Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

Patent metadata

Field	Value
Publication number	US-9930892-B2
Application number	US-201715408666-A
Country	US
Kind code	B2
Filing date	Jan 18, 2017
Priority date	Jan 25, 2016
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, compositions containing such molecules, and processes of using such molecules and compositions against such pests. These molecules and compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

First claim

The invention claimed is:

1. A molecule having the following formula

wherein:
(A) R 1 , R 5 , R 6 , R 11 , and R 12 are each independently selected from the group consisting of H, F, Cl, Br, I, CN, (C 1 -C 4 )alkyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, and (C 1 -C 4 )haloalkoxy;
(B) R 2 , R 3 , and R 4 are each independently selected from the group consisting of H, F, Cl, Br, I, CN, (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 2 -C 4 )alkynyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, and (C 1 -C 4 )haloalkoxy;
(C) R 7 is (C 1 -C 6 )haloalkyl;
(D) R 9 is selected from the group consisting of H, F, Cl, Br, I, CN, (C 1 -C 4 )alkyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, and (C 1 -C 4 )haloalkoxy;
(E) R 10 is selected from the group consisting of (F), F, Cl, Br, I, CN, (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 2 -C 4 )alkenyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, and (C 1 -C 4 )haloalkoxy;
(F) R 9 and R 10 together can optionally form a 3- to 5-membered saturated or unsaturated, hydrocarbyl link,
wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, and CN;
(G) R 13 and R 14 are each independently selected from the group consisting of H, (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, and (C 1 -C 4 )haloalkoxy;
(H) X is selected from the group consisting of C, S, and P(C 1 -C 6 )alkyl;
(I) n is 1 or 2;
(J) R 15 is selected from the group consisting of (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, (C 1 -C 4 )haloalkoxy, phenyl, and NH(C 1 -C 4 )haloalkyl,
wherein each alkyl, alkenyl, haloalkyl, alkoxy, haloalkoxy, and phenyl may optionally be substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, I, CN, and OH; and

agriculturally acceptable acid addition salts, salt derivatives, solvates, ester derivatives, crystal polymorphs, isotopes, resolved stereoisomers, and tautomers, of the molecules of Formula One.

2. A molecule according to claim 1 wherein R 1 , R 3 , R 4 , R 5 , R 6 , R 9 , R 11 , R 12 , R 13 , and R 14 are H.

3. A molecule according to claim 1 wherein R 2 is Cl, Br, or CH 3 .

4. A molecule according to claim 1 wherein R 3 is H, F, Cl, Br, or —CH═CH 2 .

5. A molecule according to claim 1 wherein R 4 is H, Cl, Br, or CH 3 .

6. A molecule according to claim 1 wherein R 2 , R 3 , and R 4 are Cl.

7. A molecule according to claim 1 wherein R 7 is CF 3 or CF 2 CH 3 .

8. A molecule according to claim 1 wherein R 10 is Cl, Br, I, CH 3 , or CF 3 .

9. A molecule according to claim 1 wherein R 13 or R 14 are CH 3 .

10. A molecule according to claim 1 wherein X is C or S.

11. A molecule according to claim 1 wherein n is 1.

12. A molecule according to claim 1 wherein R 15 is CH 2 CH 2 CF 3 or NHCH 2 CF 3 .

13. A molecule according to claim 1 wherein
(A) R 1 , R 5 , R 6 , R 11 , and R 12 are H;
(B) R 2 , R 3 , and R 4 are each independently selected from the group consisting of H, F, Cl, Br, I, (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, and (C 1 -C 4 )haloalkyl;
(C) R 7 is (C 1 -C 6 )haloalkyl;
(D) R 9 is H;
(E) R 10 is selected from the group consisting of H, F, Cl, Br, I, (C 1 -C 4 )alkyl, and (C 1 -C 4 )haloalkyl;
(G) R 13 and R 14 are each independently selected from the group consisting of H and (C 1 -C 4 )alkyl;
(H) X is selected from the group consisting of C and S;
(I) n is 1 or 2; and
(J) R 15 is selected from the group consisting of (C 1 -C 4 )haloalkyl and NH(C 1 -C 4 )haloalkyl.

14. A molecule according to claim 1 wherein said molecule is selected from one of the following molecules

No.
Structure

P1

P2

P3

P4

P5

P6

P7

P8

P9

P10

P11

P12

P13

Assignees

• Dow Agrosciences Llc

Inventors

• Barton Thomas
• Gao Xin
• Hunter Jim
• Leplae Jr Paul R
• Lo William C
• Boruwa Joshodeep
• Tangirala Raghuram
• Watson Gerald B
• Herbert John

Classifications

• A01N57/30

  containing aromatic radicals · CPC title

• A01N47/24

  containing the groups [IMAGE cpc-sch-A01N-0944.gif], [IMAGE cpc-sch-A01N-0945.gif] or[IMAGE cpc-sch-A01N-0946.gif]; Thio analogues thereof · CPC title

• A01N55/00

  Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur (containing organo-phosphorus compounds A01N57/00) · CPC title

• A01N41/06

  Sulfonic acid amides · CPC title

• C07C243/38

  with acylating carboxyl groups bound to carbon atoms of six-membered aromatic rings · CPC title