Curable transparent rubber composition, a cured transparent rubber composition made thereof, and manufacturing process for the same

Patent metadata

Field	Value
Publication number	US-9932463-B2
Application number	US-201615083856-A
Country	US
Kind code	B2
Filing date	Mar 29, 2016
Priority date	Mar 30, 2015
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

The present disclosure relates to a curable transparent rubber composition containing one or more synthetic isoprene polymers, a styrenic block copolymer, a curing agent, and additives that do not influence transparency of the final composition. Once cured, the curable transparent rubber composition has a haze of less than 30% and a total light transmission of more than 80%. The disclosure further relates to a cured transparent rubber composition made thereof, and a manufacturing process for the cured composition. The present disclosure also relates to an article including the rubber composition, in particular for tubes, medical stoppers, catheters, dental dams and other medical applications and artificial nipples.

First claim

The invention claimed is:

1. A solid curable, transparent, rubber composition that once cured has a haze of less than 30% and a total light transmission of more than 80%, both measured according to ASTM D1003-13, comprising:
Component (a): from 15-80 wt. % of one or more synthetic isoprene polymers having a refractive index of between 1.500 to 1.525 at 23° C.;
Component (b): from 15-80 wt. % of a styrenic block copolymer having 2 or more poly(vinyl aromatic) blocks and at least one block of polymerized conjugated diene, wherein the styrenic block copolymer has a weight average molecular weight of 150,000 to 250,000, the poly(vinyl aromatic) blocks have a weight average molecular weight ranging from 9,000 to 15,000, and the content of poly(vinyl aromatic) blocks in the styrenic block copolymer ranges from 8 to 13 wt. %, based on the total styrenic block copolymer wherein the difference between the refractive indices of component (a) and (b) is 0.100 or less;
Components (c) and (d): from 0.05-8.0 wt. % of a curing agent, optionally with a co-agent present in an amount of 0 to 7.95 wt. %, and
Component (e): from 0.01-20 wt. % of additives that do not influence the transparency,

wherein all amounts of components (a), (b), (c), (d) and (e) present in the composition are in percentages by weight on the total composition.

2. The composition according to claim 1 , wherein component (a) is a homopolymer of isoprene.

3. The composition according to claim 1 , wherein component (a) is a homopolymer of isoprene, made by anionic polymerization.

4. The composition according to claim 1 , wherein component (a) is present in an amount of 20-75 wt. %.

5. The composition according to claim 1 , wherein the difference between the refractive indices of component (a) and (b) is 0.050 or less.

6. The composition according to claim 5 , wherein component (b) has a mixing processing temperature of at most 150° C.

7. The composition according to claim 1 , wherein component (b) is present in an amount of 20-75 wt. %.

8. The composition according to claim 1 , wherein component (c) is a peroxide, selected from a group consisting of 2,5-dimethyl-2,5-di-(t-butylperoxy)hexane, 1,1-di (tert-butylperoxy)cyclohexane, or 2,5-dimethyl-2,5-di-(t-butylperoxy)hexane.

9. The composition according to claim 8 , wherein a co-agent (d) is used in a weight ratio (c) to (d) of 1:2 10.

10. The composition according to claim 1 , having at least one of the following properties:
A Type A Durometer hardness (30 sec) of 25 or more, measured according to ASTM D2240;
A Tear Strength of 10 N/mm or more, measured according to ASTM D624.

11. A process for manufacturing a transparent, cured rubber composition from the composition according to claim 1 , wherein the process comprises the steps of:
mixing components (a), and (b) and (e) to obtain a mixture thereof;
adding a curing agent (c) and optionally a co-agent (d); and
uniformly kneading the mixture and curing the same.

12. An article based on the composition according to claim 1 or a having a composition prepared by the process according to claim 11 .

13. The article according to claim 12 , wherein the article is selected from the group consisting of tubes, medical stoppers, catheters, dental dams and other medical applications, clothes and underclothes, rain gears, eyewear, masks, toys, damping materials, building materials, coating material for wiring, packaging materials, protective members for computers, computer peripherals, contraceptive devices, sex toys, artificial nipples, disposable diapers, stationery, containers, food trays, balls for sports, ball chairs, protection films, seals, and key covers.

14. A solid curable, transparent, rubber composition that once cured has a haze of less than 30% and a total light transmission of more than 80%, both measured according to ASTM D1003-13, comprising:
Component (a): from 15-80 wt. % of one or more synthetic isoprene polymers having a refractive index of between 1.500 to 1.525 at 23° C.;
Component (b): from 15-80 wt. % of a styrenic block copolymer having a simple structure A-B-Y-(B-A)n wherein
each A is independently a polymer block composed of at least 90 mole % of an alkenyl aromatic hydrocarbon;
the content of A by weight of the total weight of the polymer (PSC) is in the range of 8-13%;
Y is the remnant of a coupling agent having a functionality greater than 2;
the degree of branching (DoB) is n+1, wherein n is an integer from 2 to 5;
each B is independently a polymer block composed of at least 90 mole % of one or more conjugated dienes;
the styrenic block copolymer has a coupling efficiency (CE) of at least 90%;
each A block independently has a weight average molecular weight (MW A) ranging from 9,000 to 15,000; and
each B block independently has a weight average molecular weight (MW B) ranging from 75,000 to 150,000;

Components (c) and (d): from 0.05-8.0 wt. % of a curing agent, optionally with a co-agent present in an amount of 0 to 7.95 wt. %, and
Component (e): from 0.01-20 wt. % of additives that do not influence the transparency,
wherein all amounts of components (a), (b), (c), (d) and (e) present in the composition are in percentages by weight on the total composition;
wherein the difference between the refractive indices of component (a) and (b) is 0.050 or less; and
wherein component (b) has a mixing processing temperature of at most 150° C.

15. The composition according to claim 14 , wherein component (b) is a block copolymer the blocks A of which have weight average molecular weights between about 10,000 and about 12,000, and the blocks B thereof have weight average molecular weights between about 80,000 and about 120,000, and wherein the weight percentage of the A blocks in the block polymer is between 10% and 12% by weight.

Assignees

• Kraton Polymer U S Llc
• Kraton Polymers Us Llc

Inventors

• Van Der Waal Arie Willem
• SMIT Joris

Classifications

• C08L2201/10

  Transparent films; Clear coatings; Transparent materials · CPC title

• C08L7/00

  Compositions of natural rubber · CPC title

• C08L53/02 Primary

  of vinyl-aromatic monomers and conjugated dienes · CPC title

• C08L9/06 Primary

  Copolymers with styrene · CPC title

• C08K3/0016

  Chemistry & Metallurgy · mapped topic