Method of decontaminating a fuel reactant stream for a fuel cell

Patent metadata

Field	Value
Publication number	US-9923221-B2
Application number	US-201615378642-A
Country	US
Kind code	B2
Filing date	Dec 14, 2016
Priority date	Apr 27, 2009
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

An example method of decontaminating a fuel reactant stream for a fuel cell flows the fuel reactant stream through a fluidized ammonia dissolving media, while simultaneously flowing water through the fluidized ammonia dissolving media to separate contaminants from the fuel reactant stream into a separated contaminant and water stream. The separated contaminant and water stream from the fluidized bed is accumulated within an accumulator, circulated through a water-control loop, and decontaminated by flowing the stream through an ion exchange bed secured in fluid communication with the water-control loop. A decontaminated water stream from the ion exchange bed is circulated back through the ammonia dissolving media. A temperature of the fuel reactant stream is controlled upstream of the fuel reactant stream entering the separator scrubber to produce a predetermined temperature of the fuel reactant stream passing through the separator scrubber.

First claim

What is claimed is:

1. A method of decontaminating a fuel reactant stream for a fuel cell, comprising:
flowing the fuel reactant stream through a fluidized ammonia dissolving media within a fluidized bed that dissolves ammonia and removes particulates from the fuel reactant stream within a separator scrubber, while simultaneously flowing water through the fluidized ammonia dissolving media within the fluidized bed to separate contaminants from the fuel reactant stream into a separated contaminant and water stream;
accumulating the separated contaminant and water stream from the fluidized bed within an accumulator;
circulating the separated contaminant and water stream from the accumulator through a water-control loop;
decontaminating the separated contaminant and water stream by flowing the stream through an ion exchange bed secured in fluid communication with the water-control loop;
circulating a decontaminated water stream from the ion exchange bed back through the ammonia dissolving media; and
controlling a temperature of the fuel reactant stream upstream of the fuel reactant stream entering the separator scrubber to produce a predetermined temperature of the fuel reactant stream passing through the separator scrubber.

2. The method of claim 1 , comprising adding an ammonia solubility enhancing reagent to the ammonia dissolving media within the separator scrubber.

3. The method of claim 1 , comprising replacing the ion exchange bed exchange material at predetermined time intervals.

4. The method of claim 1 , comprising selecting a volume of the ion exchange bed ion exchange material so that the volume of ion exchange material within the bed may be replaced at predetermined time intervals.

5. The method of claim 1 , wherein said controlling the temperature of the fuel reactant stream upstream of the fuel reactant stream entering the separator scrubber comprises controlling the temperature of the fuel reactant stream upstream of booth the separator scrubber and the water-control loop.

6. The method of claim 1 , comprising sensing information from the fuel reactant stream, wherein said controlling a temperature of the fuel reactant stream upstream of the fuel reactant stream entering the separator scrubber is performed based on the sensed information.

7. The method of claim 6 , wherein the sensed information includes at least one of a temperature of the fuel reactant stream, a moisture content of the fuel reactant stream, and a water level of the fuel reactant stream.

8. The method of claim 1 :
wherein said controlling a temperature of the fuel reactant stream upstream of the fuel reactant stream entering the separator scrubber comprises cooling the fuel reactant stream with a first heat exchanger upstream of the separator scrubber; and
wherein the method comprises heating the fuel reactant stream with a different, second heat exchanger downstream of the separator scrubber.

9. The method of claim 8 , comprising:
pumping coolant through a coolant loop conduit from a coolant plate secured adjacent to the fuel cell, through a coolant heat exchanger configured to remove heat from the coolant, and back to the coolant plate;
wherein said heating the fuel reactant stream with a different, second heat exchanger downstream of the separator scrubber comprises directing a flow of coolant from the coolant loop conduit to be in heat exchange relationship with the fuel reactant stream downstream of the separator scrubber.

10. The method of claim 1 , comprising selectively discharging excess water out of the water-control loop through a water discharge valve that is in fluid communication with the water-control loop.

11. The method of claim 1 , wherein the ion exchange bed includes a cation-only exchange resin.

12. A method of decontaminating a fuel reactant stream for a fuel cell, the method comprising:
directing the fuel reactant stream into a fluidized ammonia dissolving media within a fluidized bed;
removing contaminants from the fuel reactant stream within a separator scrubber;
directing water through the fluidized ammonia dissolving media to separate contaminants from the fuel reactant stream into a separated contaminant and water stream;
decontaminating the separated contaminant and water stream using an ion exchange bed;
circulating a decontaminated water stream from the ion exchange bed back through the ammonia dissolving media; and
controlling a temperature of the fuel reactant stream upstream of the fuel reactant stream entering the separator scrubber to produce a predetermined temperature of the fuel reactant stream entering the separator scrubber.

Assignees

• Doosan Fuel Cell America Inc
• Doosan Fuel Cell Amreica Inc

Inventors

• Isom Joshua D
• Vandine Leslie L
• Hildreth Derek W
• Preston John L
• Hanrahan Paul R
• Hamilton Lynn

Classifications

• B01D53/1425

  Regeneration of liquid absorbents · CPC title

• H01M8/0687 Primary

  Reactant purification by the use of membranes or filters · CPC title

• H01M8/04708

  of fuel cell reactants · CPC title

• B01D53/1412

  Controlling the absorption process · CPC title

• H01M8/04014

  Heat exchange using gaseous fluids; Heat exchange by combustion of reactants · CPC title