Décor paper having improved optical performance comprising treated inorganic particles

Patent metadata

Field	Value
Publication number	US-9920486-B2
Application number	US-201314655181-A
Country	US
Kind code	B2
Filing date	Jan 9, 2013
Priority date	Jan 9, 2013
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

The disclosure provides a décor paper prepared from a dispersion having improved optical performance without negatively impacting mechanical strength, wherein the dispersion comprises a TiO 2 particle slurry comprising a treated TiO 2 particle having a surface area of at least about 30 m 2 /g, and a cationic polymer; wherein the treatment comprises an oxide of silicon, aluminum, phosphorus or mixtures thereof; and the treatment is present in the amount of at least 15% based on the total weight of the treated titanium dioxide particle; paper pulp; and a cationic polymer; wherein the cationic polymer in the slurry and the cationic polymer in the dispersion are compatible; wherein for equal optical performance, the amount of treated TiO 2 particle in the dispersion is reduced by about 10% when compared to a dispersion not comprising the treated TiO 2 particle of (a). These décor papers are useful in preparing paper laminates.

First claim

What is claimed is:

1. A décor paper prepared from a dispersion, wherein the dispersion comprises
(a) a TiO 2 particle slurry comprising a treated TiO 2 particle having a surface area of at least about 30 m 2 /g, and a cationic polymer; wherein the treatment is selected from the group consisting of an oxide of silicon, oxide of aluminum, oxide of phosphorus, and mixtures thereof; and the treatment is present in the amount of at least 15% based on the total weight of the treated titanium dioxide particle;
(b) paper pulp; and
(c) a cationic polymer;
wherein the treated TiO 2 particle is present at 30 to 45% by weight, based on the total weight of the décor paper, and wherein for equal optical performance, the amount of treated TiO 2 particle in the dispersion is reduced by about 10% when compared to the same TiO 2 particle dispersion not comprising the specific treated TiO 2 particle slurry of (a).

2. The décor paper of claim 1 wherein the TiO 2 particle is a pigment.

3. The décor paper of claim 1 wherein the cationic polymer in the slurry is a urea-formaldehyde resin, a melamine-formaldehyde resin, a cationic polyacrylamide polymer, a polydialkyllammonium polymer, a polyacrylamide-polydialkylammonium copolymer, or a polyimide-polyamine-epichlorhydrin resin.

4. The décor paper of claim 1 wherein the cationic polymer (c) in the dispersion is a urea-formaldehyde resin, a melamine-formaldehyde resin or a polyimide-polyamine-epichlorhydrin resin.

5. The décor paper of claim 1 wherein the oxide is an oxide of silicon at a treatment level of at least about 6% by weight, based on the total weight of the treated TiO 2 pigment.

6. The décor paper of claim 1 wherein the oxide is an oxide of aluminum at a treatment level of about 4 to about 8%, based on the total weight of the treated TiO 2 pigment.

7. The décor paper of claim 1 wherein the TiO 2 particle has a particle size of about 0.02 to about 0.95 microns.

8. The décor paper of claim 1 wherein the TiO 2 particle has a particle size of about 0.5 to about 0.75 microns.

9. The décor paper of claim 1 wherein the TiO 2 particle is a pyrogenic TiO 2 particle.

10. The décor paper of claim 9 wherein the oxide is an oxide of silicon that is applied by deposition of pyrogenic silica onto a pyrogenic TiO 2 particle, co-oxygenation of silicon tetrachloride with titanium tetrachloride or by deposition via condensed phase aqueous oxide.

11. The décor paper of claim 10 wherein the oxide is an oxide of silicon that is applied by deposition via condensed phase aqueous oxide.

12. The décor paper of claim 1 wherein the oxide is an oxide of silicon that is applied by deposition via condensed phase aqueous oxide.

13. The décor paper of claim 1 wherein the oxide of silicon, oxide of aluminum, or both are substantially homogenous on the surface of the TiO 2 particle.

14. The décor paper of claim 1 wherein the cationic resin is present in the amount of about 0.5 to about 1.5% by weight, based on the total dry weight of the pulp used in the paper.

Assignees

• Chemours Company Tt Llc
• Chemours Co Fc Llc

Inventors

• Chinn Mitchell Scott
• Vanhecke Franck Andre

Classifications

• D21H27/30

  Multi-ply (for surface covering D21H27/18; making on paper-making machines D21F9/00, D21F11/00) · CPC title

• B32B2451/00

  Decorative or ornamental articles · CPC title

• D21H17/74

  of organic and inorganic material · CPC title

• B32B2250/26

  All layers being made of paper or paperboard · CPC title

• D21H27/26 Primary

  characterised by the overlay sheet or the top layers of the structures (decorative panels B44C5/04; wood grain effects B44F9/02) · CPC title