C 12 alkenylene radical, or a polyunsaturated C 4 to C 12 alkylene radical,
the radical R′ is a C 1 to C 12 alkyl radical,
R″ is a methyl or ethyl radical, and
x is 0 to 2.

7. The solventborne primer surfacer as claimed in claim 6 , wherein R 1 is a C 2 to C 6 alkylene radical.

8. The solventborne primer surfacer as claimed in claim 6 , wherein x=0.

9. The solventborne primer surfacer of claim 1 , wherein the oligoester (a) is obtained by reacting components that comprise at least one saturated linear aliphatic dicarboxylic acid and at least one mono- or polyunsaturated linear aliphatic dicarboxylic acid.

10. The solventborne primer surfacer of claim 1 , wherein the oligoester (a) is obtained by reacting components that comprise at least one saturated linear aliphatic dicarboxylic acid and at least one mono- or polyunsaturated linear aliphatic dicarboxylic acid,
and wherein a molar ratio of saturated dicarboxylic acid to mono- and/or polyunsaturated aliphatic dicarboxylic acid is from 0.5:1.5 to 1.5:0.5.

11. The solventborne primer surfacer of claim 1 , wherein the at least one organic solvent is a member selected from the group consisting of aliphatic hydrocarbons, aromatic hydrocarbons, ketones, esters, ethers, alcohols, and mixtures thereof.

12. A process for producing a multicoat paint system on a substrate, the process comprising
(A) applying the primer surfacer of claim 1 , and (B) applying a further coating material.

13. The process as claimed in claim 12 , wherein
i. the primer surfacer film obtained in step (A) is dried,
ii. the coating material in step (B) is a topcoat material, and
iii. the dried primer surfacer film and the topcoat film obtained in step (B) are jointly cured.

14. A multicoat paint system producible by the process as claimed in claim 13 .

15. The process as claimed in claim 12 , wherein
i. a primer is applied to the substrate before the application of the primer surfacer in step (A), and the resulting primer film is dried,
ii. the dried primer film and the primer surfacer film obtained in step (A) are jointly cured,
iii. the further coating material in step (B) is a basecoat material, and is applied to the cured primer surfacer film and subsequently dried, and
iv. a clearcoat material is applied to the dried basecoat film, and the dried basecoat film and the resulting clearcoat film are jointly cured.

16. A multicoat paint system producible by the process as claimed in claim 15 .

17. A process for improving adhesion of a primer surfacer, the process comprising formulating at least one organic solvent and at least one additive into a solventborne primer surfacer, wherein the at least one additive is preparable by reacting
(a) at least one alpha,omega-hydroxy-functionalized oligoester which possesses the following structural formula (I):

where
the radicals R 1 independently of one another are a linear or cyclic alkylene radical,
the radicals R 2 independently of one another are an alkylene or alkenylene radical, the ratio of alkylene to alkenylene radicals being such that the alpha,omega-hydroxy-functionalized oligoester of the structural formula (I) possesses a theoretical carbon-carbon double bond content of 1 to 2.5 mmol/g, and
the index in is such that the number-average molecular weight of the alpha,omega-hydroxy-functionalized oligoester of the structural formula (I) is 1000 to 3000 g/mol,
wherein the alpha,omega-hydroxy-functionalized oligoester possesses an OH number of 30 to 160 mg KOH/g, and a weight-average molecular weight of 2800 to 10 000 g/mol, and
(b) at least one alkoxysilane of the structural formula (II)
A-R—Si(R′) x (OR″) 3-x

where
A is an OH-reactive functional group,
R is an aliphatic radical having 2 to 12 carbon atoms, a cycloaliphatic radical having 3 to 12 carbon atoms, an aromatic radical having 6 to 12 carbon atoms, or an araliphatic radical having 7 to 18 carbon atoms,
the radical R′ is a C 1 to C 12 alkyl radical,
R″ is a methyl or ethyl radical, and
x is 0 to 2,
with the proviso that at least 90 mol % of all the OH groups of the alpha,omega-hydroxy-functionalized oligoester have been reacted with an OH-reactive functional group A,
and,
the sum of the weight percentage fractions of

Assignees

• Basf Coatings Gmbh

Inventors

• Andersen Audree
• Corten Cathrin
• Niemeier Manuela
• Foelling Frederik
• Hesener Simone
• Freitag Nicole
• Boshe-Plois Stefanie

Classifications

• B05D7/14 Primary

  to metal, e.g. car bodies (involving a chemical reaction between the metal and the coating C23) · CPC title

• C08K5/5425

  containing at least one C=C bond · CPC title

• C08G18/6225

  Polymers of esters of acrylic or methacrylic acid · CPC title

• C08G63/6958

  Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation · CPC title

• B05D7/544

  the first layer is let to dry at least partially before applying the second layer · CPC title