Chemical looping combustion method with a reaction zone including a gas-solid separation zone and plant using same

Patent metadata

Field	Value
Publication number	US-9927118-B2
Application number	US-201113701221-A
Country	US
Kind code	B2
Filing date	May 24, 2011
Priority date	Jun 2, 2010
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

The object of the invention is a combustion method for a solid feed using a chemical loop wherein an oxygen-carrying material circulates, said method comprising at least:
contacting the solid feed particles in the presence of metallic oxide particles in a first reaction zone (R 1 ) operating in dense fluidized bed mode, carrying out combustion of the gaseous effluents from first reaction zone (R 1 ) in the presence of metallic oxide particles in a second reaction zone (R 2 ), separating in a separation zone (S 3 ) the unburnt particles and the metallic oxide particles within a mixture coming from second reaction zone (R 2 ), re-oxidizing the metallic oxide particles in an oxidation zone (R 4 ) prior to sending them back to first zone (R 1 ).

First claim

The invention claimed is:

1. A combustion method for a solid feed using a chemical loop wherein an oxygen-carrying material circulates, said method comprising at least:
supplying metallic oxide particles to a first reaction zone, the first reaction zone comprising a chamber,
contacting the solid feed particles with the supplied metallic oxide particles in the first reaction zone operating in dense fluidized bed mode,
transferring the supplied metallic oxide particles and gaseous effluents from the first reaction zone to a second reaction zone, the second reaction zone comprising an elongated reactor positioned above the first reaction zone,
carrying out combustion of the gaseous effluents from the first reaction zone in the presence of the metallic oxide particles supplied to the first reaction zone in the second reaction zone operating in dilute fluidized bed mode,
separating in a separation zone the unburnt particles and the metallic oxide particles within a mixture coming from second reaction zone comprising combustion gas, unburnt particles and metallic oxide particles,
re-oxidizing the metallic oxide particles in an oxidation zone prior to sending them back to first zone.

2. A method as claimed in claim 1 , wherein the mixture of particles to be separated in separation zone is supplied in a dilute phase of the fluidized bed of this zone.

3. A method as claimed in claim 1 , wherein the solid feed is selected from among coal, coke, pet coke, biomass, bituminous sands and household waste.

4. A method as claimed in claim 1 , wherein the mean residence time of the solid phase in reaction zone ranges between 0.25 and 20 minutes, and the superficial gas velocity ranges between 0.3 and 3 m/s.

5. A method as claimed in claim 1 , wherein the mean residence time of the gas in second zone ranges between 1 and 20 seconds, and the mean residence time of the solids ranges between 2 seconds and 1 minute, the void fraction in zone being above 0.9.

6. A method as claimed in claim 1 , wherein, in separation zone, a gas flow of imposed velocity is induced at least at 80% by the gaseous combustion effluent containing the particles from second zone, the other part being provided by a gas coming from an external source.

7. A method as claimed in claim 1 , wherein, in separation zone, the superficial gas velocity in the dilute phase of the separation zone is set at a value ranging between 30 and 300% of the mean terminal fall velocity of the oxygen-carrying particles.

8. A method as claimed in claim 7 , wherein, in separation zone, the superficial gas velocity in the dilute phase of the separation zone is set at a value ranging between 50 and 150% of the mean terminal fall velocity of the oxygen-carrying particles.

9. A method as claimed in claim 1 , wherein at the outlet of separation zone, the gas stream containing the light particles and a fraction of oxygen-carrying particles is sent to at least one gas-solid separation stage so as to recover nearly all of the particles contained in the gas stream coming from separation zone, which are then recycled to first reaction zone.

10. A method as claimed in claim 1 , wherein a mixture of particles and of gas is allowed into the enclosure of separation zone, the particles are extracted through an outlet in the upper part of the enclosure and a discharge line in the lower part of this enclosure, the intake and extraction parameters being so selected as to create in the enclosure a lower dense phase and an upper dilute phase, a dilute phase into which said mixture is allowed.

11. A plant for carrying out combustion of a solid feed, said plant comprising at least:
a first reaction zone comprising a solid feed, a fluidization gas and an oxygen-carrying particle feed point, the first reaction zone having a temperature between 800 and 1000° C. and being a dense fluidized bed reaction zone,
a second reaction zone receiving, through a feed point, combustion gases containing particles from the first reaction zone, the second reaction zone having a temperature between 800 and 1000° C. and being a diluted fluidized bed reaction zone, the second reaction zone comprising an outer wall and a fresh oxygen-carrying solid feed point,
a solid particle separation zone receiving, through intake, a gaseous combustion effluent from the second reaction zone, containing ashes, oxygen-carrying particles and unburnt particles, the solid particle separation zone comprising:
an enclosure having an inner wall,
an annular space between the inner wall and the outer wall of the second reaction zone, and
an intake comprising an opening of the second reaction zone positioned above a portion of the annular space,

an oxidation zone supplied with oxygen-carrying particles by the solid particle separation zone and with air.

12. A plant as claimed in claim 11 , wherein the second reaction zone comprises an oxygen feed point.

13. A plant as claimed in claim 11 , wherein separation zone comprises a discharge line arranged in the lower part of the enclosure and an outlet line arranged in the upper part of the device, the intake and discharge/outlet parameters being so selected as to create in the enclosure a dense phase in the lower part and a dilute phase in the upper part, and wherein said delivery line opening into the dilute phase.

14. A plant as claimed in claim 13 , wherein the enclosure of separator also comprises a delivery line for a gas coming from an external source.

15. A plant as claimed in claim 11 , wherein the section of flow of second reaction zone is smaller than the section of flow of first reaction zone.

16. A plant as claimed in claim 11 , also comprising at least one gas-solid separation stage for recovering the particles contained in the gas stream from separation zone and for recycling them through a line to first reaction zone.

17. A plant as claimed in claim 16 , comprising two gas-solid separation stages wherein one of the separation stages is supplied with a gas stream containing particles coming from the other separation stage.

18. A plant as claimed in claim 17 , wherein at least one enclosure containing a fluidized bed for separation of the light particles remaining among the unburnt particles is present on lines.

19. A plant as claimed in claim 11 , wherein a connection between the second reaction zone and the solid particle separation zone comprises of a divergent cone, at an angle preferably ranging between 6° and 30°.

20. A plant as claimed in claim 11 , wherein a connection between the second reaction zone and the solid particle separation zone comprises an insert in form of a divergent cone to facilitate the distribution of the mixture coming from second reaction zone over the entire section of the solid particle separation zone.

21. A method as claimed in claim 1 , wherein the second reaction zone is narrower than the first reaction zone.

22. A plant for carrying out combustion of a solid feed, said plant comprising:
a first reaction zone comprising a chamber, a solid feed, a fluidization gas and a oxygen-carrying particle feed point, the first reaction zone having a temperature between 800 and 1000° C. and being a dense fluidized bed reaction zone,
a second reaction zone positioned above the first reaction zone, the second reaction zone comprising an elongated reactor having an outer wall and receiving, through a feed point, the combustion gases containing particles from the first reaction zone, the second reaction zone having a temperature between

Assignees

• Gauthier Thierry
• Hoteit Ali
• Guillou Florent
• Stainton Helene
• Total Sa
• Ifp Energies Now

Inventors

• Gauthier Thierry
• Hoteit Ali
• Guillou Florent
• Stainton Helene

Classifications

• F23J2217/40

  by cyclones · CPC title

• F23C6/04

  in series connection (consuming smoke or fumes in separate combustion apparatus F23G7/06) · CPC title

• F23C10/10

  the separation apparatus being located outside the combustion chamber · CPC title

• C10J2300/0959

  Oxygen · CPC title

• B01J8/0055

  using cyclones · CPC title