Removing acid gases from water vapour-containing fluid streams

Patent metadata

Field	Value
Publication number	US-9931594-B2
Application number	US-201313780377-A
Country	US
Kind code	B2
Filing date	Feb 28, 2013
Priority date	Mar 2, 2012
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

A process for removing acid gases from a water vapor-containing fluid stream comprises a) providing an absorption liquid which is incompletely miscible with water; b) treating the fluid stream in an absorption zone with the absorption liquid to obtain an acid gas-depleted treated fluid stream and an acid gas-loaded absorption liquid; c) directing the treated fluid stream to a rehydration zone and treating the fluid stream with an aqueous liquid to volatilize at least part of the aqueous liquid; d) regenerating the loaded absorption liquid to expel the acid gases at least in part and obtain a regenerated absorption liquid, and directing the regenerated absorption liquid to step b); and e) separating, from the absorption liquid, an aqueous liquid that has condensed in the absorption zone, and directing the aqueous liquid to step c). The process allows for an efficient removal of water accumulated in the absorption liquid system.

First claim

We claim:

1. A process for removing acid gases from a water vapour-containing fluid stream comprising
a) providing an absorption liquid which is incompletely miscible with water;
b) treating the water vapour-containing fluid stream in an absorption zone with the absorption liquid to obtain an acid gas-depleted treated fluid stream and an acid gas-loaded absorption liquid;
c) directing the acid gas-depleted treated fluid stream to a rehydration zone and treating the acid gas-depleted treated fluid stream with an aqueous liquid to volatilize at least part of the aqueous liquid;
d) regenerating the acid gas-loaded absorption liquid to expel the acid gases at least in part and obtain a regenerated absorption liquid, and directing the regenerated absorption liquid to step b); and
e) separating, from the acid gas-loaded absorption liquid, an aqueous liquid that has condensed in the absorption zone, and directing the aqueous liquid to step c),
wherein separating the aqueous liquid comprises subjecting the acid gas-loaded absorption liquid to liquid-liquid phase separation to separate the aqueous liquid therefrom;
wherein regenerating the acid gas-loaded absorption liquid occurs by pressure release, heating, stripping or any combination thereof.

2. The process according to claim 1 , wherein the absorption liquid is essentially immiscible with water.

3. The process according to claim 1 , wherein the aqueous liquid is incompletely volatilized in step c) so as to scrub the acid gas-depleted treated fluid stream with the aqueous liquid to remove entrained absorption liquid from the acid gas-depleted treated fluid stream, and to collect a spent aqueous liquid loaded with entrained absorption liquid.

4. The process according to claim 3 , wherein at least part of the spent aqueous liquid is combined with the absorption liquid in step a) or the regenerated absorption liquid of step d) or both.

5. The process according to claim 3 , wherein the spent aqueous liquid is subjected to liquid-liquid phase separation to obtain an aqueous phase and an entrained absorption liquid phase, and at least part of the entrained absorption liquid phase is combined with the absorption liquid in step a) or the regenerated absorption liquid of step d) or both.

6. The process according to claim 1 , wherein the fluid stream has an acid gases partial pressure of less than 2 bar.

7. The process according to claim 1 , wherein the fluid stream is an exhaust gas from a combustion process.

8. The process according to claim 1 , wherein the acid gas-loaded absorption liquid is preheated by indirect heat exchange with the regenerated absorption liquid.

9. The process according to claim 1 , wherein the absorption liquid comprises a nitrogenous base and a weak acid.

10. The process according to claim 9 , wherein the nitrogenous base is selected from amidines, guanidines and combinations thereof.

11. The process according to claim 9 , wherein the weak acid is selected from alcohols.

12. The process according to claim 1 , wherein less than 20% by weight of water is soluble in the absorption liquid at 25° C.

13. The process according to claim 1 , wherein less than 5% by weight of water is soluble in the absorption liquid at 25° C.

14. The process according to claim 1 , wherein the rehydration zone is arranged on top of the absorption zone.

Assignees

• Basf Se

Inventors

• Katz Torsten
• Riemann Christian
• Sieder Georg

Classifications

• B01D2257/408

  Cyanides, e.g. hydrogen cyanide (HCH) · CPC title

• B01D2257/80

  Water · CPC title

• B01D2257/304

  Hydrogen sulfide · CPC title

• B01D2258/05

  Biogas · CPC title

• B01D2252/504

  Mixtures of two or more absorbents · CPC title