Systems and methods for recovering ammonium and phosphorus from liquid effluents

Patent metadata

Field	Value
Publication number	US-9926213-B2
Application number	US-201615170129-A
Country	US
Kind code	B2
Filing date	Jun 1, 2016
Priority date	Jun 1, 2015
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

A system and method for capture of ammonia and phosphorus from an ammonia and phosphorus containing liquid effluent. The invention allows for the precipitation of phosphorus from said liquid effluent that has been under low aeration and has a pH of greater than about pH 9.

First claim

We claim:

1. A system for reducing ammonia and phosphorus concentration in liquid effluents comprising:
at least one gas permeable membrane manifold in an ammonia removal tank allowing for the diffusion of ammonia gas from said liquid effluent into said membrane in said manifold;
a first reservoir containing a stripping solution;
a first delivery system for (i) delivering the stripping solution from the first reservoir to said membrane manifold to chemically change the ammonia gas to ammonia salts, and (ii) for carrying the salts to said first reservoir containing said stripping solution, wherein said delivery system comprises (a) a pump having an intake end and a discharge end, (b) a first hollow tube having one end attached to the discharge end of the pump and a second end attached to a first side of said gas permeable membrane manifold, and (c) a second hollow tube having a first end attached to a second side of said gas permeable membrane and a second end disposed above or in said first reservoir for discharging ammonium salts to said first reservoir;
a second reservoir containing a phosphorous precipitating agent; and
a second delivery system for adding the phosphorus precipitating agent to said effluent.

2. The system of claim 1 , wherein the liquid effluent contains an amount of phosphorus, and
wherein the second delivery system is configured to add the phosphorus precipitating agent to the liquid effluent in an amount to precipitate at least about 93% of the amount of phosphorus in said liquid effluent.

3. The system of claim 1 further comprising a phosphorus removal tank,
wherein said phosphorus precipitating agent is added to said phosphorus removal tank receiving liquid effluent from said ammonia removal tank having said gas permeable membrane manifold, and
wherein said effluent has been stripped of ammonia and has a pH greater than about 9.

4. The system of claim 1 wherein said phosphorus precipitating agent is added to said ammonia removal tank of said system wherein said ammonia removal tank contains an ammonia and phosphorus containing liquid effluent under low aeration having a pH greater than about 9.5.

5. A method for producing ammonium salt and phosphorus from an ammonia- and phosphorus-containing liquid effluent comprising:
ammonium recovery; and
phosphorus recovery,
wherein the ammonium recovery comprises:
(1) capturing ammonia from the liquid effluent within the confines of a gas-permeable membrane manifold, and
(2) causing a stripping solution stored in a reservoir to contact said ammonia to produce ammonium salts and transporting the salts to the reservoir for collection, and

wherein the phosphorus recovery comprises:
(1) adding a phosphorus precipitating agent to said liquid effluent and allowing said precipitated phosphorus to settle in a tank, and
(2) collecting said precipitated phosphorus.

6. The method of claim 5 , wherein the ammonium recovery is conducted prior to the phosphorus recovery.

7. The method of claim 5 , wherein the ammonium recovery is conducted substantially simultaneously with the phosphorus recovery.

8. The method of claim 5 , further comprising providing low rate aeration of the liquid effluent.

9. The method of claim 5 , wherein the phosphorus precipitating agent is magnesium chloride.

10. The method of claim 5 , further comprising adding a nitrification inhibitor to the effluent.

11. The system of claim 1 , further comprising a blower connected to the ammonia removal tank, the blower being configured to provide low rate aeration to the effluent in the ammonia removal tank.

12. The system of claim 1 , wherein the phosphorus precipitating agent is magnesium chloride.

13. The system of claim 1 , wherein the ammonia removal tank in configured to allow the addition of a nitrification inhibitor into the ammonia removal tank.

Assignees

• Us Agriculture

Inventors

• Vanotti Matias B
• Szogi Ariel A
• Dube Patrick J

Classifications

• C02F1/20

  by degassing, i.e. liberation of dissolved gases (degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D) · CPC title

• C02F2101/105

  Phosphorus compounds · CPC title

• C02F9/00

  Multistage treatment of water, waste water or sewage · CPC title

• C02F2209/06

  pH · CPC title

• C02F1/5254

  using magnesium compounds and phosphoric acid for removing ammonia · CPC title