Process for the preparation of isomers of xylene

Patent metadata

Field	Value
Publication number	US-9919984-B2
Application number	US-201314913825-A
Country	US
Kind code	B2
Filing date	Oct 25, 2013
Priority date	Aug 23, 2013
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

The present disclosure relates to a process for the preparation of isomers of xylene. The process includes method step of contacting an activated alkylation catalyst composite with toluene and methanol in the presence of an inert gas, at a temperature of 300 to 500° C. to obtain isomers of xylene. The alkylation catalyst composite used in accordance with the present disclosure comprises a molecular sieve loaded with at least one metal ion. The metal loaded on the molecular sieve is at least one alkali earth metal selected from the group consisting of barium, strontium, magnesium and calcium.

First claim

The invention claimed is:

1. A process for the preparation of isomers of xylene, said process comprising the following steps:
i. obtaining an alkylation catalyst composite consisting of X-zeolite loaded with at least one metal ion, wherein said metal is selected from the group consisting of barium, strontium, and calcium;
ii. activating the alkylation catalyst composite at a temperature of 450 to 650° C. for a time period of 30 minutes to 2 hours in a reactor to obtain an activated alkylation catalyst composite, wherein the temperature for activating the alkylation catalyst composite is attained by heating the reactor at a rate of 4 to 10° C. per minute; and
iii. contacting the activated alkylation catalyst composite with toluene and methanol in the presence of an inert gas, at a temperature of 300 to 500° C. to obtain a reaction mixture comprising isomers of xylene, wherein a mass of ortho-xylene in said reaction mixture is greater than individual mass of para-xylene and meta-xylene.

2. The process as claimed in claim 1 , wherein a weight ratio of toluene to methanol ranges between 1:1 and 4:1.

3. The process as claimed in claim 1 , wherein a flow rate of toluene is maintained at a weight hourly space velocity of 1 per hour to 5 per hour of the activated alkylation catalyst composite.

4. The process as claimed in claim 1 , wherein the inert gas is at least one selected from the group consisting of nitrogen, argon and helium.

5. The process as claimed in claim 1 , wherein a flow rate of the inert gas ranges between 5 and 15 ml per minute.

Assignees

• Hindustan Petroleum Corp Ltd

Inventors

• Ravishankar Raman
• Peddy Venkata Chalapathi Rao
• Nettem Venkateswarlu Choudary
• Shanbhag Ganapati
• Marakatti Vijaykumar
• Halgeri Anand
• GANDHAM Sriganesh

Classifications

• B01J2229/186

  not in framework positions · CPC title

• C07C2529/70

  of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 · CPC title

• B01J29/082

  X-type faujasite · CPC title

• C07C2529/18

  of the mordenite type · CPC title

• B01J29/084

  Y-type faujasite · CPC title