Process for removing oxygenates from hydrocarbon streams

Patent metadata

Field	Value
Publication number	US-9926498-B2
Application number	US-201615164576-A
Country	US
Kind code	B2
Filing date	May 25, 2016
Priority date	May 25, 2016
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

A method of removing oxygenates from a hydrocarbon stream comprises passing a hydrocarbon stream to a caustic tower having a plurality of loops, contacting the hydrocarbon stream with a sulfided catalyst between a first loop of the plurality of loops and a second loop of the plurality of loops to produce a reaction product, passing the reaction product to the second loop, removing at least a portion of the hydrogen sulfide in the second loop of the caustic tower to produce a product stream, and separating the product stream into a plurality of hydrocarbon streams in a separation zone located downstream of the caustic tower. The hydrocarbon stream comprises hydrocarbons, oxygen containing components, and sulfur containing compounds. At least a portion of the sulfur compounds react in the presence of the sulfided catalyst to produce hydrogen sulfide in the reaction product.

First claim

What is claimed is:

1. A method comprising:
passing a hydrocarbon stream to a caustic tower, wherein the hydrocarbon stream comprises one or more hydrocarbons, one or more oxygen containing components, and one or more sulfur containing compounds, and wherein the caustic tower comprises a plurality of loops;
contacting the hydrocarbon stream with a sulfided catalyst between a first loop of the plurality of loops and a second loop of the plurality of loops to produce a reaction product, wherein at least a portion of the one or more sulfur containing compounds reacts in the presence of the sulfided catalyst to produce hydrogen sulfide in the reaction product;
passing the reaction product to the second loop; and
removing at least a portion of the hydrogen sulfide in the second loop of the caustic tower to produce a product stream.

2. The method of claim 1 , further comprising:
producing the hydrocarbon stream in a cracking process, wherein the cracking process comprises at least one of a fluid catalytic cracking process, a steam cracking process, and a deep catalytic cracking process.

3. The method of claim 2 , wherein producing the hydrocarbon stream comprises:
producing a first product stream in a fluid catalytic cracking process;
separating the first product stream to obtain a dry gas stream from the first product stream;
passing the dry gas stream to a steam cracking unit; and
cracking the dry gas stream in the steam cracking unit to produce the hydrocarbon stream.

4. The method of claim 1 , wherein the hydrocarbon stream comprises a sulfur concentration of greater than about 80 ppm by weight.

5. The method of claim 4 , further comprising:
reducing the sulfur concentration of the hydrocarbon stream to less than about 80 ppm by weight in the first loop of the caustic tower prior to contacting the hydrocarbon stream with the sulfided catalyst.

6. The method of claim 1 , wherein the sulfided catalyst comprises nickel sulfide.

7. The method of claim 1 , wherein the first loop uses a caustic solution having a caustic concentration of between about 0.5% and about 10%.

8. The method of claim 1 , wherein at least a portion of the one or more oxygen containing components reacts in the presence of the sulfided catalyst to produce carbon dioxide in the reaction product, and wherein the method further comprises removing at least a portion of the carbon dioxide in the second loop of the caustic tower.

9. The method of claim 1 , wherein the hydrocarbon stream comprises an olefin.

10. The method of claim 1 , wherein the product stream comprises hydrogen, methane, ethane, propane, butane, ethylene, propylene, butene, or any combination thereof.

11. The method of claim 1 , further comprising:
separating the product stream into a plurality of hydrocarbon streams in a separation zone located downstream of the caustic tower.

12. A method comprising:
passing a hydrocarbon stream to a first loop of a caustic tower, wherein the hydrocarbon stream comprises one or more hydrocarbons, one or more oxygen containing components, and one or more acid gas components;
removing a portion of the one or more acid gas components in the first loop of the caustic tower to produce a first product stream;
passing the first product stream from the first loop of the caustic tower to a hydrogenation unit;
contacting the first product stream with a sulfided catalyst in the hydrogenation unit to produce a second product stream, wherein at least a portion of one or more sulfur containing compounds reacts in the presence of the sulfided catalyst to produce hydrogen sulfide in the second product stream;
passing the second product stream to a second loop of the caustic tower; and
removing at least a portion of the hydrogen sulfide in the second product stream in the second loop of the caustic tower to produce a third product stream.

13. The method of claim 12 , further comprising:
contacting a hydrocarbon feed stream with a cracking catalyst in a fluid catalytic cracking unit;
generating a fourth product stream comprising olefins in the fluid catalytic cracking unit;
separating the fourth product stream to produce a dry gas stream, wherein the dry gas stream comprises at least a portion of the olefins;
passing the dry gas stream to a steam cracking unit; generating the hydrocarbon stream in the steam cracking unit; and
passing the hydrocarbon stream to the caustic tower.

14. The method of claim 13 , further comprising:
separating the third product stream into a plurality of hydrocarbon streams in a separation system located downstream of the caustic tower.

Assignees

• Fluor Tech Corp

Inventors

• Dierickx Jan

Classifications

• C10G29/04

  Metals, or metals deposited on a carrier · CPC title

• C10G67/14

  including at least two different refining steps in the absence of hydrogen · CPC title

• C10G2300/4087

  Catalytic distillation · CPC title

• C10G2300/207

  Acid gases, e.g. H2S, COS, SO2, HCN · CPC title

• C10G19/02

  with aqueous alkaline solutions · CPC title