Electrode active material for lithium secondary battery, method of preparing the electrode active material, electrode for lithium secondary battery including the same, and lithium secondary battery using the same

Patent metadata

Field	Value
Publication number	US-9917302-B2
Application number	US-201213585371-A
Country	US
Kind code	B2
Filing date	Aug 14, 2012
Priority date	Oct 11, 2011
Publication date	Mar 13, 2018
Grant date	Mar 13, 2018

Abstract

An electrode active material for a lithium secondary battery, a method of preparing the electrode active material, an electrode for a lithium secondary battery which includes the same, a lithium secondary battery using the electrode. The electrode active material includes a core active material and a coating layer including magnesium aluminum oxide (MgAlO 2 ) and formed on the core active material. 1s binding energy peaks of oxygen (O) in the electrode active material measured by x-ray photoelectron spectroscopy (XPS) are shown at positions corresponding to 529.4±0.5 eV, about 530.7 eV, and 531.9±0.5 eV, and a peak intensity at the position corresponding to 529.4±0.5 eV is stronger than a peak intensity at the position corresponding to about 530.7 eV.

First claim

What is claimed is:

1. An electrode active material for a lithium secondary battery, the electrode active material comprising:
a core active material; and
a uniform coating layer comprised of magnesium aluminum oxide (MgAlO 2 ) and formed on a surface of the core active material, wherein a content of magnesium aluminum oxide (MgAlO 2 ) of the coating layer is in a range of about 0.001 to about 10 parts by weight based on 100 parts by weight of the core active material,
1s binding energy peaks of oxygen (O) in the electrode active material measured by x-ray photoelectron spectroscopy (XPS) are shown at positions corresponding to
529.4±0.5 eV,
about 530.7 eV, and
531.9±0.5 eV, and,

a peak intensity at the position corresponding to 529.4±0.5 eV is stronger than a peak intensity at the position corresponding to about 530.7 eV, wherein a content of magnesium (Mg) at a penetration depth of 2 μm or less of the coating layer measured by energy dispersive x-ray analysis (EDX) is about 0.01 to about 3.0 weight % based on the total weight of the coating layer with the penetration depth of 2 μm or less, wherein a content of aluminum (Al) at a penetration depth of 2 μm or less of the coating layer measured by EDX is about 0.01 to about 3.0 weight % based on the total weight of the coating layer with the penetration depth of 2 μm or less, wherein the electrode active material is produced by a process comprising:
forming a core of LiCoO 2 ;
producing an Mg-doped LiCoO 2 core by doping the LiCoO 2 core with Mg until an Mg content is about 1 to about 15 parts per million (ppm) by weight of the LiCoO 2 core; and
transferring the Mg from the Mg-doped LiCoO 2 core to the coating layer by performing a heat treatment in the range of about 300 to about 1000° C. in an air or oxygen atmosphere.

2. The electrode active material for the lithium secondary battery of claim 1 , wherein an intensity ratio of the peak at the position corresponding to 529.4±0.5 eV to the peak at the position corresponding to about 530.7 eV is between about 1:0.6 through about 1:0.9.

3. The electrode active material for the lithium secondary battery of claim 1 , wherein a peak intensity at the position corresponding to 531.9±0.5 eV is either the same or stronger than the peak intensity at the position corresponding to about 530.7 eV.

4. The electrode active material for the lithium secondary battery of claim 1 , wherein an intensity ratio of the peak at the position corresponding to about 530.7 eV to the peak at the position corresponding to 531.9±0.5 eV is between about 1:1.0 through about 1:1.3.

5. The electrode active material for the lithium secondary battery of claim 1 , wherein an intensity ratio of the peak at the position corresponding to about 529.4±0.5 eV to the peak at the position corresponding to about 531.9±0.5 eV is between about 1:0.7 through about 1:1.0.

6. The electrode active material for the lithium secondary battery of claim 1 , wherein a content of Mg at a penetration depth of 2 μm or less of the coating layer measured by EDX is about 0.02 to about 20 parts by weight based on 100 parts by weight of oxygen in the coating layer with the penetration depth of 2 μm or less.

7. The electrode active material for the lithium secondary battery of claim 1 , wherein a content of Al at a penetration depth of 2 μm or less of the coating layer measured by EDX is about 0.02 to about 20 parts by weight based on 100 parts by weight of oxygen in the coating layer with the penetration depth of 2 μm or less.

8. The electrode active material for the lithium secondary battery of claim 1 , wherein the core active material is a lithium-transition metal composite oxide represented by the following Formula 1
Li a Mg b MO 2   [Formula 1]

wherein M is at least one selected from the group consisting of cobalt (Co), manganese (Mn), iron (Fe), and nickel (Ni),
0<a≦1, and
0<b<0.5.

9. The electrode active material for the lithium secondary battery of claim 8 , wherein M in Formula 1 is Co.

10. The electrode active material for the lithium secondary battery of claim 1 , wherein binding energy peaks of Mg measured by XPS are shown at positions corresponding to 304.2±0.5 eV and 1302.2±0.5 eV.

11. The electrode active material for the lithium secondary battery of claim 1 , wherein a thickness of the coating layer is about 1 nm to about 100 nm.

12. The electrode active material for the lithium secondary battery of claim 1 , wherein an average particle diameter of the electrode active material is about 1 μm to about 80 μm.

13. An electrode for a lithium secondary battery, the electrode comprising the electrode active material according to claim 1 .

14. A lithium secondary battery comprising the electrode of claim 1 .

Assignees

• Jeong Chang Ui
• Moon Sung Hwan
• Kim Jae Hyuk
• Matulevich Yury
• Chu Hee Young
• Jeong Myung Hwan
• Choi Jong Seo
• Samsung Sdi Co Ltd

Inventors

• Jeong Chang-Ui
• Moon Sung-Hwan
• Kim Jae-Hyuk
• Matulevich Yury
• Chu Hee-Young
• Jeong Myung-Hwan
• Choi Jong-Seo

Classifications

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/48

  of inorganic oxides or hydroxides · CPC title

• H01M4/366 Primary

  as layered products · CPC title

• H01M10/052

  Li-accumulators · CPC title