Powder for powder magnetic core, and powder magnetic core

Patent metadata

Field	Value
Publication number	US-9922758-B2
Application number	US-201314406288-A
Country	US
Kind code	B2
Filing date	Jul 9, 2013
Priority date	Jul 20, 2012
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

A powder for a powder magnetic core, being composed of iron-base soft magnetic powder particles which each have a phosphoric acid-based chemical conversion coating on the surface. In this powder, the maximum thickness of the phosphoric acid-based chemical conversion coating is 20 to 200 nm, and recessed portions are formed on the surface of the chemical conversion coating with the total area of openings of the recessed portions being 0.5 to 50% by area relative to the total area of the observation visual fields, as determined by observing ten or more parts of the surface of the phosphoric acid-based chemical conversion coating through a scanning electron microscope with a magnification of 10000× or more.

First claim

The invention claimed is:

1. A powder, comprising
iron-based soft magnetic powder particles comprising a phosphoric acid-based chemical conversion coating on a surface thereof,
wherein
the phosphoric acid-based chemical conversion coating has a non-uniform thickness and recessed portions are formed on a surface of the phosphoric acid-based chemical conversion coating,
the phosphoric acid-based chemical conversion coating has a maximum thickness of 20-200 nm, and
the recessed portions form openings on the surface of the phosphoric acid-based chemical conversion coating, the openings having a total area of 0.5-50% relative to a total area of field of view when ten or more positions of the surface of the phosphoric acid-based chemical conversion coating are observed under a scanning electron microscope of 10,000 or more magnifications.

2. The powder according to claim 1 , wherein
the openings are of a generally circular shape having an average circle equivalent diameter of 50-1,000 nm; and
when 10 or more positions of a region of 5 μm×5 μm on the surface of the phosphoric acid-based chemical conversion coating are observed, a number of the openings is 10 or more on average, or
when 10 or more positions of a cross section of the phosphoric acid-based chemical conversion coating are observed, a number of the openings is one or more on average per 5 μm surface length of the iron-based soft magnetic powder particles.

3. A powder magnetic core, obtained by a process comprising
compressively forming a powder, which comprises iron-based soft magnetic powder particles having a phosphoric acid-based chemical conversion coating on a surface thereof,
wherein
the phosphoric acid-based chemical conversion coating has a non-uniform thickness and recessed portions are formed on a surface of the phosphoric acid-based chemical conversion coating,
when a broken-out section of the powder magnetic core is observed, in a portion surrounded by three or more of the iron-based soft magnetic powder particles:
the phosphoric acid-based chemical conversion coating has a maximum thickness of 20-200 nm;
the recessed portions form openings on the surface of the phosphoric acid-based chemical conversion coating; and
a total length of surface of the three or more iron-based soft magnetic powder particles where the phosphoric acid-based chemical conversion coating is adhered is 50% or more relative to a total length of the surface of the three or more iron-based soft magnetic powder particles; and

in the portion surrounded by three or more of the iron-based soft magnetic powder particles:
one or more on average recessed portions comprising 50-1,000 nm-wide openings are present per 5 μm length of the surface of the iron-based soft magnetic powder particles in the phosphoric acid-based chemical conversion coating;
a first oxide layer, the phosphoric acid-based chemical conversion coating, and a second oxide layer are laminated in this order on the surface of the iron-based soft magnetic powder particles where the phosphoric acid-based chemical conversion coating is adhered; and
a thickness of the first oxide layer is 200 nm or less.

4. The powder according to claim 1 , wherein the phosphoric acid-based chemical conversion coating contains Ni.

5. The powder according to claim 1 , further comprising
a silicone resin coating on the phosphoric acid-based chemical conversion coating.

6. The powder magnetic core according to claim 3 , wherein the phosphoric acid-based chemical conversion coating contains Ni.

7. The powder according to claim 5 , wherein the silicon resin coating has a thickness of 1-200 nm.

8. A powder magnetic core, obtained by a process comprising
compressively forming the powder according to claim 1 .

9. The powder magnetic core according to claim 3 , wherein the powder further comprises a silicone resin coating on the phosphoric acid-based chemical conversion coating.

10. The powder according to claim 1 , wherein the recessed portions are portions of the phosphoric acid-based chemical conversion coating having a thickness which is 50% or less of the maximum thickness of the phosphoric acid-based chemical conversion coating.

11. The powder according to claim 5 , wherein a total thickness of the phosphoric acid-based chemical conversion coating and the silicon resin coating is 250 nm or less.

12. The powder magnetic core according to claim 3 , wherein the recessed portions are portions of the phosphoric acid-based chemical conversion coating having a thickness which is 50% or less of the maximum thickness of the phosphoric acid-based chemical conversion coating.

13. The powder magnetic core according to claim 9 , wherein the silicon resin coating has a thickness of 1-200 nm.

14. The powder magnetic core according to claim 9 , wherein a total thickness of the phosphoric acid-based chemical conversion coating and the silicon resin coating is 250 nm or less.

Assignees

• Kobe Steel Ltd

Inventors

• Urushihara Wataru
• Takeda Mikako
• Hosokawa Mamoru
• Hojo Hirofumi
• Kamijo Tomotsuna

Classifications

• B22F1/16

  Metallic particles coated with a non-metal (coated with lubricating or binding agents or with organic material B22F1/10) · CPC title

• B22F1/102

  Metallic powder coated with organic material · CPC title

• H01F1/26

  by macromolecular organic substances · CPC title

• C23C22/07

  containing phosphates · CPC title

• C23C22/23

  Condensed phosphates · CPC title