Environmental barrier for a refractory substrate containing silicon

Patent metadata

Field	Value
Publication number	US-9926238-B2
Application number	US-201414897471-A
Country	US
Kind code	B2
Filing date	Jun 11, 2014
Priority date	Jun 13, 2013
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

A part including a substrate in which at least a portion adjacent to a surface of the substrate is made of a refractory material containing silicon, is protected by an environmental barrier formed on the surface of the substrate and having at least a self-healing layer containing a rare earth silicate. The self-healing layer is formed: for at least 90 mol %, by a system constituted by 30 mol % to at most 80 mol % of at least one rare earth silicate RE 2 Si 2 O 7 , RE being a rare earth, and at least 20 mol % to 70 mol % of manganese oxide MnO; and for at most 10 mol %, by one or more oxides other than MnO, having a eutectic point with SiO2 less than or equal to 1595° C.; the self-healing layer presenting a liquid phase having a self-healing function at least throughout the temperature range 1200° C. to 1400° C., while conserving a majority solid phase.

First claim

The invention claimed is:

1. A part comprising a substrate in which at least a portion adjacent to a surface of the substrate is made of a refractory material containing silicon, and an environmental barrier formed on the surface of the substrate and having at least a self-healing layer containing a rare earth silicate, wherein the self-healing layer is formed:
for at least 90 mol %, by a system constituted by 30 mol % to at most 80 mol % of at least one rare earth silicate RE 2 Si 2 O 7 , RE being a rare earth, and at least 20 mol % to 70 mol % of manganese oxide MnO; and
for at most 10 mol %, by one or more oxides other than MnO, having a eutectic point with SiO 2 less than or equal to 1595° C., said one or more oxides, when present, being selected from Ga 2 O 3 , In 2 O 3 , Nb 2 O 5 , ZnO and Ta 2 O 5 ;
the self-healing layer presenting a liquid phase having a self-healing function at least throughout the temperature range 1200° C. to 1400° C., while conserving a majority solid phase.

2. A part according to claim 1 , wherein RE is selected from yttrium, scandium, and the lanthanides.

3. A part according to claim 1 , wherein the environmental barrier further comprises an underlayer interposed between the surface of the substrate and the self-healing layer, and selected from:
an underlayer essentially constituted by at least one rare earth silicate RE 2 Si 2 O 7 ;
an underlayer constituted by at least one rare earth silicate RE 2 Si 2 O 7 deposited on a silicon coating formed on the substrate;
an underlayer essentially constituted by mullite;
an underlayer essentially constituted by mullite deposited on a silicon coating formed on the substrate; and
an underlayer essentially having a silicon-mullite composition gradient starting from silicon beside the substrate and ending with mullite beside the self-healing layer.

4. A part according to claim 1 , wherein the self-healing layer is interposed between the substrate and an external layer of refractory material.

5. A part according to claim 1 , wherein the self-healing layer is interposed between the substrate and an external layer of abradable material.

6. A part according to claim 1 , wherein RE is yttrium.

7. A part according to claim 1 , wherein the substrate is made of a ceramic matrix composite material having fiber reinforcement.

8. A part according to claim 7 , wherein the matrix is made up of a plurality of different layers.

9. A method of providing a substrate in which at least a portion adjacent to a surface is made of a refractory material containing silicon, with protection while the substrate is in use at high temperature in an oxidizing medium, by forming an environmental barrier on the surface of the substrate, the barrier having at least a self-healing layer containing a rare earth silicate, wherein the self-healing layer is formed:
for at least 90 mol %, by a system constituted by 30 mol % to at most 80 mol % of at least one rare earth silicate RE 2 Si 2 O 7 , RE being a rare earth, and at least 20 mol % to 70 mol % of manganese oxide MnO; and
for at most 10 mol %, by one or more oxides other than MnO, having a eutectic point with SiO 2 less than or equal to 1595° C., said one or more oxides, when present, being selected from Ga 2 O 3 , In 2 O 3 , Nb 2 O 5 , ZnO and Ta 2 O 5 ;
so as to obtain a self-healing layer presenting a liquid phase having a self-healing function at least throughout the temperature range 1200° C. to 1400° C., while conserving a majority solid phase.

10. A method according to claim 9 , wherein RE is selected from yttrium, scandium, and the lanthanides.

11. A method according to claim 9 , wherein an environmental barrier is formed also having a sublayer interposed between the surface of the substrate and the self-healing layer, the sublayer being selected from:
an underlayer essentially constituted by at least one rare earth silicate RE 2 Si 2 O 7 ;
an underlayer constituted by at least one rare earth silicate RE 2 Si 2 O 7 deposited on a silicon coating formed on the substrate;
an underlayer essentially constituted by mullite;
an underlayer essentially constituted by mullite deposited on a silicon coating formed on the substrate; and
an underlayer essentially having a silicon-mullite composition gradient starting from silicon beside the substrate and ending with mullite beside the self-healing layer.

12. A method according to claim 9 , wherein an external layer of refractory material is formed on the self-healing layer.

13. A method according to claim 9 , wherein an external layer of abradable material is formed on the self-healing layer.

Assignees

• Herakles
• Univ Bordeaux

Inventors

• Louchet Caroline
• Courcot Emilie
• Rebillat Francis
• Delehouze Arnaud

Classifications

• C04B41/5027

  Oxide ceramics in general; Specific oxide ceramics not covered by C04B41/5029 - C04B41/5051 · CPC title

• C04B41/52

  Multiple coating or impregnating {multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation} · CPC title

• C04B41/4525

  using a molten bath as vehicle, e.g. molten borax · CPC title

• C04B41/5024

  Silicates (C04B41/5022 takes precedence; silico-fluorides C04B41/5018) · CPC title

• C04B41/5037

  Clay, Kaolin · CPC title