Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

Patent metadata

Field	Value
Publication number	US-9924716-B2
Application number	US-201715408682-A
Country	US
Kind code	B2
Filing date	Jan 18, 2017
Priority date	Jan 25, 2016
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, compositions containing such molecules, and processes of using such molecules and compositions against such pests. These molecules and compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

First claim

The invention claimed is:

1. A molecule having the following formula

wherein:
(A) R 1 , R 5 , R 6 , R 11 , R 12 , R 13 , and R 14 are each independently selected from the group consisting of H, F, Cl, Br, I, CN, (C 1 -C 4 )alkyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, and (C 1 -C 4 )haloalkoxy;
(B) R 2 , R 3 , and R 4 are each independently selected from the group consisting of H, F, Cl, Br, I, CN, (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 2 -C 4 )alkynyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, and (C 1 -C 4 )haloalkoxy;
(C) R 7 is (C 1 -C 6 )haloalkyl;
(D) R 9 is selected from the group consisting of H, F, Cl, Br, I, CN, (C 1 -C 4 )alkyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, and (C 1 -C 4 )haloalkoxy;
(E) R 10 is selected from the group consisting of F, Cl, Br, I, CN, (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 2 -C 4 )alkynyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, and (C 1 -C 4 )haloalkoxy;
(F) R 9 and R 10 together can optionally form a 3- to 5-membered saturated or unsaturated, hydrocarbyl link,
wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, I, and CN;
(G) L is (C 1 -C 6 )alkyl;
(H) X is selected from the group consisting of C, S, and P(C 1 -C 6 )alkyl;
(I) n is 1 or 2;
(J) R 15 is selected from the group consisting of (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 3 -C 4 )cycloalkyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, (C 1 -C 4 )haloalkoxy, phenyl, and NH(C 3 -C 4 )cycloalkyl,
wherein each alkyl, alkenyl, cycloalkyl, haloalkyl, alkoxy, haloalkoxy, and phenyl may optionally be substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, I, CN, and OH; and

agriculturally acceptable acid addition salts, salt derivatives, solvates, ester derivatives, crystal polymorphs, isotopes, resolved stereoisomers, and tautomers, of the molecules of Formula One.

2. A molecule according to claim 1 wherein R 1 , R 3 , R 4 , R 5 , R 6 , R 9 , R 11 , R 12 , R 13 , and R 14 are H.

3. A molecule according to claim 1 wherein R 2 is Cl, Br, or CH 3 .

4. A molecule according to claim 1 wherein R 3 is F, Cl, Br, or CH═CH 2 .

5. A molecule according to claim 1 wherein R 4 is Cl, Br, or CH 3 .

6. A molecule according to claim 1 wherein R 2 , R 3 , and R 4 are Cl.

7. A molecule according to claim 1 wherein R 7 is CF 3 , CF 2 CH 3 , or CF 2 CH 2 CH 3 .

8. A molecule according to claim 1 wherein R 10 is Cl, Br, I, CH 3 , or CF 3 .

9. A molecule according to claim 1 wherein L is CH(CH 3 ) or CH(CH 2 CH 3 ).

10. A molecule according to claim 1 wherein X is C or S.

11. A molecule according to claim 1 wherein n is 1.

12. A molecule according to claim 1 wherein R 15 is CH 2 CH 3 , cyclopropyl, CH 2 CF 3 , CH 2 CH 2 CF 3 , or NHcyclopropyl.

13. A molecule according to claim 1 wherein
(A) R 1 , R 5 , R 6 , R 11 , R 12 , R 13 , and R 14 are H;
(B) R 2 , R 3 , and R 4 are each independently selected from the group consisting of H, F, Cl, Br, (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl;
(C) R 7 is (C 1 -C 6 )haloalkyl;
(D) R 9 is H;
(E) R 10 is selected from the group consisting of Cl, Br, (C 1 -C 4 )alkyl, and (C 1 -C 4 )haloalkyl;
(G) L is (C 1 -C 6 )alkyl;
(H) X is C or S;
(I) n is 1 or 2;
(J) R 15 is selected from the group consisting of (C 1 -C 4 )alkyl, (C 3 -C 4 )cycloalkyl, (C 1 -C 4 )haloalkyl, and NH(C 3 -C 4 )cycloalkyl,
wherein each alkyl, alkenyl, cycloalkyl, haloalkyl, alkoxy, haloalkoxy, and phenyl may optionally be substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, I, CN, and OH.

14. A molecule according to claim 1 wherein said molecule is selected from one of the molecules in the following Table

No.
Structure

F1

F2

F3

F4

F5

F6

F7

F8

F9

F10

F11

F12

Assignees

• Dow Agrosciences Llc

Inventors

• Barton Thomas
• Gao Xin
• Hunter Jim
• Leplae Jr Paul R
• Lo William C
• Boruwa Joshodeep
• Tangirala Raghuram
• Watson Gerald B
• Herbert John

Classifications

• A61P33/14

  Ectoparasiticides, e.g. scabicides · CPC title

• A61P33/10

  Anthelmintics · CPC title

• A01N37/26 Primary

  containing the group [IMAGE cpc-sch-A01N-0936.gif]; Thio analogues thereof · CPC title

• C07C311/09

  the carbon skeleton being further substituted by at least two halogen atoms · CPC title

• C07F9/36

  Amides thereof · CPC title