Aerogels, calcined and crystalline articles and methods of making the same

Patent metadata

Field	Value
Publication number	US-9925126-B2
Application number	US-201715486579-A
Country	US
Kind code	B2
Filing date	Apr 13, 2017
Priority date	Oct 10, 2011
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

Aerogel, calcined articles, and crystalline articles comprising ZrO 2 . Exemplary uses of the crystalline metal oxide articles include dental articles (e.g., restoratives, replacements, inlays, onlays, veneers, full and partial crowns, bridges, implants, implant abutments, copings, anterior fillings, posterior fillings, and cavity liner, and bridge frameworks) and orthodontic appliances (e.g., brackets, buccal tubes, cleats, and buttons).

First claim

What is claimed is:

1. A monolithic aerogel comprising organic material and crystalline metal oxide particles, wherein the crystalline metal oxide particles are in a range from 3 to 20 volume percent, based on the total volume of the monolithic aerogel, wherein at least 70 mole percent of the crystalline metal oxide is ZrO 2 .

2. The monolithic aerogel of claim 1 , wherein the crystalline metal oxide particles comprise 1 to 15 mole percent Y 2 O 3 .

3. The monolithic aerogel of claim 1 , wherein the crystalline metal oxide particles have an average primary particle size in a range of 2 nanometers to 50 nanometers.

4. The monolithic aerogel of claim 1 , wherein the crystalline material further comprises at least one of Y 2 O 3 or La 2 O 3 .

5. The monolithic aerogel of claim 1 , wherein the ZrO 2 is all tetragonal or cubic.

6. The monolithic aerogel of claim 1 , wherein the organic content in a range of 3 to 30 percent by weight, based on the total weight of the aerogel.

7. The monolithic aerogel of claim 1 , wherein the aerogel has a surface area in a range of 100 m 2 /gram to 300 m 2 /gram.

8. The monolithic aerogel of claim 1 , wherein an average connected pore size is in a range of 10 nanometers to 20 nanometers.

9. The monolithic aerogel of claim 1 , wherein the aerogel is crack-free.

10. The monolithic aerogel of claim 1 , wherein the organic material content is in a range of 3 to 30 weight percent, based on a total weight of the aerogel.

11. The monolithic aerogel of claim 1 , wherein the crystalline metal oxide particles further comprise at least one of Fe 2 O 3 , MnO 2 , Co 2 O 3 , Cr 2 O 3 , NiO, CuO, Bi 2 O 3 , Ga 2 O 3 , Er 2 O 3 , Pr 2 O 3 , Eu 2 O 3 , Dy 2 O 3 , Sm 2 O 3 , or CeO 2 .

12. The monolithic aerogel of claim 1 , wherein the crystalline metal oxide particles further comprise at least one of CeO 2 , Pr 2 O 3 , Nd 2 O 3 , Pm 2 O 3 , Sm 2 O 3 , Eu 2 O 3 , Gd 2 O 3 , Tb 2 O 3 , Dy 2 O 3, Ho 2 O 3 , Er 2 O 3 , Tm 2 O 3 , Yb 2 O 3 , Fe 2 O 3 , MnO 2 , Co 2 O 3 , Cr 2 O 3 , NiO, CuO, Bi 2 O 3 , Ga 2 O 3 , or Lu 2 O 3 .

13. The monolithic aerogel of claim 1 , wherein the organic material comprises a polymer prepared from one or more radically polymerizable monomers.

14. The monolithic aerogel of claim 13 , wherein the one or more radically polymerizable monomers comprise a radically polymerizable surface modifier for ZrO 2 .

15. The monolithic aerogel of claim 1 , wherein the crystalline metal oxide particles are surface modified.

16. A method of making an aerogel comprising organic material and crystalline metal oxide particles, wherein the crystalline metal oxide particles are in a range from 3 to 20 volume percent, based on the total volume of the aerogel, wherein at least 70 mole percent of the crystalline metal oxide is ZrO 2 , the method comprising:
providing a first zirconia sol comprising crystalline metal oxide particles having an average primary particle size of not greater than 50 nanometers, wherein at least 70 mole percent of the crystalline metal oxide is ZrO 2 ,
optionally concentrating the first zirconia sol to provide as concentrated zirconia sol;
adding a radically reactive surface modifier to the zirconia sol to provide a radically polymerizable surface-modified zirconia sol;
adding a radical initiator to the radically polymerizable surface-modified zirconia sol;
heating at least one temperature for a time sufficient to polymerize the radically surface-modified zirconia sol comprising the radical initiator to form a gel;
optionally removing water, if present, from the gel via alcohol exchange to provide an at least partially de-watered gel; and
extracting alcohol, if present, from the gel via super critical extraction to provide the aerogel.

17. The method of claim 16 , further comprising adding a radically reactive co-monomer to the concentrated zirconia sol.

Assignees

• 3M Innovative Properties Co

Inventors

• Kolb Brant U
• Feisel Bryan C
• Goetzinger Martin
• Hall Philip S
• Hauptmann Holger
• Hendrickson Mark J
• Humpal Kathleen M
• Longabach John W
• Mathers James P
• Naujok Roberta R
• Pennington Paul D
• Schechner Gallus

Classifications

• A61K6/818 Primary

  comprising zirconium oxide · CPC title

• A61K6/17

  Particle size · CPC title

• A61K6/887

  Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• A61K6/822

  comprising rare earth metal oxides · CPC title

• A61K6/15

  Compositions characterised by their physical properties · CPC title