Living radical polymerization catalyst, and polymer production method using same

Patent metadata

Field	Value
Publication number	US-9926386-B2
Application number	US-201515117640-A
Country	US
Kind code	B2
Filing date	Feb 10, 2015
Priority date	Feb 13, 2014
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

An object of the present invention is to provide a living radical polymerization catalyst that is excellent in terms of safety and cost, and is applicable to various vinyl monomers, and to provide a method for producing a polymer using this living radical polymerization catalyst. The living radical polymerization catalyst contains at least one member selected from the group consisting of alkali metal halide compounds and alkaline earth metal halide compounds.

First claim

The invention claimed is:

1. A living radical polymerization catalyst consisting of at least one member selected from the group consisting of alkali metal halide compounds and alkaline earth metal halide compounds.

2. The living radical polymerization catalyst according to claim 1 , consisting of at least one member selected from the group consisting of alkali metal iodide compounds and alkaline earth metal iodide compounds.

3. The living radical polymerization catalyst according to claim 1 , consisting of at least one member selected from the group consisting of sodium iodide and potassium iodide.

4. A method for producing a polymer by living radical polymerization of one or more radically polymerizable monomers, the method comprising:
a step of performing living radical polymerization using the living radical polymerization catalyst of claim 1 .

5. The method for producing a polymer according to claim 4 , wherein the catalyst is used in an amount of 0.000125 to 1 mol, per mole of the one or more radically polymerizable monomers.

6. The method for producing a polymer according to claim 4 , wherein the living radical polymerization reaction is further performed by adding a polyether compound.

7. The method for producing a polymer according to claim 6 , wherein the polyether compound is used in an amount of 1 mol or more, per mole of the living radical polymerization catalyst, and 10000 parts by weight or less, per 100 parts by weight of the one or more radically polymerizable monomers.

8. The living radical polymerization catalyst according to claim 2 , consisting of at least one member selected from the group consisting of sodium iodide and potassium iodide.

9. A method for producing a polymer by living radical polymerization of one or more radically polymerizable monomers, the method comprising:
a step of performing living radical polymerization using the living radical polymerization catalyst of claim 2 .

10. A method for producing a polymer by living radical polymerization of one or more radically polymerizable monomers, the method comprising:
a step of performing living radical polymerization using the living radical polymerization catalyst of claim 3 .

11. The method for producing a polymer according to claim 5 , wherein the living radical polymerization reaction is further performed by adding a polyether compound.

Assignees

• Univ Kyoto

Inventors

• Goto Atsushi

Classifications

• C08F2438/01

  Atom Transfer Radical Polymerization [ATRP] or reverse ATRP · CPC title

• C08F4/04

  Azo-compounds · CPC title

• C08F120/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08F2438/00

  Living radical polymerisation · CPC title

• B01J27/138

  with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury · CPC title