Synthesis of high temperature ceramic powders

Patent metadata

Field	Value
Publication number	US-9919973-B1
Application number	US-201715475674-A
Country	US
Kind code	B1
Filing date	Mar 31, 2017
Priority date	Mar 31, 2017
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

The present invention relates to methods and apparatuses for forming high temperature ceramic powders. A method of producing high temperature ceramic powders according to an embodiment of the present invention can include preparing a solution, atomizing the solution, providing a gas and carrying the atomized solution into a furnace via the gas, evaporating the solvent, precipitating and drying the solutes, performing a thermolysis (or pyrolysis) reaction, and performing a carbothermal reduction reaction (CTR) in situ, and collecting product particles after they exit from the furnace.

First claim

We claim:

1. A method of producing ceramic powders comprising:
preparing a solution including a solvent and solutes;
atomizing the solution;
providing a gas and carrying the atomized solution into a furnace via the gas;
evaporating the solvent, precipitating and drying the solutes, and performing a carbothermal reduction reaction in situ; and
collecting product particles after exiting from the furnace.

2. The method of producing ceramic powders of claim 1 , characterized in that the product particles include one or more of high temperature ceramics, non-oxide ceramics, and high temperature non-oxide ceramics.

3. The method of producing ceramic powders of claim 1 , characterized in that the solution includes one or more of transition metals, actinoids, and metalloids.

4. The method of producing ceramic powders of claim 3 , characterized in that the gas is an inert gas including one or more of argon and nitrogen.

5. The method of producing ceramic powders of claim 4 , characterized in that the solution includes a carbon source or carbon precursor.

6. The method of producing ceramic powders of claim 5 , characterized in that the carbon source or carbon precursor includes one or more of a phenolic resin, a vinylidene chloride polymer, carbon black, acetylene carbon black, a hydrocarbon, and a carbohydrate.

7. The method of producing ceramic powders of claim 5 , characterized in that the solution is mixed with a precipitating agent prior to being atomized.

8. The method of producing ceramic powders of claim 5 , characterized in that the solvent includes one or more alcohols.

9. The method of producing ceramic powders of claim 4 , characterized in that the gas is fed directly to a nebulizer or atomizer and ambient air is kept out of the furnace.

10. A method of producing high temperature ceramic powders comprising:
preparing a solution including a solvent and solutes;
atomizing the solution;
providing a gas and carrying the atomized solution into a furnace via the gas;
evaporating the solvent, precipitating and drying the solutes, performing a thermolysis or pyrolysis reaction, and performing a carbothermal reduction reaction in situ; and
collecting product particles after they exit from the furnace.

11. The method of producing ceramic powders of claim 10 , characterized in that the solution includes one or more of metals, transition metals, actinoids, and metalloids, as well as a carbon source or carbon precursor.

12. The method of producing ceramic powders of claim 11 , further comprising mixing a precipitating agent with the solution prior to it being atomized.

13. The method of producing ceramic powders of claim 11 , further comprising rinsing or mixing and filtering the product particles with an additional solvent to remove unwanted compositions.

14. The method of producing ceramic powders of claim 10 , characterized in that the solution includes one or more of Tantalum, Hafnium, Zirconium, Titanium, Niobium, Vanadium, Magnesium, Aluminum, Chromium, Molybenum, Tungsten, Scandium, Yttrium, Lanthanum, and other Lanthanide metals, Manganese, Iron, Cobalt, and Nickel.

15. The method of producing ceramic powders of claim 14 , characterized in that the product particles include high temperature ceramic particles having an average size ranging from 10 nm to 500 nm.

16. The method of producing ceramic powders of claim 15 , characterized in that a stage of the furnace is maintained at a temperature range of 1400° C. to 2400° C.

17. The method of producing high temperature ceramic powders of claim 16 , characterized in that the average furnace retention time is less than 10 minutes.

18. The method of producing high temperature ceramic powders of claim 10 , characterized in that the product particles include one or more of carbides, borides, or nitrides of Tantalum, Hafnium, Zirconium, Titanium, Niobium, Vanadium, Magnesium, Aluminum, Chromium, Molybenum, Tungsten, Scandium, Yttrium, Lanthanum, Lanthanide metals, Manganese, Iron, Cobalt, or Nickel.

19. The method of producing high temperature ceramic powders of claim 18 , further comprising rinsing, or mixing and filtering, the product particles with an additional solvent.

20. The method, according to claim 18 , wherein the product particles include one or more composites selected from SiC, HfC, HfB 2 , HfN, WC, TiC, TiB 2 , TiN, BN, TaC, ZrB 2 , ZrC, ZrN, (Ta, Hf)C, and (Zr, Hf)B 2 .

Assignees

• Cheng Zhe
• Foroughi Paniz
• Behrens Andres
• The Florida International Univ Board Of Trustees

Inventors

• Cheng Zhe
• Foroughi Paniz
• Behrens Andres

Classifications

• C04B35/626 Primary

  Preparing or treating the powders individually or as batches {(pigments for ceramics C09C1/0009); preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B} · CPC title

• B01J2/04

  in a gaseous medium {(if combined with suspending the material in a gas, e.g. fluidised beds B01J2/16)} · CPC title

• C04B35/5607

  based on refractory metal carbides · CPC title

• C04B2235/95

  Products characterised by their size, e.g. microceramics · CPC title

• C04B35/58064

  based on refractory borides · CPC title