Sweep membrane separator and fuel processing systems

Patent metadata

Field	Value
Publication number	US-9917320-B2
Application number	US-201715417283-A
Country	US
Kind code	B2
Filing date	Jan 27, 2017
Priority date	Sep 2, 2011
Publication date	Mar 13, 2018
Grant date	Mar 13, 2018

Abstract

A sweep membrane separator includes a membrane that is selectively permeable to a selected gas, the membrane including a retentate side and a permeate side. A mixed gas stream including the selected gas enters the sweep membrane separator and contacts the retentate side of the membrane. At least part of the selected gas separates from the mixed gas stream and passes through the membrane to the permeate side of the membrane. The mixed gas stream, minus the separated gas, exits the sweep membrane separator. A sweep gas at high pressure enters the sweep membrane separator and sweeps the selected gas from the permeate side of the membrane. A mixture of the sweep gas and the selected gas exits the sweep membrane separator at high pressure. The sweep membrane separator thereby separates the selected gas from the gas mixture and pressurizes the selected gas.

First claim

The invention claimed is:

1. A fuel processing system comprising:
a hydrodesulfurization reactor;
a raw sulfur-bearing hydrocarbon fuel supply connected to the hydrodesulfurization reactor; and
a sweep membrane separator connected to the hydrodesulfurization reactor, the sweep membrane separator including a membrane that is selectively permeable to hydrogen; the membrane including a retentate side and a permeate side;
a supply of reformate configured to enter the sweep membrane separator and contact the retentate side of the membrane, the reformate including hydrogen;
wherein at least part of the hydrogen separates from the reformate and passes through the membrane to the permeate side of the membrane; and,
wherein the reformate, minus the separated hydrogen, exits the sweep membrane separator;

and,
a supply of sweep gas configured to enter the sweep membrane separator and sweep the hydrogen from the permeate side of the membrane;
wherein a mixture of the sweep gas and the hydrogen exits the sweep membrane separator; and,
wherein the sweep membrane separator separates hydrogen from the reformate and pressurizes the hydrogen.

2. The fuel processing system of claim 1 further comprising a vaporizer configured to produce the sweep gas for the sweep membrane separator.

3. The fuel processing system of claim 1 further comprising a vaporizer configured to vaporize the sulfur-bearing hydrocarbon fuel prior to the hydrodesulfurization reactor.

4. The fuel processing system of claim 1 , wherein the sweep gas is steam.

5. The fuel processing system of claim 1 , wherein the sweep gas is vaporized fuel.

6. The fuel processing system of claim 1 further comprising a reforming reactor configured to produce and feed a reformate to the sweep membrane separator.

7. The fuel processing system of claim 6 wherein the hydrodesulfurization reactor is configured to operate at a higher pressure than the reforming reactor.

8. The fuel processing system of claim 6 further comprising a burner configured to heat the reforming reactor, wherein the burner operates on excess reformate or off-gas from the hydrodesulfurization reactor.

9. The fuel processing system of claim 6 further comprising a burner configured to heat the reforming reactor, and a fuel condenser configured to remove clean fuel from non-condensable gases, the non-condensable gases being directed to the burner.

10. The fuel processing system of claim 6 wherein the reforming reactor is a microtech reactor.

11. The fuel processing system of claim 6 further comprising a clean fuel output at least a portion of which is directed to the reforming reactor.

12. The fuel processing system of claim 6 wherein the sweep membrane separator is connected to direct hydrogen to the reforming reactor.

13. The fuel processing system of claim 6 further comprising a solid oxide fuel cell, and wherein fuel processing system directly routes reformate from sweep membrane separator to the solid oxide fuel cell.

Assignees

• Battelle Memorial Institute

Inventors

• Thornton Douglas A
• Contini Vincent J
• George Ii Paul E

Classifications

• C01B2203/066

  with fuel cells · CPC title

• H01M8/12

  operating at high temperature, e.g. with stabilised ZrO2 electrolyte · CPC title

• C01B2203/127

  Catalytic desulfurisation · CPC title

• C10G67/06

  including a sorption process as the refining step in the absence of hydrogen · CPC title

• B01D2053/221

  Devices · CPC title