Process for capturing sulfur dioxide from a gas stream

Patent metadata

Field	Value
Publication number	US-9919262-B2
Application number	US-201415034360-A
Country	US
Kind code	B2
Filing date	Nov 5, 2014
Priority date	Nov 7, 2013
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

A process for removing sulfur dioxide from a feed gas stream, which comprises (i) contacting the feed gas stream with an aqueous lean absorbing medium comprising a chemical solvent comprising a regenerable absorbent, a physical solvent, and one or more heat stable salts. The regenerable absorbent is an amine. The ratio of the wt % of the physical solvent over that of the regenerable absorbent is 0.5 to 2.5. The ratio of the wt % of heat stable salts over that of the regenerable absorbent is 0.29 to 0.37. The pH of the lean absorbing medium is 6 or less. With the process SO2 can be selectively removed. When the absorbing medium is stripped, a reduced amount of energy is required as compared to known processes.

First claim

That which is claimed is:

1. A process for removing sulfur dioxide from a feed gas stream, which process comprises:
(i) contacting the feed gas stream with an aqueous lean absorbing medium to absorb sulfur dioxide and to form a sulfur dioxide lean treated gas stream and a spent absorbing medium;
wherein the aqueous lean absorbing medium comprises:
(a) a chemical solvent comprising a regenerable absorbent,
(b) a physical solvent, and
(c) one or more heat stable salts;

wherein the regenerable absorbent is an amine;
wherein the ratio of the weight percentage of the physical solvent in the lean absorbing medium over that of the regenerable absorbent is in the range of from 0.5 to 2.5;
wherein the ratio of the weight percentage of heat stable salts in the lean absorbing medium over that of the regenerable absorbent is in the range of from 0.29 to 0.37; and
wherein the pH of the lean absorbing medium is 6 or less.

2. The process according to claim 1 , wherein the process further comprises:
(ii) stripping, absorbed sulfur dioxide from the spent absorbing medium to produce a regenerated aqueous absorbing medium and a gaseous sulfur dioxide;
and optionally
(iii) recycling the regenerated aqueous absorbing medium from step (ii) to step (i).

3. The process according to claim 1 , wherein the absorbing medium is present in a single liquid phase during step (i).

4. The process according to claim 2 , wherein the absorbing medium is present in a single liquid phase during step (ii).

5. The process according to claim 2 , wherein step (ii) is performed in a reboiler,
forced circulation reboiler, fired reboiler, falling film reboiler, direct steam reboiler, or thermosyphon.

6. The process according to claim 2 , wherein at least 97 vol % of the spent absorbing medium formed in step (i) is stripped in step (ii).

7. The process according to claim 1 , wherein the regenerable absorbent is a diamine or polyamine which in half salt form has a pK a value for the free nitrogen atom of 3.0 to 5.5, preferably 3.5 to 4.7, at a temperature of 20° C. in an aqueous medium.

8. The process according to claim 1 , wherein the regenerable absorbent is a diamine represented by the formula:

wherein R 1 is an alkylene of two or three carbon atoms as a straight chain or as a branched chain, R 2 , R 3 , R 4 , and R 5 may be the same or different and can be hydrogen, alkyl, hydroxyalkyl, aralkyl, aryl, or alkaryl, and any of R 2 , R 3 , R 4 , and R 5 may form cyclic structures.

9. The process according to claim 1 , wherein the regenerable absorbent is a tertiary amine represented by the formula:

wherein R 1 is an alkylene of two or three carbon atoms as a straight chain or as a branched chain, and R 2 , R 3 , R 4 , and R 5 can be alkyl, hydroxyalkyl, aralkyl, aryl, or alkaryl, and any of R 2 , R 3 , R 4 , and R 5 may form cyclic structures.

10. The process according to claim 1 , wherein the regenerable absorbent is piperazine, hydroxyethyl piperazine, bis-hydroxyethyl piperazine, hydroxyethylethylenediamine, bis-hydroxyethylethylenediamine, 1,4-diazabicyclo[2.2.2]octane (DABCO), 2-[2-aminoethyl]pyridine, 2-aminomethylpyridine, 3-amino 5-methylpyrazole, 3-aminopyrazole, 3-methylpyrazole, N,N,N′,N′-tetraethyldiethylenetriamine, N,N,N′,N′-tetramethyldiethylenetriamine, 2-piperazinone 1,4-bis[2-hydroxyethyl], or a combination thereof.

11. The process according to claim 1 , wherein the lean absorbing medium additionally comprises an organic acid and/or an anorganic acid.

12. The method according to claim 1 , wherein the physical solvent has a vapour pressure less than 0.1 mmHg at 20° C. with a boiling point equal to or higher than 240° C.

13. The process according to claim 1 , wherein the physical solvent is a polyol, a polycarbonate, an N-formyl morpholine, or a combination thereof.

14. The process according to claim 1 , wherein the physical solvent is polyethyleneglycol dimethylether (PEGDME), tetraethyleneglycol dimethylether (TetraEGDME), tetraethylene glycol (TetraEG), triethyleneglycol monomethylether (TriEGMME), or a combination thereof.

15. The process according to claim 1 , wherein the physical solvent is polyethyleneglycol dimethylether (PEGDME), and
wherein the regenerable absorbent is
4-[hydroxyethyl]piperazine (Hep), or
1,4-bis[hydroxyethyl]piperazine (DiHep), or
3-aminopyrazole, or
a mixture of 4-[hydroxyethyl]piperazine (Hep) and
1,4-bis[hydroxyethyl]piperazine (DiHep).

Assignees

• Cansolv Tech Inc
• Shell Oil Co

Inventors

• Ouimet Michel
• Infantino Mélina

Classifications

• Y02C20/40

  of CO2 · CPC title

• B01D2252/20415

  Tri- or polyamines · CPC title

• B01D2252/2041

  Diamines · CPC title

• B01D53/1493

  Selection of liquid materials for use as absorbents · CPC title

• B01D2252/20

  Organic absorbents · CPC title