Porous carbon and method of preparing the same

Patent metadata

Field	Value
Publication number	US-9919924-B2
Application number	US-201314417279-A
Country	US
Kind code	B2
Filing date	Jul 24, 2013
Priority date	Jul 27, 2012
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

This disclosure relates to porous carbon and a method of preparing the same. The porous carbon of the present invention is derived from a carbide compound having a composition comprising metal and oxide. The porous carbon of the present invention comprises both micropores and mesopores, and has large specific surface area, and thus, may be usefully used in various fields.

First claim

The invention claimed is:

1. A method for preparing porous carbon comprising:
a step of mixing at least one metal source with a carbon source, wherein the metal source is a metal selected from the group consisting of Ti, V, Cr, Zr, Nb, Mo, W, Hf, Ta, and oxides thereof;
a step of heating the mixture to form a carbide compound;
a step of reacting the carbide compound with halogen gas; and
a step of heating the reaction mixture under hydrogen atmosphere,

wherein the carbide compound has a composition represented by the following Formula 1:
M(C x O y )  [Formula 1]

in the Formula 1, M is at least one metal selected from the group consisting of Ti, V, Cr, Zr, Nb, Mo, W, Hf, and Ta;
x is 0.6 to 0.99, and y is 0.01 to 0.4.

2. The method according to claim 1 , further comprising a step of pulverizing the mixture, simultaneously with or after the step of mixing a metal source with a carbon source.

3. The method according to claim 2 , wherein the step of pulverizing the mixture is conducted using an attritor mill, a planetary mill or a horizontal mill, at a BPR (ball-to-power ratio) of about 10:1 or more, and a milling speed of about 50 rpm or more.

4. The method according to claim 1 , wherein the step of heating the mixture to form a carbide compound is conducted at a temperature of 800 to 1,600° C. for 5 minutes to 5 hours.

5. The method according to claim 1 , wherein the halogen gas is chlorine (Cl 2 ) gas.

6. The method according to claim 1 , wherein the step of reacting a carbide compound with halogen gas is conducted at a temperature of 400 to 1,200° C. for 1 to 5 hours.

7. The method according to claim 1 , wherein the step of heating the reaction mixture under hydrogen atmosphere is conducted at a temperature of 400 to 1,000° C.

8. The method according to claim 1 , further comprising a step of activating pores, after the step of heating under hydrogen atmosphere.

9. The method according to claim 8 , wherein the step of activating pores comprises
heating the porous carbon under atmosphere of at least one gas selected from the group consisting of inert gas and N 2 gas; and
flowing carbon dioxide gas (CO 2 ) at the heated temperature.

10. A method for preparing porous carbon comprising:
a step of mixing at least one metal source with a carbon source, and a hydrogen (H) source or a boron (B) source, wherein the metal source is a metal selected from the group consisting of Ti, V, Cr, Zr, Nb, Mo, W, Hf, Ta, and oxides thereof;
a step of heating the mixture to form a carbide compound;
a step of reacting the carbide compound with halogen gas; and
a step of heating the reaction mixture under hydrogen atmosphere,
wherein the carbide compound has a composition represented by the following Formula 2:
M(C x O y A z )  [Formula 2]

in the Formula 2, M is at least one metal selected from the group consisting of Ti, V, Cr, Zr, Nb, Mo, W, Hf, and Ta;
A is boron (B) or hydrogen (H);
x is 0.6 to 0.99, y is 0.01 to 0.4, and z is 0.01 to 0.4.

Assignees

• Hanwha Chemical Corp
• Snu R&Db Foundation

Inventors

• Kang Shin Hoo
• Ihm Ji Soon
• Kim Dong Ok

Classifications

• C01G41/006

  Compounds containing tungsten, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• C01G23/00

  Compounds of titanium {(preparation of Ti-compounds from ores or scraps C22B34/12)} · CPC title

• C01B32/05 Primary

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• C01P2006/12

  Surface area · CPC title