Process for separating components of a polymer-monomer mixture obtained by high-pressure polymerization of ethylenically unsaturated monomers

Patent metadata

Field	Value
Publication number	US-9931608-B2
Application number	US-201515523909-A
Country	US
Kind code	B2
Filing date	Nov 12, 2015
Priority date	Nov 13, 2014
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

A process for separating polymeric and gaseous components of a polymer-monomer mixture at a pressure of from 0.12 MPa to 0.6 MPa and a temperature of from 120° C. to 300° C. in a separation vessel is provided. The separation vessel has a vertically arranged cylindrical shape with a ratio of length to diameter L/D of from 0.6 to 10 and an inlet pipe capable of introducing the polymer-monomer mixture into the separation vessel which the inlet pipe extends vertically from the top of the separation vessel into the separation vessel. Further a process for preparing ethylene homopolymers or copolymers from ethylenically unsaturated monomers in the presence of free-radical polymerization initiators at temperatures from 100° C. to 350° C. and pressures in the range of from 110 MPa to 500 MPa comprising such a process for separating a polymer-monomer mixture is provided.

First claim

What is claimed is:

1. A process for separating a polymer-monomer mixture comprising polymeric components and gaseous components into a liquid fraction and a gaseous fraction comprising the steps of:
(i) introducing the polymer-monomer mixture into a separation vessel;
(ii) separating the polymer-monomer mixture at a pressure of from 0.12 MPa to 0.6 MPa and a temperature of from 120° C. to 300° C. into a gaseous fraction and a liquid fraction;
(iii) withdrawing the gaseous fraction from the top of the separation vessel; and
(iv) withdrawing the liquid fraction from the bottom of the separation vessel,
wherein the polymeric components of the mixture are produced by high-pressure polymerization of ethylenically unsaturated monomers in the presence of at least one free-radical polymerization initiator,
and wherein
a) the separation vessel has a vertically arranged cylindrical shape with a ratio of length to diameter L/D of from 0.6 to 10;
b) the separation vessel is equipped with an inlet pipe capable of introducing the polymer-monomer mixture into the separation vessel;
c) the inlet pipe extends vertically from the top of the separation vessel into the separation vessel; and
d) the ratio of the inner diameter of the inlet pipe at its lower end and the inner diameter of the separating vessel in its cylindrical part is in the range of from 0.15 to 0.4.

2. The process according to claim 1 , wherein the inlet pipe is centrally arranged in the separation vessel.

3. The process according to claim 1 , wherein the polymer-monomer mixture is produced as a liquid fraction by separating a reaction mixture produced by high-pressure polymerization and the separation was carried out at a pressure of from 15 MPa to 50 MPa and a temperature of from 120° C. to 300° C.

4. The process according to claim 1 , wherein the inlet pipe extends for a distance into the separation vessel which is from 25% to 40% of the length of the separation vessel.

5. The process according to claim 1 , wherein the velocity of the polymer-monomer mixture at the lower end of the inlet pipe is in the range of from 0.3 m/s to 20 m/s.

6. The process according to claim 1 , wherein the vertical velocity of the rising gas in the region from the lower end of the inlet pipe to the outlet for withdrawing the gaseous fraction from the separation vessel is in the range of from 0.02 m/s to 2.0 m/s.

7. The process according to claim 1 , wherein the surfaces within the separation vessel which are in contact with the liquid fraction have an average roughness Ra of at the most 3.2 μm.

8. The process according to claim 1 , wherein the surfaces within the separation vessel which are in contact with the liquid fraction are provided with a polytetrafluoroethylene coating.

9. The process according to claim 1 , wherein the angle of the conical part of the separator is in the range of from 30 to 60°.

10. The process according to claim 1 , wherein inlet pipe has a conical part which has an angle in the range of from 5 to 25°.

11. The process according to claim 1 , wherein the level of the liquid fraction in the separation vessel is measured by radiometric level measurement and is controlled by a product discharge valve.

12. The process according to claim 1 , wherein the conduit providing the polymer-monomer mixture to the separation vessel has a bend in the range of from 60° to 120°.

13. The process according to claim 1 , wherein the separation vessel is mounted to a pelletizing device.

14. A process for preparing ethylene homopolymers or copolymers comprising polymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators at temperatures from 100° C. to 350° C. and pressures in the range of from 110 MPa to 500 MPa in a polymerization reactor, the process comprising a process for separating a produced polymer-monomer mixture comprising polymeric components and gaseous components into a liquid fraction and a gaseous fraction, the process comprising the steps of:
(v) introducing the polymer-monomer mixture into a separation vessel;
(vi) separating the polymer-monomer mixture at a pressure of from 0.12 MPa to 0.6 MPa and a temperature of from 120° C. to 300° C. into a gaseous fraction and a liquid fraction;
(vii) withdrawing the gaseous fraction from the top of the separation vessel; and
(viii) withdrawing the liquid fraction from the bottom of the separation vessel,
wherein the polymeric components of the mixture are produced by high-pressure polymerization of ethylenically unsaturated monomers in the presence of at least one free-radical polymerization initiator,
and wherein
a) the separation vessel has a vertically arranged cylindrical shape with a ratio of length to diameter L/D of from 0.6 to 10;
b) the separation vessel is equipped with an inlet pipe capable of introducing the polymer-monomer mixture into the separation vessel;
c) the inlet pipe extends vertically from the top of the separation vessel into the separation vessel; and
d) the ratio of the inner diameter of the inlet pipe at its lower end and the inner diameter of the separating vessel in its cylindrical part is in the range of from 0.15 to 0.4.

15. The process according to claim 14 , wherein the polymerization is carried out in one or more tubular reactors or autoclave reactors or combinations of such reactors.

16. The process according to claim 14 , wherein the inlet pipe is centrally arranged in the separation vessel.

17. The process according to claim 14 , wherein the separation is carried out at a pressure of from 15 MPa to 50 MPa and a temperature of from 120° C. to 300° C.

18. The process according to claim 14 , wherein the inlet pipe extends for a distance into the separation vessel which is from 25% to 40% of the length of the separation vessel.

19. The process according to claim 14 , wherein the velocity of the polymer-monomer mixture at the lower end of the inlet pipe is in the range of from 0.3 m/s to 20 m/s.

20. The process according to claim 14 , wherein the surfaces within the separation vessel which are in contact with the liquid fraction have an average roughness Ra of at the most 3.2 μm.

Assignees

• Basell Polyolefine Gmbh

Inventors

• Littmann Dieter
• Groos Georg
• Finette Andre-Armand
• Deuerling Michael
• Wolfram Sven
• Mohrbutter Juergen
• Khayrullin Danir
• Fibla Claudio
• Wolf Christoph

Classifications

• B01J2219/1943

  cylindrical · CPC title

• B01J4/002 Primary

  Nozzle-type elements (nozzle-type reactors B01J19/26) · CPC title

• C08F2/004 Primary

  by a prior coating on the reactor walls · CPC title

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• B01J2219/1946

  conical · CPC title