Vehicle part cover including methacrylic-based resin

Patent metadata

Field	Value
Publication number	US-9920148-B2
Application number	US-201214435999-A
Country	US
Kind code	B2
Filing date	Oct 19, 2012
Priority date	Oct 19, 2012
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

A vehicle part cover including a methacrylic-based resin (I) having a weight average molecular weight measured by gel permeation chromatography (GPC) of 65,000 to 300,000,
the methacrylic-based resin (I) comprising: 50 to 97% by mass of a methacrylate monomer unit (A); 3 to 30% by mass of a structural unit (B) having a ring structure in its main chain, and being at least one selected from the group consisting of a maleimide-based structural unit, a glutaric anhydride structural unit, a glutarimide-based structural unit, and a lactone ring structural unit; and 0 to 20% by mass of another vinyl monomer unit (C) that is copolymerizable with a methacrylate monomer.

First claim

The invention claimed is:

1. A vehicle part cover comprising a methacrylic-based resin (I) having a weight average molecular weight measured by gel permeation chromatography (GPC) of 65,000 to 300,000 and a weight loss ratio of 6% or less when held for 30 minutes at 290° C.,
the methacrylic-based resin (I) comprising:
50 to 97% by mass of a methacrylate monomer unit (A);
3 to 30% by mass of a structural unit (B) having a ring structure in its main chain, and being at least one selected from the group consisting of a maleimide-based structural unit, a glutaric anhydride structural unit, a glutarimide-based structural unit, and a lactone ring structural unit; and
0 to 20% by mass of another vinyl monomer unit (C) that is copolymerizable with a methacrylate monomer.

2. The vehicle part cover according to claim 1 , wherein the structural unit (B) having a ring structure in its main chain comprises at least one structural unit selected from the group consisting of a glutarimide-based structural unit, a lactone ring structural unit, and a maleimide-based structural unit.

3. The vehicle part cover according to claim 1 , wherein the structural unit (B) having a ring structure in its main chain comprises a maleimide-based structural unit.

4. The vehicle part cover according to claim 1 , wherein the structural unit (B) having a ring structure in its main chain comprises a N-cyclohexylmaleimide-based structural unit and/or a N-aryl group-substituted maleimide-based structural unit.

5. The vehicle part cover according to claim 1 , wherein the structural unit (B) having a ring structure in its main chain comprises a N-aryl group-substituted maleimide-based structural unit.

6. The vehicle part cover according to claim 1 , wherein the another vinyl monomer unit (C) that is copolymerizable with the methacrylate monomer is formed from at least one selected from the group consisting of an acrylate monomer, an aromatic vinyl monomer, and a vinyl cyanide monomer.

7. The vehicle part cover according to claim 1 , wherein the another vinyl monomer unit (C) that is copolymerizable with the methacrylate monomer is formed from at least one selected from the group consisting of methyl acrylate, ethyl acrylate, styrene, and acrylonitrile.

8. The vehicle part cover according to claim 1 , having a Vicat softening temperature of 110° C. or more.

9. The vehicle part cover according to claim 1 , having a thickness of 0.1 to 5 mm.

10. The vehicle part cover according to claim 1 , wherein the vehicle part cover is:
a vehicle instrument cover selected from the group consisting of a vehicle clock cover, an indicator cover, a combination meter cover, a meter cover, and a vehicle head-up display, or
vehicle rear lamp cover selected from the group consisting of a tail lamp cover, a rear combination lamp cover, and a high mount stop lamp cover.

11. The vehicle part cover according to claim 1 , wherein the vehicle part cover is a vehicle instrument cover selected from the group consisting of a vehicle clock cover, an indicator cover, a combination meter cover, a meter cover, and a vehicle head-up display.

12. The vehicle part cover according to claim 1 , wherein the vehicle part cover is a vehicle rear lamp cover selected from the group consisting of a tail lamp cover, a rear combination lamp cover, and a high mount stop lamp cover.

13. The vehicle part cover according to claim 1 , comprising 10 to 99% by mass of the methacrylic-based resin (I),
and further comprising 90 to 1% by mass of a methacrylic-based resin (II) that comprises at least 80 to 99.5% by mass of a methacrylate monomer unit (A′), and that has a weight average molecular weight measured by gel permeation chromatography (GPC) of 20,000 to 300,000.

14. The vehicle part cover according to claim 13 , wherein a weight average molecular weight of methacrylic-based resin obtained by mixing the methacrylic-based resin (I) and the methacrylic-based resin (II) is 65,000 to 300,000.

15. The vehicle part cover according to claim 1 , further comprising 0 parts by mass to 5 parts by mass of a thermal stabilizer based on 100 parts by mass of the methacrylic-based resin.

16. The vehicle part cover according to claim 15 , wherein the thermal stabilizer is at least one selected from the group consisting of a hindered phenol antioxidant and a phosphorus-based antioxidant.

17. The vehicle part cover according to claim 15 , wherein a content ratio Y (parts by mass) of the thermal stabilizer based on 100 parts by mass of the methacrylic-based resin satisfies the following formula (i):
( Y )≥0.053×[methacrylate monomer unit content/( B ) content]−0.4  (i).

18. The vehicle part cover according to claim 17 , wherein the thermal stabilizer is at least one selected from the group consisting of a hindered phenol antioxidant and a phosphorus-based antioxidant.

19. The vehicle part cover according to claim 17 , wherein the methacrylic-based resin (I) comprises more than 0% by mass of the another vinyl monomer unit (C).

Assignees

• Murakami Fumiki
• Asahi Kasei Chemicals Corp

Inventors

• Murakami Fumiki

Classifications

• C08F226/06 Primary

  by a heterocyclic ring containing nitrogen · CPC title

• B60R13/02

  {Internal} Trim mouldings {; Internal} Ledges; Wall liners {for passenger compartments}; Roof liners (B60R13/01 takes precedence {; padded linings for the vehicle interior B60R21/04; arrangements or adaptations of floor mats or carpets in vehicles B60N3/04; internal lining for trains B61D17/18}) · CPC title

• C08L39/04

  Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member · CPC title

• B60K37/00 Primary

  Dashboards (as road-vehicle superstructure sub-units B62D25/14) · CPC title

• F21S41/25

  Projection lenses · CPC title