Modular cathode assemblies and methods of using the same for electrochemical reduction

Patent metadata

Field	Value
Publication number	US-9920443-B2
Application number	US-201414528146-A
Country	US
Kind code	B2
Filing date	Oct 30, 2014
Priority date	Dec 23, 2010
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

Modular cathode assemblies are useable in electrolytic reduction systems and include a basket through which fluid electrolyte may pass and exchange charge with a material to be reduced in the basket. The basket can be divided into upper and lower sections to provide entry for the material. Example embodiment cathode assemblies may have any shape to permit modular placement at any position in reduction systems. Modular cathode assemblies include a cathode plate in the basket, to which unique and opposite electrical power may be supplied. Example embodiment modular cathode assemblies may have standardized electrical connectors. Modular cathode assemblies may be supported by a top plate of an electrolytic reduction system. Electrolytic oxide reduction systems are operated by positioning modular cathode and anode assemblies at desired positions, placing a material in the basket, and charging the modular assemblies to reduce the metal oxide.

First claim

What is claimed is:

1. A modular cathode assembly, comprising:
a basket including a permeable surface permitting a fluid electrolyte to pass through the basket, the basket being electrically conductive;
a first assembly support joined to a rim of the basket; and
a cathode plate extending through the first assembly support and into the basket, the cathode plate being electrically insulated from the basket, the cathode plate being electrically conductive.

2. The modular cathode assembly of claim 1 , wherein the basket includes an upper portion and a lower portion, the upper portion and the lower portion being electrically connected and defining at least one gap in the basket through which material may be placed in the basket.

3. The modular cathode assembly of claim 2 , wherein the basket has a planar shape and wherein the lower portion includes the permeable surface on at least two sides with a largest area of the lower portion.

4. The modular cathode assembly of claim 2 , wherein the lower portion is divided into a plurality of sections each configured to retain solid material and prevent the solid material from moving between the sections.

5. The modular cathode assembly of claim 1 , wherein the cathode plate extends a substantially full length of the basket and a substantially full width of the basket.

6. The modular cathode assembly of claim 1 , wherein
the first assembly support is configured to support the cathode plate.

7. The modular cathode assembly of claim 6 , further comprising:
at least one plate electrical connector extending through the first assembly support, the plate electrical connector configured to provide electric power to the cathode plate and being insulated from the first assembly support; and
at least one basket electrical connector extending from the first assembly support, the basket electrical connector configured to provide electric power to the basket through the first assembly support.

8. The modular cathode assembly of claim 7 , wherein the basket electrical connector and the plate electrical connector have a same knife-edge shape and are arranged in a line.

9. The modular cathode assembly of claim 6 , wherein the first assembly support has a length so as to support the modular cathode assembly within a frame, and the basket is aligned at a center portion of the first assembly support so as to provide a substantially even reducing potential through the modular cathode assembly.

10. The modular cathode assembly of claim 1 , wherein the cathode plate is fabricated of a material chosen from the group of stainless steel, tungsten, tantalum, and molybdenum.

11. The modular cathode assembly of claim 1 , further comprising:
at least one insulating band on a surface of the cathode plate, the insulating band having a thickness and length to seat between the cathode plate and basket.

12. The modular cathode assembly of claim 1 , wherein the first assembly support has a lateral dimension that is greater than a lateral dimension of the basket.

13. The modular cathode assembly of claim 1 , wherein the first assembly support is configured to facilitate a lifting of an entirety of the modular cathode assembly.

14. The modular cathode assembly of claim 1 , further comprising:
a second assembly support joined to the cathode plate, the second assembly support disposed above the first assembly support.

15. The modular cathode assembly of claim 14 , further comprising:
an insulating pad disposed between the first assembly support and the second assembly support.

16. The modular cathode assembly of claim 1 , further comprising:
a pair of lift posts on opposite ends of the first assembly support, the pair of lift posts being positioned above the basket and the cathode plate.

Assignees

• Wiedmeyer Stanley G
• Barnes Laurel A
• Williamson Mark A
• Willit James L
• Ge Hitachi Nuclear Energy Americas Llc

Inventors

• Wiedmeyer Stanley G
• Barnes Laurel A
• Williamson Mark A
• Willit James L

Classifications

• C25C7/005

  of cells for the electrolysis of melts (C25C7/02 - C25C7/06 take precedence) · CPC title

• C25C7/02 Primary

  Electrodes (consumable anodes for the refining the metals C25C1/00 - C25C5/00); Connections thereof · CPC title

• C25C7/025

  used in cells for the electrolysis of melts · CPC title

• G21F9/30

  Processing (separating different isotopes of the same chemical element B01D59/00) · CPC title

• G21C19/48

  Non-aqueous processes · CPC title