Method for preparing a sorbent

Patent metadata

Field	Value
Publication number	US-9919286-B2
Application number	US-201415035797-A
Country	US
Kind code	B2
Filing date	Dec 4, 2014
Priority date	Dec 18, 2013
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

A method is described for preparing a sorbent including the steps of:
(i) mixing together an inert particulate support material and one or more binders to form a support mixture, (ii) shaping the support mixture by granulation in a granulator to form agglomerates, (iii) coating the agglomerates with a coating mixture powder including a particulate copper sulphide and one or more binders to form a coated agglomerate, and (iv) drying the coated agglomerate to form a dried sorbent.

First claim

The invention claimed is:

1. A method for preparing a sorbent comprising copper sulphide, the method comprising the steps of:
(i) mixing together an inert particulate support material and one or more binders to form a support mixture,
(ii) shaping the support mixture by granulation in a granulator to form agglomerates,
(iii) coating the agglomerates with a coating mixture powder comprising a particulate copper sulphide and one or more binders to form coated agglomerates, and
(iv) drying the coated agglomerates at a temperature less than or equal to 200° C. to form a dried sorbent wherein the coating and/or drying steps are performed under non-oxidising conditions.

2. The method according to claim 1 wherein the inert particulate support material is alumina, metal-aluminate, silicon carbide, silica, titania, zirconia, zeolite, metal carbonate, zinc oxide, aluminosilicate, carbon, or a mixture thereof.

3. The method according to claim 1 wherein the inert particulate support material is an alumina or a hydrated alumina.

4. The method according to claim 1 wherein the inert particulate support material is in the form of a powder with a D 50 particle size in the range 1-100 μm.

5. The method according to claim 1 wherein the binder used to prepare the agglomerates is a clay binder, a cement binder or an organic polymer binder.

6. The method according to claim 1 wherein the agglomerates have a diameter in the range 1-15 mm.

7. The method according to claim 1 wherein the particulate copper sulphide is manufactured by roasting copper or a copper compound with elemental sulphur, precipitating copper sulphide from solution, sulphiding copper compounds using hydrogen sulphide, or a mechanochemical process in which powdered copper metal is mixed with elemental sulphur under conditions that cause the elemental copper and elemental sulphur to react to form one or more copper sulphides.

8. The method according to claim 1 wherein the particulate copper sulphide comprises copper (II) sulphide and/or a substoichiometric copper sulphide of formula Cu 2-x S where x is 0-1.

9. The method according to claim 1 wherein the particulate copper sulphide has a S:Cu atomic ratio of ≥0.8.

10. The method according to claim 1 wherein the particulate copper sulphide is in the form of a powder with an average particle size, [D 50 ], in the range 5-100 μm.

11. The method according to claim 1 wherein the copper sulphide content of the sorbent is in the range 0.5-75% by weight expressed as CuS in the dried sorbent.

12. The method according to claim 1 wherein the total binder content of the coating mixture is in the range 5-20% by weight.

13. The method according to claim 1 wherein the coating mixture comprises the particulate copper sulphide and a clay binder as the sole binder.

14. The method according to claim 1 wherein the particulate copper sulphide is present as a layer on the surface of the agglomerate and the thickness of the layer in the dried sorbent is in the range 1 to 1000 μm.

15. The method according to claim 1 wherein the sorbent comprises the particulate copper sulphide and a clay binder as a surface layer coating of 1 to 1000 μm thickness on the surface of agglomerates formed from a particulate hydrated alumina support material, bound together with a cement binder and a clay binder.

16. The method according to claim 15 wherein the suface layer coating further comprises an alumina and/or hydrated alumina.

17. The method according to claim 1 wherein the coating mixture further comprises an alumina and/or hydrated alumina.

18. The method according to claim 1 wherein the agglomerates are coated by adding the coating mixture to the agglomerates in the granulator.

19. The method according to claim 1 wherein the coated agglomerate is dried at 70-150° C.

20. A sorbent prepared by the method of claim 1 .

21. A process for removing a heavy metal from a fluid stream comprising contacting the fluid stream with a sorbent according to claim 20 .

Assignees

• Johnson Matthey Plc

Inventors

• Evans Matthew James
• Lunn Matthew David Gwydion
• Partridge Martin Graham
• Young Christopher John

Classifications

• B01J20/2803

  Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products · CPC title

• B01D2253/1128

  Metal sulfides · CPC title

• Y02C20/20

  of methane · CPC title

• B01J20/3028 Primary

  Granulating, agglomerating or aggregating · CPC title

• C10L3/101

  Removal of contaminants · CPC title