Hydrogenation system for aromatic compound, hydrogen storage and transportation system equipped with same, and process for hydrogenation of aromatic compound

Patent metadata

Field	Value
Publication number	US-9919986-B2
Application number	US-201515116007-A
Country	US
Kind code	B2
Filing date	Jan 29, 2015
Priority date	Feb 3, 2014
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

The energy is minimized that is required to lower the concentration of the high boiling point components (containing the poisoning substance for the dehydrogenation catalyst) contained in the hydrogenated aromatic compound produced by the hydrogenation of an aromatic compound. The hydrogenation system ( 2 ) for an aromatic compound comprises a hydrogenation reaction unit ( 11 ) for adding hydrogen to an aromatic compound by a hydrogenation reaction to produce a hydrogenated aromatic compound, a first separation unit ( 12 ) for separating a gas and a liquid component from a product of the hydrogenation reaction unit while maintaining a temperature of the product generally higher than a boiling point of the hydrogenated aromatic compound, and a second separation unit ( 13 ) for separating the hydrogenated aromatic compound from the gas component separated by the first separation unit.

First claim

The invention claimed is:

1. A hydrogenation system for an aromatic compound, comprising:
a hydrogenation reaction unit in which hydrogen is added to an aromatic compound by a hydrogenation reaction to produce a hydrogenated aromatic compound;
a first separation unit connected with the hydrogenation reaction unit to receive a product of the hydrogenation reaction unit, the first separation unit separating a gas component and a liquid component from the product of the hydrogenation reaction unit while maintaining a temperature of the product generally higher than a boiling point of the hydrogenated aromatic compound such that the gas component contains the hydrogenated aromatic compound; and
a second separation unit connected with the first separation unit to receive the gas component separated by the first separation unit, the second separation unit separating the hydrogenated aromatic compound from the gas component separated by the first separation unit,
wherein the hydrogenation system further comprises a distillation unit connected with the first separation unit to receive the liquid component separated by the first separation unit, the distillation unit distilling the liquid component separated by the first separation unit such that an effluent of the distillation unit contains the hydrogenated aromatic compound, wherein the effluent of the distillation unit is mixed with the hydrogenated aromatic compound separated by the second separation unit.

2. The hydrogenation system for an aromatic compound according to claim 1 , further comprising a cooler configured to cool the product from which the gas and liquid components are to be separated by the first separation unit.

3. The hydrogenation system for an aromatic compound according to claim 1 , wherein a temperature of the product that is separated by the first separation unit is maintained in a range of 100° C. to 220° C.

4. The hydrogenation system for an aromatic compound according to claim 1 , wherein the distillation unit performs distillation by using reaction heat of the hydrogenation reaction unit.

5. A hydrogen storage and transportation system, comprising:
the hydrogenation system for an aromatic compound according to claim 1 ; and
a dehydrogenation system in which hydrogen is produced by a dehydrogenation of the hydrogenated aromatic compound separated by the second separation unit mixed with the effluent of the distillation unit.

Assignees

• Chiyoda Corp

Inventors

• Imagawa Kenichi
• Kawai Hironori
• Shiraga Masato
• Nakajima Yusuke

Classifications

• C07C5/10 Primary

  of aromatic six-membered rings · CPC title

• C01B2203/0277

  containing a catalytic decomposition step · CPC title

• C01B3/0015

  Organic compounds, e.g. liquid organic hydrogen carriers [LOHC] or metalorganic compounds; Solutions thereof · CPC title

• C01B3/26

  using catalysts · CPC title

• C07C2101/12

  Chemistry & Metallurgy · mapped topic