Magnesium alloy member and production method therefor

Patent metadata

Field	Value
Publication number	US-9920403-B2
Application number	US-201314395121-A
Country	US
Kind code	B2
Filing date	Mar 29, 2013
Priority date	Apr 18, 2012
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

A high-strength magnesium alloy member is suitable for products in which at least one of bending stress and twisting stress primarily acts. The member has required elongation and 0.2% proof stress, whereby strength and formability are superior, and has higher strength and large compressive residual stress in the vicinity of the surface of a wire rod. In the magnesium alloy member formed as a wire rod in which at least one of bending stress and twisting stress primarily acts, the wire rod includes a surface portion having the highest hardness of 170 HV or more in the vicinity of the surface and an inner portion having a 0.2% proof stress of 550 MPa or more and an elongation of 5% or more, and the wire rod has the highest compressive residue stress in the vicinity of the surface of 50 MPa or more.

First claim

The invention claimed is:

1. A magnesium alloy member formed as a wire rod, in which at least one of bending stress and twisting stress primarily acts, wherein the magnesium alloy consists of 2 to 5 atomic % of Ni, 2 to 5 atomic % of Y, and the balance of Mg and inevitable impurities, and the wire rod comprises: a surface portion having the highest hardness of 170 HV or more in the vicinity of the surface; and an inner portion having a 0.2% proof stress of 550 MPa or more and an elongation of 5% or more at room temperature, and the wire rod has the highest compressive residue stress in the vicinity of the surface of 50 MPa or more.

2. The magnesium alloy member according to claim 1 , wherein compressive residual stress in a region from the surface of the wire rod to a depth of 0.1 mm is 50 MPa or more and a crossing point is 0.2 mm or more.

3. The magnesium alloy member according to claim 1 , wherein the portion having the highest hardness in the vicinity of the surface has an average crystal grain diameter of 1 μm or less measured by an EBSD method.

4. The magnesium alloy member according claim 1 , wherein the highest surface roughness (Rz) is 20 μm or less.

5. The magnesium alloy member according to claim 1 , wherein the wire rod has a diameter of 3 to 13 mm.

6. The magnesium alloy member according to claim 5 , wherein the member is a spring.

7. A production method for a magnesium alloy member, comprising:
a step for yielding a raw material in a form of foil strips, foil pieces, or fibers of a magnesium alloy by a rapid solidification method,
a sintering step for forming a billet by bonding, compressing, and sintering the raw material,
a step for plastic working the billet to form a plastic worked member,
a forming step for forming the plastic worked member, and
a step for providing compressive residual stress to the plastic worked member after forming,
thereby obtaining the magnesium alloy member according to claim 1 .

8. A production method for a magnesium alloy member, comprising:
a step for forming fibers by a molten metal extraction method,
a sintering step for forming a billet by bonding, compressing, and sintering the fibers,
an extruding step for directly charging the billet into a container of a press machine and extruding the billet to form an extruded member,
a forming step for forming the extruded member, and
a step for providing compressive residual stress to the extruded member after forming by shot peening,
thereby obtaining the magnesium alloy member according to claim 1 .

9. A magnesium alloy member formed as a wire rod, in which at least one of bending stress and twisting stress primarily acts, wherein the magnesium alloy consists of 2 to 5 atomic % of Ni, 2 to 5 atomic % of Y, and the balance of Mg and inevitable impurities, and the wire rod comprises: a surface portion having the highest hardness of 170 HV or more in the vicinity of a surface thereof; and an inner portion having a 0.2% proof stress of 550 MPa or more and an elongation of 5% or more at room temperature, and the wire rod has an integrated value I −σR of compressive residue stress in a region from the surface to a crossing point of 7 MPa·mm or more, when a depth from the surface in which a value of compressive residual stress in residual stress distribution from the surface toward a depth direction is zero is set to be a crossing point.

10. The magnesium alloy member according to claim 9 , wherein compressive residual stress in a region from the surface of the wire rod to a depth of 0.1 mm is 50 MPa or more and a crossing point is 0.2 mm or more.

11. The magnesium alloy member according to claim 9 , wherein the portion having the highest hardness in the vicinity of the surface has an average crystal grain diameter of 1 μm or less measured by an EBSD method.

12. The magnesium alloy member according to claim 9 , wherein the highest surface roughness (Rz) is 20 μm or less.

13. The magnesium alloy member according to claim 9 , wherein the wire rod has a diameter of 3 to 13 mm.

14. The magnesium alloy member according to claim 13 , wherein the member is a spring.

15. The magnesium alloy member according to claim 9 , wherein the integrated value I −σR of compressive residue stress is 10 MPa·mm or more.

16. The magnesium alloy member according to claim 9 , wherein the integrated value I −σR of compressive residue stress is 20 MPa·mm or more.

17. The magnesium alloy member according to claim 9 , wherein the compressive residual stress in a region from the surface of the wire rod to a depth of 0.1 mm is 172.5 MPa or more.

18. A production method for a magnesium alloy member, comprising:
a step for yielding a raw material in a form of foil strips, foil pieces, or fibers of a magnesium alloy by a rapid solidification method,
a sintering step for forming a billet by bonding, compressing, and sintering the raw material,
a step for plastic working the billet to form a plastic worked member,
a forming step for forming the plastic worked member, and
a step for providing compressive residual stress to the plastic worked member after forming,
thereby obtaining the magnesium alloy member according to claim 9 .

19. A production method for a magnesium alloy member, comprising:
a step for forming fibers by a molten metal extraction method,
a sintering step for forming a billet by bonding, compressing, and sintering the fibers,
an extruding step for directly charging the billet into a container of a press machine and extruding the billet to form an extruded member,
a forming step for forming the extruded member, and
a step for providing compressive residual stress to the extruded member after forming by shot peening,
thereby obtaining the magnesium alloy member according to claim 9 .

Assignees

• Nhk Spring Co Ltd

Inventors

• Araoka Yuji
• Shiraishi Tohru
• Ono Yoshiki

Classifications

• C22C1/0408

  Light metal alloys · CPC title

• C21D7/00

  Modifying the physical properties of iron or steel by deformation (apparatus for mechanical working of metal B21, B23, B24) · CPC title

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title

• B22F3/17

  by forging · CPC title

• B22D11/0611

  formed by a single casting wheel, e.g. for casting amorphous metal strips or wires · CPC title