Rubber composition for flexible coupling

Patent metadata

Field	Value
Publication number	US-9932458-B2
Application number	US-201514985517-A
Country	US
Kind code	B2
Filing date	Dec 31, 2015
Priority date	Jun 29, 2015
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

Disclosed is a rubber composition for flexible coupling. In particular, the rubber composition for flexible coupling is prepared by mixing a filler including an HNBR alloy and carbon blacks having different average particle diameters with a hydrogenated acrylonitrile-butadiene rubber such that performance deterioration due to hydrolysis can be prevented even in hot and humid environments and the rubber composition has superior heat resistance and improved mechanical strength.

First claim

What is claimed is:

1. A rubber composition for flexible coupling comprising:
a rubber component comprising an amount of about 60 to 80% by weight of a hydrogenated acrylonitrile-butadiene rubber and 20 to 40% by weight of an hydrogenated nitrile butadiene rubber (HNBR) alloy, % by weight based on the total weight of the rubber component;
an amount of about 60 to 180 parts by weight of a filler based on 100 parts by weight of the rubber component;
an amount of about 0.1 to 5 parts by weight of a hardener based on 100 parts by weight of the rubber component;
an amount of about 0.1 to 5 parts by weight of an accelerator based on 100 parts by weight of the rubber component;
an amount of about 1 to 30 parts by weight of a crosslinker based on 100 parts by weight of the rubber component;
an amount of about 0.1 to 10 parts by weight of a processing aid based on 100 parts by weight of the rubber component; and
an amount of about 1 to 30 parts by weight of a plasticizer based on 100 parts by weight of the rubber component,
wherein the hydrogenated acrylonitrile-butadiene rubber has a tensile strength of about 250 to 350 kg f /cm 2 and an elongation of about 250 to 350%.

2. The rubber composition according to claim 1 , wherein the filler is a mixture of a first carbon black and a second carbon black.

3. The rubber composition according to claim 2 , wherein an average particle diameter of the first carbon black is from about 30 to about 55 nm and an average particle diameter of the second carbon black is from about 55 to about 100 nm.

4. The rubber composition according to claim 2 , wherein, in the mixture, the first carbon black and the second carbon black are mixed in a weight ratio of about 80:20 to 95:5.

5. The rubber composition according to claim 1 , wherein the filler has a nitrogen absorption surface area of about 30 to 300 m/g and a DBP oil absorption amount of about 60 to 180 cc/100 g.

6. The rubber composition according to claim 1 , wherein the hardener is one or more selected from the group consisting of sulfur powder, insoluble sulfur, sedimented sulfur and colloid sulfur.

7. The rubber composition according to claim 1 , wherein the accelerator is one or more selected from the group consisting of tetramethylthiuram monosulfide, tetramethylthiuram disulfide, tetraethylthiuram disulfide, tetrabutylthiuram disulfide, dipentamethylenethiuram tetrasulfide, N-cyclohexyl-2-benzothiazolylsulfenamide, N-oxydiethylene-2-benzothiazolylsulfenamide, N-tert-butyl-2-benzothiazolylsulfenamide and N,N′-dicyclohexyl-2-benzothiazolylsulfenamide.

8. The rubber composition according to claim 1 , wherein the crosslinker is one or more organic peroxides selected from the group consisting of benzoyl peroxide, dicumyl peroxide, di-t-butyl peroxide, t-butyl cumyl peroxide, methylethylketone peroxide, cumene hydroperoxide, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, 2,5-dimethyl-2,5-di(benzoylperoxy)hexane, 1,3-bis(t-butylperoxypropyl)benzene, di-t-butylperoxy-diisopropylbenzene, t-butylperoxybenzene, 2,4-dichlorobenzoyl peroxide, 1,1-dibutylperoxy-3,3,5-trimethylsiloxane and n-butyl-4,4-di-t-butylperoxyvalerate.

9. The rubber composition according to claim 1 , wherein the processing aid is one or more metal oxide selected from the group consisting of zinc oxides, magnesium oxides and lead oxides, one or more fatty acids selected from the group consisting of stearic acids, oleic acids and palmitic acids, or one or more selected from the group consisting of triallyl isocyanurate, ethylene glycol dimethacrylate and trimethylolpropane methacrylate.

10. The rubber composition according to claim 1 , wherein the plasticizer is a derivative of phthalic acid, isophthalic acid, adipic acid, sebacic acid, benzoic acid and phosphoric acid, and one or more selected from the group consisting of dioctyl phthalate (DOP), dibutyl phthalate (DBP), di-(2-ethylhexyl)phthalate, di-iso-octylphthalate (DIOP), higher alcohol phthalate, di-(2-ethylhexyl) sebacate, polyester adipate, dibutyl diglycol adipate, di(butoxyethoxyethyl) adipate, isooctyl-tol oil fat ester, tributyl phosphate (TBP), tributoxyethyl phosphate (TBEP), tricresyl phosphate (TCP), cresyl diphenyl phosphate (CDP) and diphenyl alkane.

11. The rubber composition according to claim 1 , further comprising an amount of about 0.1 to 15 parts by weight of an antioxidant and 0.1 to 10 parts by weight of a lubricant based on 100 parts by weight of the rubber.

12. The rubber composition according to claim 11 , wherein the antioxidant is one or more selected from the group consisting of phenyl-α-naphthylamine, 2,2,4-trimethyl-1,2-dihydroquinoline polymer (TMDQ), 6-ethoxy-2,2,4-trimethyl-1,2-dihydroquinoline (ETMDQ), p,p′-dioctyldiphenylamine (ODPA), p,p′-dicumyldiphenylamine (DCDP), N,N′-di-2-naphthyl-p-phenylenediamine (DNPD), N,N′-diphenyl-p-phenylenediamine (DPPD), N-phenyl-N′-isopropyl-p-phenylenediamine (IPPD) and N-phenyl-N′-1,3-dimethylbutyl-p-phenylenediamine (6PPD).

13. The rubber composition according to claim 11 , wherein the lubricant is one or more petroleum-based oils selected from the group consisting of paraffin-based oils, naphthene-based oils, aromatic oils, or one or more plant oils selected from the group consisting of castor oil, cotton seed oil, linseed oil, canola oil, soybean oil, palm oil, coconut oil, peanut oil, pine oil, pine-tar, tall oil, corn oil, rice bran oil, safflower oil, sesame oil, olive oil, sunflower oil, palm kernel oil, camellia oil, jojoba oil, macadamia nut oil, safflower oil and tung oil.

14. A flexible coupling for a vehicle MDPS steering system, comprising the rubber composition for flexible coupling of claim 1 .

15. A method of manufacturing a flexible coupling for a vehicle MDPS steering system, comprising:
molding the flexible coupling comprising the rubber composition of claim 1 .

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp
• Pck Co Ltd
• Tsr Co Ltd
• Hyundai Mobis Co Ltd
• Kia Motors Company

Inventors

• Kang Jae Wook
• Yang Kyung Mo
• Park Byung Sub
• Seo Kang Won
• Kim Sung Chul
• Lee Dong Won

Classifications

• C08K2201/014

  Additives containing two or more different additives of the same subgroup in C08K · CPC title

• C08K3/22

  of metals · CPC title

• C08L15/005 Primary

  Hydrogenated nitrile rubber · CPC title

• C08K2003/222

  Magnesia, i.e. magnesium oxide · CPC title

• C08K5/14

  Peroxides · CPC title