Apparatus and methodology for measuring properties of microporous material at multiple scales

Patent metadata

Field	Value
Publication number	US-9927344-B2
Application number	US-201414760651-A
Country	US
Kind code	B2
Filing date	Feb 5, 2014
Priority date	Feb 8, 2013
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

A method for characterizing properties of a sample that employs a test apparatus including an isolated sample cell and pressure sensor where the isolated sample cell is loaded with the sample and gaseous test fluid to perform a number of different tests to derive properties of the sample. The tests can be performed over different parameters, such as different applied pressures of the test fluid to derive parameters related to apparent gas permeability of the sample as a function of applied pressure, different gaseous test fluids to characterize dependence of permeability of the sample on mean free molecular path or pressure, with both adsorptive and non-adsorptive test gases to characterize at least one property related to adsorptive interaction between the adsorptive test gas and the sample, and with samples of varying saturation levels to derive a measure of at least one property of the subsamples at corresponding saturation levels.

First claim

What is claimed is:

1. A method for characterizing properties of a sample under test, comprising:
a) providing a test apparatus including a sample cell and associated pressure sensor, wherein the sample cell is filled with test fluid under pressure and isolated from other parts of the test apparatus, and wherein the pressure sensor of the test apparatus measures pressure of the sample cell when the sample cell is isolated from other parts of the test apparatus;
b) using the test apparatus with the sample cell loaded with the sample under test and a source of gaseous test fluid to perform a test at a number of different applied pressures of the gaseous test fluid where the pressure sensor of the test apparatus is configured to measure pressure of the sample cell over time when the sample cell is isolated from other parts of the test apparatus in order to derive parameters related to apparent gas permeability of the sample under test as a function of applied pressure of the gaseous test fluid;
b1) configuring the test apparatus to perform a sequence of test operations whereby the sample cell is filled with the gaseous test fluid at the given applied pressure and isolated from other parts of the test apparatus and a data acquisition module is used to store pressure data that represents pressures measured by the pressure sensor over time,
b2) using a data processing system to process the pressure data generated and stored in b1) in conjunction with a first computational model that includes a set of pressure curves with a number of curve-related variables and associated values in order to identify a matching pressure curve, and
b3) using the data processing system to process the values of the curve-related variables for the matching pressure curve identified in b2) in order to derive an estimated value of apparent gas permeability of the sample under test at the given applied pressure of the gaseous test fluid.

2. A method according to claim 1 , further comprising:
c) using the data processing system to fit the estimated values of apparent gas permeability of the sample under test at different applied pressures of the gaseous test fluid as derived in b3) to a first parametric function for the apparent gas permeability of the sample under test as a function of applied pressure in order to derive the value of at least one parameter of the first parametric function;
d) for each given applied pressure of the gaseous test fluid in b),
d1) using the data processing system to process the pressure data generated measured and stored in b1) in conjunction with a second computational model that includes a set of pressure curves with a number of curve-related variables and associated values in order to identify a matching pressure curve, wherein the second computational model employs the at least one parameter and associated value as derived in c), and
d2) using the data processing system to process the values of the curve-related variables for the matching pressure curve identified in d1) in order to derive an estimated value of apparent gas permeability of the sample under test at the given applied pressure of the gaseous test fluid;

e) using the data processing system to fit the estimated values of apparent gas permeability of the sample under test at different applied pressures of the gaseous test fluid as derived in d2) to the first parametric function for the apparent gas permeability of the sample under test as function of applied pressure in order to derive the value of at least one parameter of the first parametric function;
f) controlling the data processing system to repeat the operations of d) and e) for a number of iterations until the results converge;
g) subsequent to f), using the data processing system to derive a measure of apparent gas permeability of the sample under test as a function of applied pressure based upon the value of the at least one parameter derived in the last iteration of e).

3. A method according to claim 2 , wherein the data processing system repeats steps d) through g) until the results converge.

4. A method according to claim 2 , wherein the data processing system in g) employs a second parametric function that represents the apparent gas permeability of the sample under test as a function of applied pressure.

5. A method according to claim 2 , wherein the data processing system in g) is used to fit the estimated values of apparent gas permeability of the sample under test at different applied pressures of the gaseous test fluid as derived in the last iteration of d2) to the second parametric function in order to derive at least one parameter of the second parametric function.

6. A method according to claim 2 , wherein the first parametric function has the form

k

k
0

=

(

1
+

b
P

)

,

where k is apparent gas permeability,
k 0 is zero slip (infinite pressure) permeability,
P is mean gas pressure, and
b is the Klinkenberg factor.

7. A method according to claim 2 , wherein the second parametric function has the form

k

k
0

=

(

1
+

(

b
P

)

2

⁢

L
KE

λ

)

,

where k is apparent gas permeability,
k 0 is zero slip (infinite pressure) permeability,
P is mean gas pressure,
b is the double-slip constant,
λ is the free mean molecule path, and
L KE is the second length-scale of the flow associated with the kinetic energy of bouncing back gas molecules after collisions with capillary walls.

8. A method according to claim 1 , wherein the sample under test comprises a sample of porous rock extracted from a geologic formation.

Assignees

• Schlumberger Technology Corp

Inventors

• Chertov Maxim Andreevich
• Suarez-Rivera Roberto
• Willberg Dean M
• Green Sidney J

Classifications

• G01N33/24

  Earth materials (G01N33/42 takes precedence) · CPC title

• G01N15/08

  Investigating permeability, pore-volume, or surface area of porous materials · CPC title

• G01N15/0826

  and measuring fluid flow rate, i.e. permeation rate or pressure change · CPC title

• G01N7/00 Primary

  Analysing materials by measuring the pressure or volume of a gas or vapour · CPC title

• G01N15/0806

  Details, e.g. sample holders, mounting samples for testing · CPC title