Cutting elements and methods for fabricating diamond compacts and cutting elements with functionalized nanoparticles

Patent metadata

Field	Value
Publication number	US-9931735-B2
Application number	US-201615005212-A
Country	US
Kind code	B2
Filing date	Jan 25, 2016
Priority date	Jan 25, 2016
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

A method of fabricating a diamond compact includes functionalizing surfaces of diamond nanoparticles with fluorine; combining the functionalized diamond nanoparticles with a non-group-VIII metal to form a particle mixture; and subjecting the particle mixture to high pressure and high temperature (HPHT) conditions to form inter-granular bonds between the diamond nanoparticles. A cutting element for an earth-boring tool includes a plurality of grains of diamond material; a plurality of diamond nanoparticles bonded to the plurality of grains of diamond material; and a non-group-VIII metal fluoride disposed within interstitial spaces between the grains of diamond material and the plurality of diamond nanoparticles. The cutting element is substantially free of a metal-solvent catalyst.

First claim

What is claimed is:

1. A method of fabricating a diamond compact, comprising:
functionalizing surfaces of diamond nanoparticles with fluorine;
combining the functionalized diamond nanoparticles with a non-group-VIII metal in a liquid solvent, wherein the liquid solvent is unreactive to both the functionalized diamond nanoparticles and the non-group-VIII metal;
removing the liquid solvent to form a particle mixture comprising the functionalized diamond nanoparticles and the non-group-VIII metal; and
subjecting the particle mixture to high pressure and high temperature (HPHT) conditions to form inter-granular bonds between the diamond nanoparticles.

2. The method of claim 1 , wherein functionalizing surfaces of diamond nanoparticles with fluorine comprises functionalizing surfaces of crushed diamond nanoparticles with fluorine.

3. The method of claim 1 , further comprising including non-functionalized diamond grit in the particle mixture.

4. The method of claim 1 , wherein combining the functionalized diamond nanoparticles with a non-group-VIII metal comprises combining the functionalized diamond nanoparticles with at least one metal selected from the group consisting of aluminum, copper, silver, indium, zinc, lead, lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, and barium.

5. The method of claim 4 , wherein combining the functionalized diamond nanoparticles with a non-group-VIII metal comprises combining the functionalized diamond nanoparticles with aluminum.

6. The method of claim 1 , wherein the particle mixture consists essentially of the functionalized diamond nanoparticles, the non-group-VIII metal, and non-functionalized diamond particles.

7. The method of claim 1 , wherein subjecting the mixture to HPHT conditions comprises heating the particle mixture to a temperature above a melting point of the non-group-VIII metal.

8. The method of claim 1 , wherein subjecting the mixture to HPHT conditions comprises heating the particle mixture to a temperature of at least about 1,400° C. and a maximum pressure of less than about 8.0 GPa.

9. The method of claim 1 , wherein subjecting the mixture to HPHT conditions comprises increasing an average particle size of the diamond nanoparticles.

10. The method of claim 1 , wherein combining the functionalized diamond nanoparticles with a non-group-VIII metal comprises forming a mixture in which the non-group-VIII metal comprises from about 0.1% to about 20.0% by weight of the mixture.

11. A method of forming a cutting element for an earth-boring tool, comprising:
functionalizing surfaces of diamond nanoparticles with fluorine;
combining the functionalized diamond nanoparticles with a non-group-VIII metal in a liquid solvent, wherein the liquid solvent is unreactive to both the functionalized diamond nanoparticles and the non-group-VIII metal;
removing the liquid solvent to form a particle mixture comprising the functionalized diamond nanoparticles and the non-group-VIII metal;
providing the particle mixture over a body; and
subjecting the particle mixture and the body to high pressure and high temperature (HPHT) conditions to form inter-granular bonds between the diamond nanoparticles and secure the inter-granular bonded diamond nanoparticles to the body.

12. The method of claim 11 , wherein functionalizing surfaces of diamond nanoparticles with fluorine comprises functionalizing surfaces of crushed diamond nanoparticles with fluorine.

13. The method of claim 11 , wherein subjecting the particle mixture and the body to HPHT conditions comprises forming a metal fluoride.

14. The method of claim 13 , wherein forming a metal fluoride comprises forming aluminum fluoride.

15. The method of claim 11 , wherein the liquid solvent comprises a material selected from the group consisting of dry hexane, cyclohexane, heptane, benzene, and toluene.

16. The method of claim 11 , wherein removing the liquid solvent further comprises evaporating the liquid solvent by heating the combination of the liquid solvent, the functionalized diamond nanoparticles, and the non-group-VIII metal.

17. The method of claim 11 , further comprising forming a cohesive solid from the particle mixture before subjecting the particle mixture to HPHT conditions.

18. The method of claim 17 , wherein forming a cohesive solid further comprises forming a cohesive solid by a process selected from the group consisting of extrusion, pressing, molding, spray drying, spin coating, hot rolling, cold rolling, and tape casting.

19. The method of claim 11 , further comprising mixing the particle mixture with relatively larger diamond particles.

Assignees

• Baker Hughes Inc
• Baker Hughes A Ge Co Llc

Inventors

• Khabashesku Valery N
• Filonenko Vladimir P

Classifications

• E21B10/46

  characterised by wear resisting parts, e.g. diamond inserts · CPC title

• C04B35/52

  based on carbon, e.g. graphite · CPC title

• C04B2235/427

  Diamond · CPC title

• Y10S977/773

  Nanoparticle, i.e. structure having three dimensions of 100 nm or less · CPC title

• C04B35/62685

  characterised by the order of addition of constituents or additives · CPC title