Photocatalyst body, photocatalyst dispersion, and method for manufacturing photocatalyst body

Patent metadata

Field	Value
Publication number	US-9919292-B2
Application number	US-201113211597-A
Country	US
Kind code	B2
Filing date	Aug 17, 2011
Priority date	Sep 13, 2010
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

According to one embodiment, a photocatalyst body satisfies at least one condition described below, (1) a ratio of an absorption intensity at a wave number of 3450 cm −1 to a peak intensity of an absorption at about 1037 cm −1 being 2.5 or less in an analysis of a surface of the body, (2) a ratio of a maximum peak intensity of an absorption in a wave number range of not less than 1500 cm −1 and not more than 1700 cm −1 to a peak intensity of an absorption at about 1037 cm −1 being 0.7 or less in the analysis and (3) the photocatalyst body having no absorption peak in a wave number range of not less than 5000 cm −1 and not more than 5400 cm −1 or a ratio of a maximum peak intensity of an absorption to an absorption intensity at 5250 cm −1 being 1.7 or less in the analysis.

First claim

What is claimed is:

1. A photocatalyst dispersion comprising:
at least one fine particle selected from a tungsten oxide fine particle and a tungsten oxide composite fine particle; and
a solvent,
the solvent comprising ammonia as an ion additive,
a hydrogen ion concentration index of the photocatalyst dispersion being from pH 5.3 to pH 6.9,
the photocatalyst dispersion being capable of forming a photocatalyst body by being applied to a surface of a base body,
the photocatalyst body comprising: at least one fine particle selected from a tungsten oxide fine particle and a tungsten oxide composite fine particle formed on the surface of the base body,
the photocatalyst body satisfying at least one condition of (1) to (3) below and a condition of (4) below:
(1) a ratio of an absorption intensity at a wave number of 3450 cm −1 to a peak intensity of an absorption at a wave number of about 1037 cm −1 being 0.9 or less when a surface of the photocatalyst body is analyzed by infrared spectroscopy;
(2) a ratio of a maximum peak intensity of an absorption in a wave number range of 1500 cm −1 to 1700 cm −1 to a peak intensity of an absorption at a wave number of about 1037 cm −1 being 0.5 or less when the surface of the photocatalyst body is analyzed by infrared spectroscopy;
(3) the photocatalyst body having no absorption peak in a wave number range of 5000 cm −1 5400 cm −1 or a ratio of a maximum peak intensity of an absorption to an absorption intensity at a wave number of 5250 cm −1 being 1.7 or less when the surface of the photocatalyst body is analyzed by near infrared spectroscopy;
(4) a ratio of a peak intensity of an absorption at a wave number of about 3690 cm −1 to a peak intensity of an absorption at a wave number of about 1037 cm −1 being 0.025 or more when the surface of the photocatalyst body is analyzed by infrared spectroscopy, and
an adsorption amount of water being suppressed in the photocatalyst body which shows a peak of the absorption corresponding to hydroxyl groups in the infrared spectroscopy.

2. The photocatalyst body according to claim 1 , wherein the at least one fine particle has an average primary particle diameter (D50) of 1 nm to 400 nm.

3. The photocatalyst dispersion according to claim 1 , wherein a concentration of the fine particle is from 0.1 mass % to 20 mass %.

4. A method for manufacturing the photocatalyst body according to claim 1 , comprising:
producing a photocatalyst dispersion comprising at least one fine particle selected from a tungsten oxide fine particle and a tungsten oxide composite fine particle, and a solvent;
applying the photocatalyst dispersion to a surface of a base body, thereby forming a applied photocatalyst dispersion; and
forming a photocatalyst on the surface of the base body by drying the applied photocatalyst dispersion, thereby producing a formed photocatalyst body,
a hydrogen ion exponent of the photocatalyst dispersion being adjusted in the producing the photocatalyst dispersion so that the formed photocatalyst body satisfies at least one condition of (I) to (III) below and a condition of (IV) below:
(I) a ratio of an absorption intensity at a wave number of 3450 cm −1 to a peak intensity of an absorption at a wave number of about 1037 cm −1 being 0.9 or less when a surface of the formed photocatalyst body is analyzed by infrared spectroscopy;
(II) a ratio of a maximum peak intensity of an absorption in a wave number range of 1500 cm −1 to 1700 cm −1 to a peak intensity of an absorption at a wave number of about 1037 cm −1 being 0.5 or less when the surface of the formed photocatalyst body is analyzed by infrared spectroscopy;
(III) the formed photocatalyst body having no absorption peak in a wave number range of 5000 cm −1 to 5400 cm −1 or a ratio of a maximum peak intensity of an absorption to an absorption intensity at a wave number of 5250 cm −1 being 1.7 or less when the surface of the formed photocatalyst body is analyzed by near infrared spectroscopy; and
(IV) a ratio of a peak intensity of an absorption at a wave number of about 3690 cm −1 to a peak intensity of an absorption at a wave number of about 1037 cm −1 being 0.025 or more when the surface of the formed photocatalyst body is analyzed by infrared spectroscopy.

5. The method according to claim 4 , wherein the hydrogen ion exponent of the photocatalyst dispersion is adjusted with an ion additive to not more than pH 6.9 in the producing the photocatalyst dispersion.

6. The method according to claim 4 , wherein the applied photocatalyst dispersion is dried by a condition satisfying at least one of being heated at not less than 110° C. and not more than 500° C. and being placed in an atmosphere with a pressure lower than atmospheric pressure in the forming the photocatalyst on the surface of the base body.

7. The photocatalyst dispersion of claim 1 , wherein the hydrogen ion concentration index of the photocatalyst dispersion is higher than 6.5 and lower than 6.9.

8. The photocatalyst dispersion according to claim 1 , wherein the solvent comprises ammonia as an ion additive, and the hydrogen on concentration index of the photocatalyst dispersion is from pH 5.3 to pH 5.5.

9. The photocatalyst dispersion according to claim 1 , wherein the photocatalyst body satisfies conditions (1), (2), (3) and (4).

Assignees

• Tokuno Yoko
• Makino Nobuaki
• Sasaki Akito
• Nakano Kayo
• Kusaka Takao
• Toshiba Kk
• Toshiba Materials Co Ltd

Inventors

• Tokuno Yoko
• Makino Nobuaki
• Sasaki Akito
• Nakano Kayo
• Kusaka Takao

Classifications

• B01J37/0215

  Coating · CPC title

• B01D2255/9202

  Linear dimensions · CPC title

• B01D2255/20776

  Tungsten · CPC title

• B01J35/004

  Operations & Transport · mapped topic

• B01D2255/802

  Photocatalytic · CPC title