Method and apparatus for sustainable carbon dioxide sequestration
US-2024424442-A1 · Dec 26, 2024 · US
US9919263B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9919263-B2 |
| Application number | US-201615145824-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 4, 2016 |
| Priority date | Oct 11, 2013 |
| Publication date | Mar 20, 2018 |
| Grant date | Mar 20, 2018 |
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An amino-siloxane composition is presented. The amino-siloxane composition includes structure (I): wherein R 1 is independently at each occurrence a C 1 -C 5 aliphatic radical; R 2 is a C 3 -C 4 aliphatic radical; R 3 is a C 1 -C 5 aliphatic radical or R 4 , wherein R 4 comprises structure (II): and X is an electron donating group. Methods of reducing an amount of carbon dioxide in a process stream using the amino-siloxane composition are also presented.
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The invention claimed is: 1. An amino-siloxane composition comprising structure (I): wherein R 1 is independently at each occurrence a C 1 -C 5 aliphatic radical; R 2 is a C 3 -C 4 aliphatic radical; R 3 is a C 1 -C 5 aliphatic radical or R 4 , wherein R 4 comprises structure (II): and X comprises an R 5 O— group; an R 5 S group; or a morpholine group, wherein R 5 is independently at each occurrence a C 1 -C 5 aliphatic radical. 2. The amino-siloxane composition according to claim 1 comprising structure (Ia): wherein R 1 is independently at each occurrence a C 1 -C 5 aliphatic radical; R 2 is a C 3 -C 4 aliphatic radical; and X comprises an R 5 O— group; an R 5 S group; or a morpholine group, wherein R 5 is independently at each occurrence a C 1 -C 5 aliphatic radical. 3. The amino-siloxane composition according to claim 1 comprising structure (Ib): wherein R 1 is independently at each occurrence a C 1 -C 5 aliphatic radical; and X comprises an R 5 O— group; an R 5 S group; or a morpholine group, wherein R 5 is independently at each occurrence a C 1 -C 5 aliphatic radical. 4. The amino-siloxane composition according to claim 1 comprising structure (Ic): wherein X comprises an R 5 O— group; an R 5 S group; or a morpholine group, wherein R 5 is independently at each occurrence a C 1 -C 5 aliphatic radical. 5. The amino-siloxane composition according to claim 1 , wherein X comprises a CH 3 O— group; a C 2 H 5 O— group; or a morpholine group. 6. A reaction product of the amino-siloxane composition of claim 1 with carbon dioxide. 7. An adduct of an amino-siloxane having structure (I) and carbon dioxide wherein R 1 is independently at each occurrence a C 1 -C 5 aliphatic radical; R 2 is a C 3 -C 4 aliphatic radical; R 3 is a C 1 -C 5 aliphatic radical or R 4 , wherein R 4 comprises structure (II): and X comprises an R 5 O— group; an R 5 S group; or a morpholine group, wherein R 5 is independently at each occurrence a C 1 -C 5 aliphatic radical, wherein the adduct is liquid under ambient conditions. 8. The adduct according to claim 7 , wherein X comprises a CH 3 O— group; a C 2 H 5 O— group; or a morpholine group. 9. The adduct according to claim 7 , wherein the amino-siloxane has structure (Ia): wherein R 1 is independently at each occurrence a C 1 -C 5 aliphatic radical; R 2 is a C 3 -C 4 aliphatic radical; and X comprises an R 5 O— group; an R 5 S group; or a morpholine group, wherein R 5 is independently at each occurrence a C 1 -C 5 aliphatic radical. 10. The adduct according to claim 7 , wherein the amino-siloxane has structure (Ib): wherein R 1 is independently at each occurrence a C 1 -C 5 aliphatic radical; and X comprises an R 5 O— group; an R 5 S group; or a morpholine group, wherein R 5 is independently at each occurrence a C 1 -C 5 aliphatic radical. 11. The adduct according to claim 7 , wherein the amino-siloxane has structure (Ic): wherein X comprises an R 5 O— group; an R 5 S group; or a morpholine group, wherein R 5 is independently at each occurrence a C 1 -C 5 aliphatic radical.
Carbon dioxide · CPC title
containing organic oxygen transferring compounds, e.g. sulfoxides · CPC title
Diamines · CPC title
Removing carbon dioxide · CPC title
Cross-Sectional Technologies · mapped topic
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