Thermoplastic resin composition and molding product made therefrom

Patent metadata

Field	Value
Publication number	US-9932428-B2
Application number	US-201615176159-A
Country	US
Kind code	B2
Filing date	Jun 8, 2016
Priority date	Dec 30, 2015
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

A thermoplastic resin composition and a molding product made therefrom are provided. The thermoplastic resin composition includes a branched copolymer obtained from a copolymerization of a urethane compound and a copolymerizable monomer, wherein the urethane compound is obtained from reaction of a (meth)acrylate compound containing hydroxyl group and a triisocyanate compound.

First claim

What is claimed is:

1. A thermoplastic resin composition, comprising:
a branched copolymer, obtained by the copolymerization of a urethane compound and a copolymerizable monomer, and based on an amount of the copolymerizable monomer being 100 parts by weight, an amount of the urethane compound is 0.005 parts by weight to 0.8 parts by weight;
wherein the urethane compound is obtained by the reaction of a (meth)acrylate compound containing hydroxyl group with a triisocyanate compound.

2. The thermoplastic resin composition according to claim 1 , wherein the triisocyanate compound is represented by Formula (1),

in Formula (1), R a , R b , R c each independently represents —(CH 2 ) n —, wherein n is an integer of 2 to 12.

3. The thermoplastic resin composition according to claim 1 , wherein the (meth)acrylate compound containing hydroxyl group is at least one selected from the group consisting of 2-hydroxyethyl acrylate, pentaerythritol triacrylate and caprolactone acrylate.

4. The thermoplastic resin composition according to claim 1 , wherein the urethane compound is represented by Formula (2),

in Formula (2), R 1 , R 2 , R 3 each independently represents —(CH 2 ) n —, wherein n is an integer of 2 to 12, X 1 , X 2 and X 3 each independently is selected from the group consisting of a residue obtained by removing a hydrogen from a hydroxyl group of 2-hydroxyethyl acrylate, a residue obtained by removing a hydrogen from a hydroxyl group of pentaerythritol triacrylate and a residue obtained by removing a hydrogen from a hydroxyl group of caprolactone acrylate.

5. The thermoplastic resin composition according to claim 4 , wherein in Formula (2), R 1 , R 2 , R 3 each independently represents —(CH 2 ) n —, and n is an integer of 2 to 10.

6. The thermoplastic resin composition according to claim 4 , wherein in Formula (2), R 1 , R 2 , R 3 each independently represents —(CH 2 ) n —, and n is an integer of 4 to 8.

7. The thermoplastic resin composition according to claim 4 , wherein in Formula (2), R 1 , R 2 , R 3 each independently represents —(CH 2 ) n —, and n is 6.

8. The thermoplastic resin composition according to claim 1 , wherein based on an amount of the copolymerizable monomer being 100 parts by weight, an amount of the urethane compound is 0.01 parts by weight to 0.4 parts by weight.

9. The thermoplastic resin composition according to claim 1 , wherein when the molar mass of the branched copolymer is in the range of 2×10 5 g/mol to 3×10 6 g/mol, the average radius of gyration is 30 nm to 50 nm.

10. The thermoplastic resin composition according to claim 1 , wherein the copolymerizable monomer is at least one selected from the group consisting of a styrene based monomer, an acrylonitrile based monomer and a (meth)acrylate based monomer.

11. The thermoplastic resin composition according to claim 1 , wherein the weight average molecular weight of the branched copolymer is 100,000 to 600,000.

12. A molding product, formed by the thermoplastic resin composition according to claim 1 .

Assignees

• Chi Mei Corp

Inventors

• Tai Chia-Hon
• Wang Po-Shih
• Wu Chen-Dao
• Hsu Jui-Hsi

Classifications

• C08G18/792

  formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates · CPC title

• C08G18/6725

  containing ester groups other than acrylate or alkylacrylate ester groups · CPC title

• C08F290/067

  Polyurethanes; Polyureas · CPC title

• C08G18/246

  containing also tin-carbon bonds · CPC title

• C08F299/065

  from polyurethanes with side or terminal unsaturations · CPC title