Mixing column for single mixed refrigerant (SMR) process

Patent metadata

Field	Value
Publication number	US-9920987-B2
Application number	US-201514707773-A
Country	US
Kind code	B2
Filing date	May 8, 2015
Priority date	May 8, 2015
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

A system and method of gas liquefaction having a compression sequence for a mixed refrigerant in which a mixing column is used to provide liquid and vapor product streams at least one step of the compression sequence in which a phase separation is desirable. In addition, the compression sequence may optionally or alternatively use a stripper column in at least one step in the compression sequence in which a phase separation is desirable.

First claim

What is claimed is:

1. A method comprising:
(a) cooling a hydrocarbon fluid in a main heat exchanger against a mixed refrigerant, the cooling of the hydrocarbon feed gas producing a product stream;
(b) withdrawing a low pressure mixed refrigerant stream from the main heat exchanger;
(c) compressing the low pressure mixed refrigerant stream in at least two compression stages in at least one compressor to produce a medium pressure mixed refrigerant stream and high pressure vapor mixed refrigerant stream;
(d) cooling the medium pressure mixed refrigerant stream to produce a medium pressure two phase mixed refrigerant stream;
(e) cooling the high pressure vapor mixed refrigerant stream to produce a high pressure two phase mixed refrigerant stream;
(f) separating the high pressure two phase mixed refrigerant stream into a high pressure liquid mixed refrigerant stream and a high pressure vapor mixed refrigerant stream;
(g) introducing at least a portion of the medium pressure two phase mixed refrigerant stream into a top end of a mixing column and the high pressure liquid mixed refrigerant stream into a bottom end of the mixing column, wherein the mixing column comprises a plurality of equilibrium stages comprising trays, packing, or a combination thereof;
(h) withdrawing a medium pressure liquid mixed refrigerant stream from a bottom end of the mixing column and a medium pressure vapor mixed refrigerant stream from a top end of the mixing column, wherein the medium pressure liquid mixed refrigerant stream withdrawn from the bottom end of the mixing column is 5-15 degrees Celsius colder than the medium pressure vapor mixed refrigerant stream withdrawn from the top end of the mixing column; and
(i) supplying at least a portion of the medium pressure liquid mixed refrigerant stream and at least a portion of the high pressure vapor mixed refrigerant stream to the main heat exchangers;
wherein the mixed refrigerant of step (a) is a fluid comprising at least two hydrocarbons.

2. The method of claim 1 , further comprising:
(j) after withdrawing the medium pressure vapor mixed refrigerant stream from the mixing column, compressing the medium pressure vapor mixed refrigerant stream to form a portion of the high pressure vapor mixed refrigerant stream.

3. The method of claim 1 , wherein step (a) comprises liquefying a hydrocarbon feed gas and a mixed refrigerant flowing through a coil wound tube side of a main heat exchanger by indirect heat exchange with the mixed refrigerant flowing through a shell side of the main heat exchanger, the cooling of the hydrocarbon feed gas producing a product stream.

4. The method of claim 3 , wherein step (c) comprises withdrawing at least one cooled refrigerant stream from the coil wound tube side of the main heat exchanger at a top end of at least one of a plurality of tube bundles, reducing a pressure of the at least one cooled refrigerant stream, then supplying the reduced pressure at least one cooled refrigerant stream to the shell side of the main heat exchanger to irrigate at least one the plurality of tube bundles.

5. The method of claim 3 , wherein step (b) comprises withdrawing a shell side mixed refrigerant stream from a shell side of the main heat exchanger at a warm end of the main heat exchanger.

6. The method of claim 3 , further comprising:
(k) withdrawing at least one cooled mixed refrigerant stream from the coil wound tube side of the main heat exchanger, reducing a pressure of the at least one cooled mixed refrigerant stream, then supplying the reduced pressure at least one cooled mixed refrigerant to the shell side of the main heat exchanger.

7. The method of claim 1 , further comprising:
(l) expanding the high pressure liquid mixed refrigerant stream before performing step (g).

8. The method of claim 1 , wherein step (g) comprises separating the medium pressure two phase mixed refrigerant stream into a medium pressure vapor mixed refrigerant stream and a medium pressure liquid mixed refrigerant stream, introducing the medium pressure liquid mixed refrigerant stream and the high pressure liquid mixed refrigerant stream into the mixing column.

9. The method of claim 1 , further comprising:
(m) separating the product stream into a cold vapor stream and a liquid product stream;
(n) supplying the cold vapor stream and a portion of the medium pressure liquid refrigerant stream to an auxiliary heat exchanger; and
(o) cooling the medium pressure liquid refrigerant stream against the cold vapor stream.

10. The method of claim 9 , further comprising:
(p) after performing step (o), supplying the cooled medium pressure liquid refrigerant stream to the shell side of the main heat exchanger.

Assignees

• Air Prod & Chem

Inventors

• Brostow Adam Adrian
• Krishnamurthy Gowri

Classifications

• F25J1/0279

  Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc. · CPC title

• F25J5/00

  Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants (heat exchangers F28C, F28D, F28F) · CPC title

• F25J1/0264

  Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams (F25J1/0272 takes precedence) · CPC title

• F25J1/0267

  using flash gas as heat sink · CPC title

• F25J1/0212

  as a single flow MCR cycle · CPC title