Floor covering adhesive composition comprising a vinyl acetate-ethylene copolymer

Patent metadata

Field	Value
Publication number	US-9919506-B2
Application number	US-201415035875-A
Country	US
Kind code	B2
Filing date	Oct 28, 2014
Priority date	Nov 14, 2013
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

The invention relates to a floor covering adhesive composition, based on an aqueous, emulsifier-stabilized polymer dispersion of vinyl acetate-ethylene copolymer, containing A) tackifying resin, B) one or more fillers, and C) a vinyl acetate-ethylene copolymer in the form of an emulsifier-stabilized aqueous dispersion, characterized in that the vinyl acetate-ethylene copolymer is obtained by radical-initiated emulsion polymerization in an aqueous medium, of a) 60 to 89.9% by weight of vinyl acetate, b) 10 to 36% by weight of ethylene, c) 0 to 2% by weight of one or more monomers selected from the group of vinyl esters of carboxylic acids having 8 to 12 C atoms and acrylic acid alkyl esters having a C 1 to C 8 alkyl radical, d) 0.1 to 5% by weight of one or more ethylenically unsaturated auxiliary monomers having a carboxylic acid group, amide group, nitrile group or sulfonic acid (salt) group, wherein the percentages stated in % by weight are each in relation to the total weight of the comonomers and add up to 100% by weight, and the polymerization is carried out in the presence of one or more emulsifiers.

First claim

The invention claimed is:

1. A process for adhesively bonding a floor covering to a flooring substrate, wherein the floor covering is made from a natural material selected from the group consisting of cork, sisal, and linoleum and the flooring substrate is selected from the group consisting of concrete, screed, and wood fiberboard, said process comprising
1) applying to the flooring substrate a floor, covering adhesive composition, and
2) while the floor covering adhesive composition is still wet, applying the floor covering thereto,
wherein the floor covering adhesive composition comprises
A) a tackifying resin, B) one or more fillers and C) a vinyl acetate-ethylene copolymer in the form of an emulsifier-stabilized aqueous dispersion,
wherein the vinyl acetate-ethylene copolymer is obtained by radically initiated emulsion polymerization, in an aqueous medium, of the following monomers and no others
a) 60 to 89.9 wt % of vinyl acetate,
b) 10 to 36 wt % of ethylene,
c) 0.1 to 2 wt % of one or more monomers selected from the group consisting of acrylic acid alkyl esters with C 1 to C 8 alkyl radicals,
d) optionally one or more vinyl esters of carboxylic acids having 8 to 12 C atoms, provided that the vinyl esters and the acrylic acid alkyl esters total to 0.1 to 2 wt %, and
e) 0.1 to 5 wt % of one or more ethylenically unsaturated auxiliary monomers bearing a carboxylic acid group, amide group, nitrile group or sulfonic acid (salt) group,
the figures in wt % being based in each case on the total weight of the comonomers and adding up to 100 wt %, and the polymerization being performed in the presence of one or more emulsifiers.

2. The process as claimed in claim 1 , wherein 5 to 35 wt % of tackifying resin A) is included.

3. The process as claimed in claim 1 , wherein 15 to 50 wt % of fillers B) is included.

4. The process as claimed in claim 1 , wherein 15 to 50 wt % of dispersion C) is included.

5. The process as claimed in claim 1 , wherein 66 to 86 wt % of vinyl acetate a), based on the total weight of the comonomers, is copolymerized.

6. The process as claimed in claim 1 , wherein 10 to 30 wt % of ethylene b), based on the total weight of the comonomers, is copolymerized.

7. The process as claimed in claim 1 , wherein 0.1 to 4 wt % of auxiliary monomers e), based on the total weight of the comonomers, is copolymerized.

8. The process as claimed in claim 1 , wherein the aqueous dispersion is stabilized with one or more nonionic or anionic emulsifiers or mixtures of nonionic and anionic emulsifiers.

Assignees

• Wacker Chemie Ag

Inventors

• Bauers Florian
• Kaiser Stephan

Classifications

• C08F2800/20

  as weight or mass percentages · CPC title

• C08L93/04

  Rosin · CPC title

• C08K2003/265

  Calcium, strontium or barium carbonate · CPC title

• B32B37/12 Primary

  characterised by using adhesives · CPC title

• B32B2471/02

  Carpets · CPC title